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    • 1. 发明专利
    • Steel product having carbo-nitrided layer and method for producing the same
    • 具有碳化物层的钢制品及其制造方法
    • JP2011168820A
    • 2011-09-01
    • JP2010032017
    • 2010-02-17
    • Sumitomo Metal Ind Ltd住友金属工業株式会社
    • HORIMOTO MASAYUKISANO NAOYUKI
    • C22C38/00C21D1/06C21D9/32C22C38/60C23C8/22C23C8/32C23C8/34
    • PROBLEM TO BE SOLVED: To provide a steel product having a carbo-nitrided layer securing superior abrasion resistance and large pitting resistance even when the content of expensive Mo is reduced or Mo is not added.
      SOLUTION: The steel product having a carbo-nitrided layer is provided, whose original steel material has a chemical composition containing 0.10 to 0.35% of C, 0.40 to 1.00% of Si, 0.60 to 1.50% of Mn, 0.40 to 0.80% of Cr, 0.01 to 0.05% of Al, 0.05% or less of S and 0.0020 to 0.0300% of N, wherein [(Si+Mn)/Cr] is 2 or more, and the balance comprises Fe and impurities. The steel product has dispersed alloy nitride consisting of MnSiN
      2 only in the region from the surface of the carbo-nitrided layer to the depth of 50 μm and has the austenitic amount in a volume proportion of 30 to 40% on the surface of the carbo-nitrided layer. The original steel material contains at least one of Mo≤0.01%, Ti≤0.10% and Nb≤0.080%, as necessary.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:即使当昂贵的Mo的含量降低或不添加Mo时,提供具有确保优异的耐磨性和大的耐点腐蚀性的碳氮化层的钢产品。 解决方案:提供具有碳氮化层的钢产品,其原钢材料具有C:0.10〜0.35%,Si:0.40〜1.00%,Mn:0.60〜1.50%,0.40〜0.80 的Cr,0.01〜0.05%的Al,0.05%以下的S和0.0020〜0.0300%的N,其中[(Si + Mn)/ Cr]为2以上,余量由Fe和杂质构成。 该钢产品仅在从碳氮化层的表面到深度为50μm的区域中仅具有由MnSiN 2 组成的分散合金氮化物,并且奥氏体体积比例为30至40 在碳氮化层的表面上的%。 原钢材料根据需要含有Mo≤0.01%,Ti≤0.10%,Nb≤0.080%中的至少一种。 版权所有(C)2011,JPO&INPIT
    • 2. 发明专利
    • Martensitic iron based heat resistant alloy
    • 马氏体耐热合金
    • JP2007162112A
    • 2007-06-28
    • JP2005363397
    • 2005-12-16
    • Sumitomo Metal Ind Ltd住友金属工業株式会社
    • YOSHIZAWA MITSURUIGARASHI MASAAKISANO NAOYUKI
    • C22C38/00C21D8/00C22C38/38C22C38/58
    • PROBLEM TO BE SOLVED: To provide a martensitic heat resistant alloy having excellent high temperature long time creep strength suitable for a steel tube for a heat exchanger, a steel sheet for a pressure vessel, a turbine material or the like used under high temperature-high pressure environments in a boiler, nuclear power generation equipment, chemical industry equipment or the like.
      SOLUTION: The martensitic iron based heat resistant alloy has a composition comprising, by mass, 8 to 16% Cr, 1 to 18% Co, 0.01 to 1% Si, 0.01 to 3% Mn, 0.0005 to 0.03% B, 0.001 to 0.1% sol.Al and 0 to 0.5% Cu, further comprising either or both of ≤2% Mo and ≤5% W in the ranges satisfying inequality (1), and the balance Fe with impurities satisfying ≤0.05% C, ≤0.01% N, ≤0.05% P and ≤0.02% S, and has a modulated structure in the using process in the temperature region of ≥575°C. The steel may comprise one or more kinds selected from Nb, V, Ni, Ta, Hf, Ti, REM, Ca and Mg as well. (1): Mo+(1/2)W≥0.5%, wherein Mo and W denote the respective contents (mass%).
      COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种适用于热交换器用钢管的高温长时间蠕变强度优异的马氏体系耐热合金,在高压下使用的压力容器用钢板,涡轮机材料等 锅炉,核能发电设备,化工设备等的高温环境。 解决方案:马氏体系铁基耐热合金的组成为:以质量计含有8〜16%的Cr,1〜18%的Co,0.01〜1%的Si,0.01〜3%的Mn,0.0005〜0.03%的B, 0.001〜0.1%的sol.Al和0〜0.5%的Cu,在满足不等式(1)的范围内进一步包含≤2%Mo和≤5%W中的任一种或两者,余量为Fe,杂质≤0.05%C, ≤0.01%N,≤0.05%P和≤0.02%S,并且在≥575℃的温度范围内的使用过程中具有调制结构。 钢可以包含Nb,V,Ni,Ta,Hf,Ti,REM,Ca和Mg中的一种或多种。 (1):Mo +(1/2)W≥0.5%,其中Mo和W表示各自的含量(质量%)。 版权所有(C)2007,JPO&INPIT
    • 4. 发明专利
    • Method for manufacturing nitrided machine part
    • 制造硝化机部件的方法
    • JP2012036495A
    • 2012-02-23
    • JP2011085823
    • 2011-04-07
    • Sumitomo Metal Ind Ltd住友金属工業株式会社
    • SANO NAOYUKITODO SHOJISUKETANI MASAHITO
    • C23C8/26C21D1/06C21D9/32C21D9/40C22C38/00C22C38/60
    • PROBLEM TO BE SOLVED: To generate a high surface hardness and a deep hardened layer by comparatively short time (several hours) treatment while maintaining low distortion of machine parts in nitriding treatment.SOLUTION: A method for manufacturing nitrided machine parts includes: a step for preparing a steel material; a step for nitriding the steel material at a nitriding temperature T(°C) of 700°C or more in a condition that a value of an austenite volume fraction Fγ(T) defined by equations (1) to (4) satisfies 0.10≤Fγ(T)≤0.60; and a step for quenching the steel material after the nitriding. The equations are (1):K=44.7×Si-30×Mn-11×Cr, (2):Xα(T)=(910-T)/8394, (3):Xγ(T)=(910+K-T)/41209, and(4): Fγ(T)=(C-Xα)/(Xγ-Xα). Each of chemical symbols of elements in the equations (1) to (4) expresses the content of each element by mass%.
    • 要解决的问题:为了在氮化处理中保持机器部件的变形较小,通过相当短的时间(几小时)处理来产生高表面硬度和深度硬化层。 解决方案:一种用于制造氮化机器部件的方法包括:制备钢材的步骤; 在等式(1)至(4)定义的奥氏体体积分数Fγ(T)的值满足0.10≤i的条件下,在700℃以上的氮化温度T(℃)下对钢材进行氮化的工序 Fγ(T)≤0.60; 以及在氮化后淬火钢材的步骤。 方程为(1):K = 44.7×Si-30×Mn-11×Cr,(2):Xα(T)=(910-T)/ 8394,(3):Xγ(T)=(910+ KT) 2 / 41209和(4):Fγ(T)=(C-Xα)/(Xγ-Xα)。 式(1)〜(4)中的各元素的化学符号以质量%表示各元素的含量。 版权所有(C)2012,JPO&INPIT
    • 5. 发明专利
    • Steel for gear to be vacuum-carburized
    • 用于齿轮的钢被真空加固
    • JP2008133501A
    • 2008-06-12
    • JP2006319925
    • 2006-11-28
    • Sumitomo Metal Ind Ltd住友金属工業株式会社
    • HORIMOTO MASAYUKISANO NAOYUKI
    • C22C38/00C22C38/26
    • PROBLEM TO BE SOLVED: To provide a steel for a gear to be vacuum-carburized, which shows superior fatigue strength to surface pressure and superior fatigue strength to bending, does not cause abnormal grain growth, and shows adequate machinability as well, even when vacuum-carburized at a high temperature exceeding 1,000°C.
      SOLUTION: The steel for the gear to be vacuum-carburized has a chemical composition comprising 0.13 to 0.30% C, more than 0.50% to 1.50% Si, 0.70 to 1.50% Mn, 0.10% or less P, 0.01 to 0.05% S, 0.70 to 1.50% Cr, 0.010 to 0.050% Nb, 0.010 to 0.050% Al, 0.0100 to 0.0250% N, while controlling the contents of Si, Mn and Cr so that Si+Mn can be 2.50% or less and 4Mn+4Cr-Si can be 7.2 to 9.0%, and the balance Fe with impurities among which V is 0.005% or less; and has a ferrite-pearlite structure before the steel is vacuum-carburized, in which the ferrite grains have sizes of 100 μm or smaller.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供对真空渗碳的齿轮钢,其对于表面压力的显示优异的疲劳强度和优异的弯曲疲劳强度,不会引起异常的晶粒生长,并且也显示出适当的机械加工性, 即使在超过1000℃的高温下进行真空渗碳。 解决方案:用于真空渗碳的齿轮的钢具有包含0.13〜0.30%C,大于0.50%〜1.50%的Si,0.70〜1.50%的Mn,0.10%以下的P,0.01〜0.05的化学组成 %S,0.70〜1.50%Cr,0.010〜0.050%Nb,0.010〜0.050%Al,0.0100〜0.0250%N,同时控制Si,Mn和Cr的含量,使Si + Mn为2.50%以下,4Mn + 4Cr-Si可以为7.2〜9.0%,余量为Fe,杂质为V为0.005%以下; 在钢被真空渗碳之前具有铁素体 - 珠光体组织,其中铁素体晶粒的尺寸为100μm或更小。 版权所有(C)2008,JPO&INPIT
    • 6. 发明专利
    • Martensitic iron based heat resistant alloy
    • 马氏体耐热合金
    • JP2007162114A
    • 2007-06-28
    • JP2005363413
    • 2005-12-16
    • Sumitomo Metal Ind Ltd住友金属工業株式会社
    • YOSHIZAWA MITSURUIGARASHI MASAAKISANO NAOYUKI
    • C22C38/00C21D8/00C22C38/38C22C38/58
    • PROBLEM TO BE SOLVED: To provide a martensitic heat resistant alloy having high temperature long time creep strength suitable for a steel tube for a heat exchanger, a steel sheet for a pressure vessel, a turbine material or the like used under high temperature-high pressure environments in a boiler, nuclear power generation equipment, chemical industry equipment or the like.
      SOLUTION: The martensitic iron based heat resistant alloy has a composition comprising, by mass, 8 to 16% Cr, 1 to 18% Co, 0.01 to 1% Si, 0.01 to 3% Mn, 0.0005 to 0.03% B, 0.001 to 0.1% sol.Al and 0 to 0.5% Cu, further comprising either or both of ≤2% Mo and ≤5% W in the ranges satisfying inequality (1), and the balance Fe with impurities satisfying ≤0.05% C, ≤0.01% N, ≤0.05% P and ≤0.02% S, and has a modulated structure. The alloy may further comprise one or more kinds selected from Nb, V, Ni, Ta, Hf, Ti, REM, Ca and Mg. (1): Mo+(1/2)W≥0.5%, wherein Mo and W denote the respective contents (mass%).
      COPYRIGHT: (C)2007,JPO&INPIT
    • 解决的问题:提供适用于热交换器的钢管的高温长时间蠕变强度的马氏体系耐热合金,高温下使用的压力容器用钢板,涡轮机材料等 - 锅炉,核能发电设备,化工设备等的高压环境。 解决方案:马氏体系铁基耐热合金的组成为:以质量计含有8〜16%的Cr,1〜18%的Co,0.01〜1%的Si,0.01〜3%的Mn,0.0005〜0.03%的B, 0.001〜0.1%的sol.Al和0〜0.5%的Cu,在满足不等式(1)的范围内进一步包含≤2%Mo和≤5%W中的任一种或两者,余量为Fe,杂质≤0.05%C, ≤0.01%N,≤0.05%P和≤0.02%S,并具有调制结构。 该合金还可以包含选自Nb,V,Ni,Ta,Hf,Ti,REM,Ca和Mg中的一种或多种。 (1):Mo +(1/2)W≥0.5%,其中Mo和W表示各自的含量(质量%)。 版权所有(C)2007,JPO&INPIT
    • 8. 发明专利
    • Aging state evaluation method for cu-containing steel product and aging treatment method using it
    • 用于含铜产品的老化状态评估方法和使用其的老化处理方法
    • JP2005274513A
    • 2005-10-06
    • JP2004091763
    • 2004-03-26
    • Jfe Steel KkJfeスチール株式会社Kobe Steel LtdNippon Steel CorpSumitomo Metal Ind Ltd住友金属工業株式会社新日本製鐵株式会社株式会社神戸製鋼所
    • NOMURA MASAHIROYAGUCHI HIROSHIYAMASHITA TAKAKOFUJIOKA MASAAKISANO NAOYUKI
    • G01N23/06C22C38/00C22C38/16G01N33/20
    • PROBLEM TO BE SOLVED: To provide an aging state evaluation method capable of grasping the precipitation state of a Cu-precipitate in the aging treatment process of a Cu-containing steel by use of XAFS measurement method and nondestructively confirming the propriety of aging treatment, and an aging treatment method using it.
      SOLUTION: In this method for evaluating the aging state of a steel product containing 1-5 mass% of Cu, when the peak height value at 8.98 KeV in the vicinity of fluorescent X-ray spectrum K absorption edge of Cu constituting a precipitate involved in aging in the steel product, which is measured at ordinary temperature by XAFS method, is within 2.8-3.8 shown by standardized phosphor yield, it is evaluated that the aging treatment is properly performed. According to this, the aging treatment state such as hardness rise of Cu-containing steel product can be nondestructively evaluated without performing a material test such as a tensile test or hardness test which needs sample adjustment, and the propriety of the aging treatment and the quality of Cu-containing aged steel product can be easily confirmed.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种能够通过使用XAFS测量方法在Cu含量钢的时效处理过程中捕获Cu沉淀物的沉淀状态的老化状态评估方法,并且非破坏性地确认老化的适当性 治疗和使用它的老化治疗方法。 解决方案:在用于评估含有1-5质量%Cu的钢产品的老化状态的方法中,当Cu的荧光X射线光谱K吸收边缘附近的8.98KeV的峰高值构成为 通过XAFS法在常温下测定的钢产品的老化沉淀在通过标准化的磷光体产率表示的2.8-3.8内,评价了适当地进行时效处理。 因此,不进行诸如需要进行样品调整的拉伸试验或硬度试验等材料试验,老化处理和质量的适当性等,可以非腐蚀性地评价含铜钢产品的老化处理状态如硬度升高 的含铜老化钢产品可以容易地确认。 版权所有(C)2006,JPO&NCIPI