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1. 发明专利

JP2007234576A Direct formic acid fuel cell and its operation method 审中-公开
标题翻译：直接酸性燃料电池及其操作方法
公开(公告)号：JP2007234576A
公开(公告)日：2007-09-13
申请号：JP2006321774
申请日：2006-11-29
申请人： Korea Inst Of Science & Technology , コリアインスティテュートオブサイエンスアンドテクノロジー
发明人： LEE JAEYOUNG , HAN JONHI , LIM TAE HOON , NAM SUK-WOO , YOON SUNG PIL , KIM HYOUNG-JUHN , CHO EUN AE , HA FUN YON , HONG SEONG AHN , OH IN HWAN , HAHM HYUNG CHUL , KIM YONG CHUN , LEE SANG YEOP , LEE KWANG SOO
IPC分类号： H01M8/04 , H01M8/10
CPC分类号： H01M8/1009 , H01M8/04194 , H01M8/04447 , H01M8/04798
摘要： PROBLEM TO BE SOLVED: To provide a direct formic acid fuel cell capable of securing its long-term operation by controlling concentration of formic acid in real time and its operation method. SOLUTION: The direct formic acid fuel cell comprises a unit cell 10 having an anode 12, a polymer electrolyte, and a cathode 11, formic acid supply parts (21, 22, 23) to supply formic acid as fuel to the anode 12, an air supply part 60 to supply air to the cathode 11, a formic acid concentration measuring instrument 30 to measure the concentration of a part of formic acid to be supplied to the anode 12, and a control part 40 which receives the measured value from the formic acid concentration measuring instrument 30, compares it with the range of concentration value established beforehand, and controls the concentration of the formic acid supplied to the anode 12 at real time corresponding to real time measurement of the formic acid concentration instrument 30 so that the concentration value measured may not be out of the range of the established concentration value. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供通过控制甲酸浓度实时确保其长期操作的直接甲酸燃料电池及其操作方法。解决方案：直接甲酸燃料电池包括具有阳极12，聚合物电解质和阴极11的单电池10，将甲酸作为燃料供应到阳极的甲酸供应部分（21,22,23） 12，向阴极11供给空气的供气部60，测定向阳极12供给的甲酸的一部分浓度的甲酸浓度测定装置30以及接收测定值的控制部40 从甲酸浓度测定装置30将其与预先确定的浓度值的范围进行比较，并且实时控制对应于甲酸浓度仪30的实时测定的与阳极12供给的甲酸的浓度，使得测得的浓度值可能不在设定浓度值的范围之外。版权所有（C）2007，JPO＆INPIT

2. 发明专利

JP2003346818A Electrode of fine structure with three-phase interface by porous ion-conductive ceria film coating, and method for manufacturing the same 有权
标题翻译：通过多孔导电陶瓷膜涂覆的三相接口的精细结构电极及其制造方法
公开(公告)号：JP2003346818A
公开(公告)日：2003-12-05
申请号：JP2002154283
申请日：2002-05-28
申请人： Korea Inst Of Science & Technology , コリアインスティテュートオブサイエンスアンドテクノロジー
发明人： HONG SUNG-AHN , OH IN-HWAN , LIM TAE-HOON , NAM SUK-WOO , HA HOONG-YOUNG , YOON SUNG PIL , HAN JONGHEE
IPC分类号： C04B38/00 , C04B35/50 , C04B41/87 , G01N27/409 , H01M4/86 , H01M4/88 , H01M8/12
CPC分类号： Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a composite electrode and a manufacturing method thereof for coating an ion conductive ceramic film on an electrode to mainly perform the electronic conduction around the electrode and an electrolyte in order to improve the electrode performance of a fuel cell, a sensor and a solid state device, and additionally extending a three-phase interface with the electrode/the electrolyte/the gas in contact therewith as an electrochemical reaction part while an electronic conductive material and an ion conductive material are independent of each other. SOLUTION: There is provided a method for improving the electrode performance by coating a continuous porous oxygen ion conductive ceramic ceria film by a sol-gel method around an electrode of a solid oxide fuel cell (SOFC) or a sensor to provide a very fine structure with a three-phase interface extended with an electronic conductive material and an ion conductive material independent from each other. No expensive device or starting material is required, the small structure is easily controlled, the electrode/electrolyte interface resistance is effectively reduced in a low-temperature step, the area of the three-phase interface is increased, the electrode resistance is reduced, and the electrode performance of the SOFC, the sensor, and the solid-state device is improved. COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供一种用于在电极上涂覆离子传导性陶瓷膜的复合电极及其制造方法，以主要在电极和电解质周围进行电子传导，以改善燃料的电极性能电池，传感器和固态器件，并且另外延伸与电极/电解质/与其接触的气体的三相界面作为电化学反应部分，同时电子导电材料和离子导电材料彼此独立。提供一种通过在固体氧化物型燃料电池（SOFC）或传感器的电极周围通过溶胶 - 凝胶法涂覆连续的多孔氧离子导电陶瓷二氧化铈膜来提高电极性能的方法，以提供具有用电子导电材料和彼此独立的离子导电材料延伸的三相界面的非常精细的结构。不需要昂贵的器件或起始材料，容易控制小结构，在低温阶段有效降低电极/电解质界面电阻，增加三相界面的面积，降低电极电阻，改善了SOFC，传感器和固态器件的电极性能。版权所有（C）2004，JPO

3. 发明专利

JP2006257390A Polybenzimidazole-based polymer and method for producing the same 审中-公开
标题翻译：基于聚苯并咪唑的聚合物及其制备方法
公开(公告)号：JP2006257390A
公开(公告)日：2006-09-28
申请号：JP2005314812
申请日：2005-10-28
申请人： Korea Inst Of Science & Technology , コリアインスティテュートオブサイエンスアンドテクノロジー
发明人： KIM HYOUNG-JUHN , CHO EUNAE , HAN JONGHEE , YOON SUNG PIL , LEE JAEYOUNG , HA HEUNG YONG , NAM SUK-WOO , OH IN-HWAN , HONG SEONG-AHN , LIM TAE-HOON
IPC分类号： C08G73/18 , H01M8/02
CPC分类号： C08J5/2256 , C08G73/0672 , C08G73/18 , C08J2379/04 , H01M8/1027 , H01M8/103 , H01M8/1048 , H01M2300/0082
摘要： PROBLEM TO BE SOLVED: To provide a low cost polybenzimidazole-based polymer which can be used for fuel batteries, especially membranes for fuel batteries, under conditions of high temperature and non-humidification, and having a high doping concentration and excellent mechanical characteristics, and to provide a method for producing the same. SOLUTION: The polybenzimidazole-based polymer prepared by doping a copolymer of 3,3'-diaminobenzidine, isophthalic acid or terephthalic acid, and diaminobenzoic acid with phosphoric acid, and a method for producing the same. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种低成本的聚苯并咪唑基聚合物，其可用于燃料电池，特别是用于燃料电池的膜，在高温和非加湿条件下，并且具有高的掺杂浓度和优异的机械特性，并提供其制造方法。解决方案：通过将3,3'-二氨基联苯胺，间苯二甲酸或对苯二甲酸和二氨基苯甲酸与磷酸的共聚物掺杂制备的聚苯并咪唑基聚合物及其制备方法。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2014152326A Cardo copolybenzimidazoles, gas separation membranes and preparation method thereof 有权
标题翻译： CARDO共聚苯二甲酸酐，气体分离膜及其制备方法
公开(公告)号：JP2014152326A
公开(公告)日：2014-08-25
申请号：JP2013083958
申请日：2013-04-12
申请人： Korea Institute Of Science And Technology , コリア・インスティテュート・オブ・サイエンス・アンド・テクノロジー
发明人： KIM HYOUNG-JOON , HAN JUN YOUNG , JANG JONG HYUN , CHO EUN AE , HAN JONGHEE , NAM SUK WOO , LIM TAE-HOON , YOON SUNG PIL , YOO SUNG JONG , DIRK HENKENSMEIER
IPC分类号： C08G61/12 , B01D71/62 , C08J5/18
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0002 , B01D67/0095 , B01D2256/12 , B01D2257/102 , C01B13/0251 , C08G73/18
摘要： PROBLEM TO BE SOLVED: To provide cardo copolybenzimidazoles, gas separation membranes, and a preparation method thereof.SOLUTION: This invention relates to cardo copolybenzimidazoles, a gas separation membrane using the same and a method for preparing the same. More particularly, cardo copolybenzimidazoles obtained by introducing cardo groups and aromatic ether groups to a polybenzimidazole backbone are synthesized. A gas separation membrane has significantly improved oxygen permeability by using the same, and the method for preparing the same is also provided. The cardo copolybenzimidazoles prepared by the invention have improved solubility as compared to the polybenzimidazole polymers according to the related art, show excellent mechanical properties while maintaining thermal stability so as to be formed into a film shape, and can provide a gas separation membrane having significantly improved gas permeability, particularly, oxygen permeability.
摘要翻译：要解决的问题：提供聚苯并咪唑类，气体分离膜及其制备方法。本发明涉及共聚苯并咪唑类，其使用的气体分离膜及其制备方法。更具体地说，合成了通过将聚苯并咪唑主链引入基团和芳族醚基团得到的共聚苯并咪唑。气体分离膜通过使用它们具有显着改善的透氧性，并且还提供了其制备方法。通过本发明制备的卡诺共聚苯并咪唑与根据现有技术的聚苯并咪唑聚合物相比具有改善的溶解性，显示出优异的机械性能，同时保持热稳定性以形成膜状，并且可以提供显着改进的气体分离膜透气性，特别是透氧性。

5. 发明专利

JP2014009157A Ceria-based composition containing bismuth oxide, ceria-based composite electrolyte powder, sinter method of the same, and sinter body of the same 有权
标题翻译：含有二氧化硅的CERIA基组合物，基于CERIA的复合电解质粉末，其烧结方法及其相同体系
公开(公告)号：JP2014009157A
公开(公告)日：2014-01-20
申请号：JP2013135850
申请日：2013-06-28
申请人： Korea Institute Of Science And Technology , コリア・インスティテュート・オブ・サイエンス・アンド・テクノロジー
发明人： YOON SUNG PIL , HAN JONGHEE , SONG SHIN AE , LIM TAE HOON , KIM HYOUNG-JUHN , JANG JONG HYUN , DIRK HENKENSMEIER , CHO EUN AE , NAM SUK WOO , HONG SEONG AHN , THIEU CAM ANH
IPC分类号： C04B35/50 , C01F17/00 , C01G29/00 , H01B1/06 , H01B1/08 , H01B13/00 , H01M8/02 , H01M8/12
CPC分类号： H01M8/126 , C04B35/50 , C04B35/62675 , C04B35/62685 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3244 , C04B2235/3298 , C04B2235/77 , C04B2235/85 , H01M8/1266 , H01M2300/0074 , H01M2300/0091 , Y02E60/521 , Y02E60/525 , Y02P70/56
摘要： PROBLEM TO BE SOLVED: To provide a method in which densifying and large area making sinter can be performed even at a low temperature sinter temperature such as an insite sinter process for large area making and cost reduction of a ceria-based composite electrolyte.SOLUTION: There are provided a ceria-based composition which comprises ceria or metal doped ceria, and bismuth oxide or metal doped bismuth oxide, and at least includes metal doped ceria and/or metal doped bismuth oxide, where the bismuth oxide or the metal doped bismuth oxide of 10 wt.% or more and less than 50 wt.% is included in the total composition, a ceria-based composite electrolyte powder, and a sinter method of the same, and a sinter body of the same. Even at low temperature for example at most 1000°C far from an existing sinter temperature for example 1400°C, a high composite sinter density can be secured, and ionic conductivity of the composite electrolyte can be raised.
摘要翻译：要解决的问题：为了提供即使在低温烧结温度下也可进行致密化和大面积烧结的方法，例如用于大面积制造的绝缘烧结工艺和二氧化铈复合电解质的成本降低。解决方案：提供了一种二氧化铈基组合物，其包含二氧化铈或金属掺杂的二氧化铈，以及氧化铋或金属掺杂的氧化铋，并且至少包括掺杂金属的氧化铈和/或金属掺杂的氧化铋，其中氧化铋或金属掺杂的氧化铋 10重量％以上且小于50重量％的二氧化铈复合电解质粉末及其烧结体及其烧结体。即使在低于现有的烧结温度（例如1400℃）的低温下，例如至多1000℃，可以确保高的复合烧结密度，并且可以提高复合电解质的离子导电性。

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