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    • 2. 发明专利
    • ELECTRODIALYSIS TANK FOR OPERATION AT HIGH TEMPERATURE
    • JPS6054713A
    • 1985-03-29
    • JP16046483
    • 1983-09-02
    • HITACHI LTDBABCOCK HITACHI KK
    • KURODA OSAMUTAKAHASHI SANKICHIKOIKE SEIJI
    • B01D61/50
    • PURPOSE:To provide the titled dialysis tank protected from deformation of membrane and leakage of liquid by operation at high temp. by interposing a film-shaped construction having higher rigidity than an ion exchange membrane of the device and superior heat resistance between the ion exchange membrane and frames of the dialysis chamber to construct a laminated construction. CONSTITUTION:A dialysis chamber of an electrodialysis tank is constructed by piling successively a cation exchange membrane 1, a film-shaped construction 20 made of a material having higher rigidity than ion exchange membranes 1, 2 and having superior heat resistance from which the parts corresponding to the communicating holes 5, 5', 6, 6' of a dialysis chamber frame 3 and the part corresponding to the dialysis chamber 4 are removed, a dialysis chamber 4 provided with a spacer 8 at its central removed part 4, a frame 3 of the dialysis chamber provided with liquid passages 7, 7' having a distributor 9 communicating the dialysis chamber to the communicating holes 6, 6', etc., another film-shaped construction 20 similar to the above described one, and an anion exchange membrane. By the above described constitution, deformation of membrane at high temp. operation, particularly, liquid at the liquid passage 7, 7' is prevented, and an electrodialysis tank exhibiting superior performance is obtd.
    • 4. 发明专利
    • OPERATION OF ELECTRODIALYSIS APPARATUS
    • JPH01218606A
    • 1989-08-31
    • JP4208488
    • 1988-02-26
    • HITACHI LTDBABCOCK HITACHI KK
    • KURODA OSAMUEBARA KATSUYATAKAHASHI SANKICHIKOIKE SEIJI
    • B01D61/54
    • PURPOSE:To keep electrode liquid always acidic as a whole so as to prevent deposition of scales by mixing the rest of cathode liquid with the whole anode liquid of an electrodialysis cell and circulating the mixture through both electrode chambers. CONSTITUTION:An electrode liquid in an electrode liquid circulation tank 6 is supplied to an anode chamber 3 equipped with an anode 2 and a cathode chamber 5 equipped with a cathode 4 of an electrodialysis apparatus 1. Part of cathode liquid is discharged out of the system through a valve 8. The rest of the cathode liquid and the whole anode liquid out of the anode chamber 3 are returned to the electrode liquid circulation tank 6 through a line 11, and an amount of salt solution corresponding to the cathode liquid discharged out of the system is also supplied to the tank 6 through a line 12. The polarities the electrodes are changed after a certain duration of the aforementioned condition. When the polarity is changed, the cathode liquid is discharged by setting a valve 9 open. It is possible, therefore, to prevent scale deposition in the electrode chambers of the electrodialysis cell without using any acid at all.
    • 5. 发明专利
    • BRINE DESALTING OPERATION IN SOLAR ENERGY POWER GENERATION ELECTRODIALYTIC APPARATUS
    • JPS60168504A
    • 1985-09-02
    • JP2472184
    • 1984-02-13
    • HITACHI LTDBABCOCK HITACHI KK
    • KURODA OSAMUKOSEKI YASUOTAKAHASHI SANKICHIKOIKE SEIJI
    • C02F1/469B01D61/46C02F1/46H01L31/00
    • PURPOSE:To utilize the varied output of a solar cell in the operation of an electrodialytic apparatus with high efficiency, by providing a fresh water tank and an intermediate concn. tank and desalting brine in the intermediate concn. tank, when the output of the solar cell is high, so as to reach an intermediate concn. while supplying brine to the intermediate concn. tank corresponding to quantity of solar radiation to regulate a salt concn. CONSTITUTION:Water with an intermediate concn., which was desalted to the intermediate concn. in the previous day, is transferred to a fresh water tank 6 in an amount corresponding to that of fresh water formed per a day and, when the output of a solar cell is low over a predetermined time from sunrise, the water in said fresh water tank 6 is transferred to an electrodialytic apparatus 2 and desalted to obtain fresh water. Next, water with an intermediate concn. in an intermediate concn. tank 5 is recirculated to the electrodialytic apparatus 2 and desalted. Because the output of the cell shows increase inclination until the southing time of the sun, a valve 11 is opened and raw water is supplied to the intermediate concn. tank 5 and conditioned so as to enhance a salt concn. Because the salt concn. is lowered with the lowering in the output of the cell from the southing time to sunset and the max. output condition of the cell is formed automatically, water with an intermediate concn. desalted in the fresh water tank 6 in the next day is obtained.
    • 8. 发明专利
    • Electrodialysis device
    • 电子装置
    • JPS59130504A
    • 1984-07-27
    • JP475883
    • 1983-01-14
    • Babcock Hitachi KkHitachi Ltd
    • KURODA OSAMUKOIKE SEIJITAKAHASHI SANKICHI
    • B01D61/46B01D61/48B01D61/50B01D61/54
    • Y02A20/134
    • PURPOSE: To perform electrodialysis always near the critical current density even if the salt concn. in a desalting chamber changes by providing electrodes for detecting the voltage between ion exchange membrane groups in the operating stage of the respective electrode chambers near the ion exchange membranes of the respective electrode chambers and controlling an impressed voltage.
      CONSTITUTION: An electrodialysis device 1 is formed with desalting chambers 4 and concentrating chambers 5, wherein anion exchange membranes 2 and cation exchange membranes 3 are alternately arranged. Electrode chambers 9a in which an anolyte 8a is kept flowing and electrode chambers 9b in which a catholyte 8b is kept flowing are provided, and detecting electrodes 11a, 11b consisting of platinum wires for detecting the potential difference between the ion exchange membrane groups during operation are provided. The detected voltage is conducted to a comparator 13 which is preliminarily inputted with a predetermined reference voltage 12. Said comparator inputs the voltage proportional to the difference between both voltages to a control device 14. Said device controls the voltage outputted from a thyristor rectifier 15 applying the voltage between anode electrodes 10b and 10a from the device 14 whereby electrodialysis is accomplished.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:即使盐浓度高于临界电流密度,也要进行电渗析。 在脱盐室中,通过设置用于检测各个电极室的离子交换膜附近的各个电极室的操作阶段的离子交换膜组之间的电压的电极,并控制外加电压来改变。 构成:电渗析装置1形成有脱盐室4和浓缩室5,其中阴离子交换膜2和阳离子交换膜3交替排列。 设置有阳极电解液8a保持流动的电极室9a和阴极电解液8b保持流动的电极室9b,并且由操作中检测离子交换膜组之间的电位差的铂线构成的检测电极11a,11b是 提供。 检测到的电压被传导到预先输入了预定参考电压12的比较器13.所述比较器将与两个电压之间的差成比例的电压输入到控制装置14.所述装置控制从晶闸管整流器15输出的电压 来自装置14的阳极电极10b和10a之间的电压,从而实现电渗析。