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    • 6. 发明公开
    • NOVEL EPOXY-URETHANE COMPOUNDS AND THEIR THERMOSETTING POLYMERS
    • EP4223821A1
    • 2023-08-09
    • EP22154900.9
    • 2022-02-03
    • Covestro LLC
    • The designation of the inventor has not yet been filed
    • C08G18/32C07C263/00C07C273/00C08G18/64C08G18/71C09D163/00C08G18/28C08G18/73C08G18/78
    • Provided is an epoxy-functional polyurethane comprising a reaction product of (A) a polyisocyanate; and (B) a compound, HX-Y-(Z) n wherein, X is O, N, or S, Y is a linear or branched C 1 -C 15 alkyl group, and Z is -CH=CDE or Z is -F-O-G-CH=CDE, n is an integer from 1 to 3, wherein D and E independently are selected from H, a linear C 1 -C 5 alkyl group, and a branched C 1 -C 5 alkyl group, F and G independently are selected from H, linear or branched C 1 -C 15 alkyl groups, and wherein compound (B) comprises a vinyl group capable of being oxidized to a corresponding epoxy group. Also provided is a process for producing an epoxy-functional polyurethane, the process comprising (1) reacting (A) a polyisocyanate; and (B) a compound: HX-Y-(Z) n wherein, X is O, N, or S, Y is a linear or branched C 1 -C 15 alkyl group, and Z is -CH=CDE or Z is -F-O-G-CH=CDE, n is an integer from 1 to 3, wherein D and E independently are selected from H, a linear C 1 -C 5 alkyl group, and a branched C 1 -C 5 alkyl group, F and G independently are selected from H, linear or branched C 1 -C 15 alkyl groups, optionally, in the presence of a catalyst to form a vinyl-functional carbamate; (2) forming a mixture containing the vinyl-functional carbamate, a ketone, water, and a base; and (3) feeding an aqueous solution of oxone into the mixture to oxidize the vinyl-functional carbamate to the epoxy-functional polyurethane. The epoxy-functional polyurethanes of the invention may find use in or as coatings, adhesives, sealants, films, elastomers, castings, foams, and composites.