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    • 8. 发明授权
    • Procédé de cyclisation de l'acide orthobenzoylbenzoique
    • 环戊基苯甲酸环化方法
    • EP0127551B1
    • 1987-04-08
    • EP84420075.8
    • 1984-04-20
    • ELF ATOCHEM S.A.
    • Devic, Michel
    • C07C46/00C07C50/18
    • C07C51/42C07C51/487C07C65/34
    • 1. Process for cyclization of orthobenzoylbenzoic acid in which the anthraquinone formed sublimes, by heating orthobenzoylbenzoic acid in the presence of a super-active bleaching clay consisting of a clay of the bentonite type activated by treatment with an inorganic acid, washed with water so that it only contains 0.1% at most of acid, expressed as hydrochloric acid, and finally dried at a temperature equal at most to 120 degrees C, at a temperature of between 300 degrees C and 400 degrees C, characterized in that orthobenzoylbenzoic acid in the solid state and the super-active bleaching clay are brought into contact in the form of a mixture of solids arranged in a layer of thickness such that the anthraquinone formed and sublimed diffuses completely, or in the form of two superposed layers of solids, the super-active bleaching clay layer covering that of orthobenzoylbenzoic acid so that the anthraquinone formed and sublimed diffuses completely.
    • 1.通过在由无机酸处理活化的膨润土类型的粘土组成的超活性漂白粘土存在下加热邻苯甲酰苯甲酸,使蒽醌形成升华的环苯甲酰苯甲酸环化方法,用水洗涤,使得 它最多仅含有0.1%的酸,以盐酸表示,最后在温度为至多120℃的温度下在300℃至400℃的温度下干燥,其特征在于固体中的邻苯甲酰基苯甲酸 状态和超活性漂白粘土以固体层的形式混合形成接触,所述混合物的厚度使得形成和升华的蒽醌完全扩散,或以两个重叠的固体层的形式扩散, 活性漂白粘土层覆盖正苯甲酰基苯甲酸,使得形成和升华的蒽醌完全扩散。