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1. 发明公开

EP4223821A1 NOVEL EPOXY-URETHANE COMPOUNDS AND THEIR THERMOSETTING POLYMERS 审中-公开
公开(公告)号：EP4223821A1
公开(公告)日：2023-08-09
申请号：EP22154900.9
申请日：2022-02-03
申请人： Covestro LLC
发明人： The designation of the inventor has not yet been filed
IPC分类号： C08G18/32 , C07C263/00 , C07C273/00 , C08G18/64 , C08G18/71 , C09D163/00 , C08G18/28 , C08G18/73 , C08G18/78
摘要： Provided is an epoxy-functional polyurethane comprising a reaction product of (A) a polyisocyanate; and (B) a compound, HX-Y-(Z) n wherein, X is O, N, or S, Y is a linear or branched C 1 -C 15 alkyl group, and Z is -CH=CDE or Z is -F-O-G-CH=CDE, n is an integer from 1 to 3, wherein D and E independently are selected from H, a linear C 1 -C 5 alkyl group, and a branched C 1 -C 5 alkyl group, F and G independently are selected from H, linear or branched C 1 -C 15 alkyl groups, and wherein compound (B) comprises a vinyl group capable of being oxidized to a corresponding epoxy group. Also provided is a process for producing an epoxy-functional polyurethane, the process comprising (1) reacting (A) a polyisocyanate; and (B) a compound: HX-Y-(Z) n wherein, X is O, N, or S, Y is a linear or branched C 1 -C 15 alkyl group, and Z is -CH=CDE or Z is -F-O-G-CH=CDE, n is an integer from 1 to 3, wherein D and E independently are selected from H, a linear C 1 -C 5 alkyl group, and a branched C 1 -C 5 alkyl group, F and G independently are selected from H, linear or branched C 1 -C 15 alkyl groups, optionally, in the presence of a catalyst to form a vinyl-functional carbamate; (2) forming a mixture containing the vinyl-functional carbamate, a ketone, water, and a base; and (3) feeding an aqueous solution of oxone into the mixture to oxidize the vinyl-functional carbamate to the epoxy-functional polyurethane. The epoxy-functional polyurethanes of the invention may find use in or as coatings, adhesives, sealants, films, elastomers, castings, foams, and composites.

2. 发明公开

EP4223820A1 GLYCIDYL UREA COMPOUNDS AND THEIR THERMOSETTING POLYMERS 审中-公开
公开(公告)号：EP4223820A1
公开(公告)日：2023-08-09
申请号：EP22154898.5
申请日：2022-02-03
申请人： Covestro LLC
发明人： The designation of the inventor has not yet been filed
IPC分类号： C08G18/32 , C07C263/00 , C07C273/00 , C08G18/64 , C08G18/71 , C09D163/00
摘要： Provided is a glycidyl urea comprising an oxidized allyl-functional urea, wherein the allyl-functional urea comprises a reaction product of a polyisocyanate and a compound containing one or more amine groups and one or more allyl groups. Also provided is a process for producing a glycidyl urea, the process comprising 1) reacting a polyisocyanate with a compound containing one or more amine groups and one or more allyl groups, optionally, in the presence of a catalyst, to form an allyl-functional urea; and 2) oxidizing the allyl-functional urea to a glycidyl urea, the oxidizing comprising a) forming a mixture of the allyl-functional urea, water, and a base, optionally in the presence of a solvent, and b) feeding an aqueous solution of an oxidant into the mixture formed in step a) to form the glycidyl urea. The glycidyl urea may be cured with a curing agent to form a thermoset polymer, and the glycidyl urea may be self-crosslinked to form a crosslinked thermoset polymer. The thermoset polymers produced from the glycidyl urea of the invention may find use in or as coatings, adhesives, sealants, films, elastomers, castings, foams, and composites.

3. 发明授权

EP2265656B1 POLYISOCYANURATES 有权
标题翻译：聚异氰
公开(公告)号：EP2265656B1
公开(公告)日：2016-10-26
申请号：EP09735777.6
申请日：2009-04-09
申请人： Agency for Science, Technology And Research
发明人： ZHANG, Yugen , YING, Jackie Y. , BINTE RIDUAN, Siti Nurhanna
IPC分类号： C08G18/71 , C07C263/00 , C07C265/00 , C08G18/02
CPC分类号： C08G18/022 , B01J23/42 , B01J23/44 , B01J31/063 , B01J35/10 , C08G18/71 , C08G18/76 , C08G18/7614 , C08G18/7671 , C08G18/77

4. 发明授权

EP2603319B1 VERFAHREN ZUR HERSTELLUNG VON URETHANEN 失效转让
标题翻译：用于生产聚氨酯
公开(公告)号：EP2603319B1
公开(公告)日：2014-10-22
申请号：EP11746221.8
申请日：2011-08-09
申请人： Bayer Intellectual Property GmbH
发明人： GÄRTNER, Felix , JACOB, Andreas , SUNDERMEYER, Jörg , KLEIN, Stephan , WERSHOFEN, Stefan
IPC分类号： B01J31/22 , C07C263/00
CPC分类号： C07C263/00 , B01J31/2243 , B01J2231/70 , B01J2531/0241 , B01J2531/16 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C245/08 , C07C251/24 , C07C269/04 , C07D213/30 , C07D215/26 , C07C271/28

5. 发明公开

EP2265656A4 POLYISOCYANURATES 有权
标题翻译：聚异氰
公开(公告)号：EP2265656A4
公开(公告)日：2014-07-16
申请号：EP09735777
申请日：2009-04-09
申请人： AGENCY SCIENCE TECH & RES
发明人： ZHANG YUGEN , YING JACKIE Y , BINTE RIDUAN SITI NURHANNA
IPC分类号： C08G18/71 , C07C263/00 , C07C265/00 , C08G18/02
CPC分类号： C08G18/022 , B01J23/42 , B01J23/44 , B01J31/063 , B01J35/10 , C08G18/71 , C08G18/76 , C08G18/7614 , C08G18/7671 , C08G18/77

6. 发明公开

EP1501790A4 NOVEL SODIUM CHANNEL BLOCKERS 审中-公开
标题翻译：新的钠通道阻滞剂
公开(公告)号：EP1501790A4
公开(公告)日：2006-03-29
申请号：EP03721784
申请日：2003-04-18
申请人： UNIV VIRGINIA
发明人： BROWN MILTON L
IPC分类号： A61K31/16 , A61K31/4015 , A61K31/4166 , A61K31/421 , A61K45/00 , A61P35/00 , A61P43/00 , C07C219/08 , C07C235/02 , C07C235/06 , C07C235/34 , C07C237/04 , C07C237/06 , C07C237/20 , C07C275/22 , C07D233/74 , C07D233/76 , C07D233/78 , C07D235/02 , C07C263/00 , A61K31/415
CPC分类号： C07D235/02 , A61K31/4015 , A61K31/4166 , A61K31/421 , C07C235/34 , C07C237/04 , C07D233/74 , C07D233/76 , C07D233/78

7. 发明授权

EP0410169B1 Verfahren zur Herstellung unsymmetrisch substituierter Harnstoffe, Carbamate, Thiocarbamate und substituierter Isocyanate 有权转让
标题翻译：一种用于不对称取代的脲，氨基甲酸酯，硫代氨基甲酸酯和取代的异氰酸酯的制备方法。
公开(公告)号：EP0410169B1
公开(公告)日：1994-12-14
申请号：EP90112743.1
申请日：1990-07-04
申请人： Chemie Linz GmbH
发明人： Müllner, Martin, Dipl.-Ing. Dr. , Stern, Gerhard, Dipl.-Ing. Dr. , Erich, Schulz , Rössler, Markus
IPC分类号： C07C273/18 , C07C275/06 , C07C269/00 , C07C263/00 , C07C333/04 , C07C265/04
CPC分类号： C07C273/1818 , C07C333/04

8. 发明公开

EP0324215A1 Process for separating a mixture comprising 2,6-toluene diisocyanate and 2,4-toluene diisocyanate 失效
标题翻译：一种用于由2,6-甲苯二异氰酸酯和2,4-甲苯混合物组成的组中的分离过程。
公开(公告)号：EP0324215A1
公开(公告)日：1989-07-19
申请号：EP88300251.1
申请日：1988-01-13
申请人： UOP
发明人： Zinnen, Hermann Albert
IPC分类号： C07C265/08 , C07C263/00
CPC分类号： C07C263/20 , C07C265/14
摘要： The toluene diisocyanate isomers in a mixture comprising 2,6-toluene diisocyanate and 2,4-toluene diisocyanate can be separated by contacting the mixture with an adsorbent comprising a Y-type zeolite cation exchanged with a potassium cation, thereby selectively adsorbing the 2,6-toluene diisocyanate, or with an adsorbent comprising a Y-type zeolite, cation exchanged with a cation selected from Na, Ca, Li, Mg and mixtures thereof, thereby selectively adsorbing said 2,4-toluene diisocyanate. The remainder of the feed mixture is removed from the adsorbent and the adsorbed toluene diisocyanate isomer is recovered by desorption with toluene.
摘要翻译：在2,6-甲苯二异氰酸，其包括和2,4-甲苯二异氰酸的混合物中二异氰酸甲苯异构体可以通过接触与吸附剂包括用钾阳离子交换的Y型沸石的阳离子，从而选择性地吸附2的混合物中分离出来， 6-甲苯二异氰酸，或与2,4-甲苯到吸附剂，其包含Y型沸石，阳离子与钠，钙，锂，镁以及它们的混合物中选择的阳离子进行交换，从而选择性地吸附。所述二异氰酸酯。所述进料混合物的其余部分被从吸附剂中除去和甲苯二异氰酸吸附异构体是通过用甲苯解吸回收。

9. 发明公开

EP4223823A1 NOVEL POLYURETHANES HAVING PENDANT EPOXY GROUPS AND THERMOSETS THEREOF 审中-公开
公开(公告)号：EP4223823A1
公开(公告)日：2023-08-09
申请号：EP22154902.5
申请日：2022-02-03
申请人： Covestro LLC
发明人： The designation of the inventor has not yet been filed
IPC分类号： C08G18/32 , C07C263/00 , C07C273/00 , C08G18/64 , C08G18/71 , C09D163/00 , C08G18/28 , C08G18/73 , C08G18/78 , C08G18/24
摘要： Provided is a polyurethane with pendant epoxy groups according to formula (I):

wherein, R 1 is a linear or branched alkyl group, an allyl group, a glycidyl group, an aromatic group, a cycloaliphatic group, an alkyl-aromatic group, or mixtures thereof, R 2 is a linear aliphatic, a cycloaliphatic, an aromatic, or an alkyl aromatic group, R 3 is a hydrogen, a methyl, an ethyl, or other higher alkyl, an allyl oxy, a glycidyl oxy, an allyl oxy methyl, or a glycidyl oxy methyl group, and R 4 is an allyl oxy, a glycidyl oxy, an allyl oxy methyl, or a glycidyl oxy methyl group. The invention further provides a process for producing these polyurethanes with pendant epoxy groups, the process comprising (1) reacting a diisocyanate with a compound containing one or more allyl groups and two hydroxyl groups, to form a linear polyurethane having pendant allyl-functional groups, and (2) oxidizing the allyl groups to produce the polyurethane with pendant epoxy groups. The polyurethanes of the present invention may be included in coatings, adhesives, sealants, films, elastomers, castings, foams, and composites.

10. 发明公开

EP3744812A1 VERFAHREN ZUR VERWERTUNG VON POLYURETHAN MATERIAL ABFALL ZUR HERSTELLUNG VON CHEMIKALISCHEN ROHSTOFFEN FÜR DIE HERSTELLUNG VON ISOCYANATEN UND POLYURETHANEN 有权
公开(公告)号：EP3744812A1
公开(公告)日：2020-12-02
申请号：EP19176668.2
申请日：2019-05-27
申请人： Covestro Deutschland AG
发明人： BULAN, Andreas , WEBER, Rainer Dr.
IPC分类号： C10B53/07 , C25B1/00 , C08G18/00 , C07C263/00 , C07C263/10
摘要： Es wird ein Verfahren zur Verwertung von Polyurethan Material Abfall (18 a) zur Herstellung von chemikalischen Rohstoffen für die Herstellung von Isocyanaten (10 a) und anschließend Polyurethanen (16 a) beschrieben, bei dem ausgehend von Polyurethan Material Abfall (18 a) durch Pyrolyse (1) Kohlendioxid (1a) und Kohlenwasserstoffe (1c) erzeugt wird, das Kohlendioxid (1a; 4a) durch Elektrolyse (5) zu Kohlenmonoxid (7b) und ggf. Wasserstoff (7a) umgesetzt wird, erhaltenes Kohlenmonoxid (7b; 7c) über Phosgen zu Isocyanat (10 a) umgesetzt wird und das Isocyanat (10 a) zu neuem Polyurethan Material (16 a) weiterverarbeitet werden kann.

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