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    • 7. 发明公开
    • Igniting substance mainly for industrial detonators with the explosion delay time up to 9000 ms after ignition, methods of its production, and industrial electric detonator and industrial non-electric detonator
    • 点火后点火物质主要为工业雷管,爆炸延迟时间达9000毫秒,其生产方法及工业电雷管和工业无电雷管
    • EP2733133A3
    • 2017-08-02
    • EP13466028.1
    • 2013-11-11
    • Austin Detonator s.r.o.Univerzita Pardubice
    • Matyás, RobertMusil, Tomás
    • C06B41/00C06C7/00
    • C06B41/00C06C7/00
    • An igniting substance mainly for detonators made of a metallic salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine selected from a group of salts containing silver salt, copper(I) salt and copper(II) salt, with the following skeletal formula

      where M is a metal selected from a group comprising silver and copper:
      M = Ag, m = 1, n = 1, x = 1 for silver salt,
      M = Cu, m = 1, n = 2, x = 2 for copper(I) salt,
      M = Cu, m = 2, n = 2, x = 1 for copper(II) salt.
      Production method of silver salt of 4,6-diazido-N-nitro-1,3,5,-triazine-2-amine, when the heated aqueous solution of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine is mixed with the aqueous solution of silver nitrate AgNO 3 and, while stirring vigorously, the silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine is precipitated and then filtered off and dried at laboratory temperature.
      Production method of silver salt of 4,6-diazido-N-nitro-1,3,5,-triazine-2-amine, when the heated aqueous solution of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine is mixed with the aqueous solution of silver nitrate AgNO 3 and, while stirring vigorously, the silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine is precipitated and then filtered off and dried at laboratory temperature.
      A non-electric industrial detonator which has a casing in the form of a cup (1) with an inserted detonation tube (19) and a space (11) for the secondary explosive at the bottom of the cup (1) closed with a lid (15), where the space is closed at the top with a time-delay device (12) with a cylindrical case containing delay-action composition (14) and with the primary explosive (13) below it, above the space (11) for the secondary explosive as the igniting substance which is metallic salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine selected from a group of salts containing silver salt, copper(I) salt and copper(II) salt.
      An electric industrial detonator which has a casing in the form of a cup (2) with an inserted electric fuse head (25) provided with supply cables (26) where in the casing there is space (21) at least for the secondary explosive and for the time-delay device (14) with a cylindrical case containing delay-action composition (14) and with the primary explosive (13) below it, above the space (11) for the secondary explosive where the primary explosive (13) as the igniting substance is metallic salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine selected from a group of salts containing silver salt, copper(I) salt and copper(II) salt.
    • 主要用于由选自含银盐,铜(I)盐和铜的一组盐的4,6-二叠氮基-N-硝基-1,3,5-三嗪-2-胺的金属盐制成的引燃剂的引燃物质 (II)盐,其具有以下骨架式,其中M是选自包括银和铜的金属:M = Ag,m = 1,n = 1,银盐的x = 1,M = Cu,m = 1 ,铜(I)盐的n = 2,x = 2,铜(II)盐的M = Cu,m = 2,n = 2,x = 1。 4,6-二叠氮基-N-硝基-1,3,5, - 三嗪-2-胺的银盐的制造方法,是将4,6-二叠氮基-N-硝基-1,3,5 - 三嗪-2-胺与硝酸银AgNO 3的水溶液混合,剧烈搅拌下,沉淀出4,6-二叠氮基-N-硝基-1,3,5-三嗪-2-胺的银盐, 然后过滤并在实验室温度下干燥。 4,6-二叠氮基-N-硝基-1,3,5, - 三嗪-2-胺的银盐的制造方法,是将4,6-二叠氮基-N-硝基-1,3,5 - 三嗪-2-胺与硝酸银AgNO 3的水溶液混合,剧烈搅拌下,沉淀出4,6-二叠氮基-N-硝基-1,3,5-三嗪-2-胺的银盐, 然后过滤并在实验室温度下干燥。 一种非电动工业雷管,其具有带有插入的爆震管(19)的杯形式的壳体(1)和用于在杯子(1)的底部处用于二次炸药的空间(11),该空间用盖子 (15),其中空间在顶部用具有包含延迟作用组合物(14)的圆柱形壳体和在其下方的主炸药(13)的时间延迟装置(12)在空间(11)上方封闭, 作为选自含有银盐,铜(I)盐和铜盐的盐的4,6-二叠氮基-N-硝基-1,3,5-三嗪-2-胺的金属盐作为点火物质的二次炸药 铜(II)盐。 一种电子工业雷管,其具有带有插入式电熔丝头(25)的杯形(2)形式的外壳,该外壳设有供电电缆(26),其中壳体内至少有用于二次炸药的空间(21) 对于具有包含延迟作用组合物(14)的圆柱形壳体和在其下方的主炸药(13)的时间延迟装置(14),在主炸药(13)为 引燃物质是选自含银盐,铜(I)盐和铜(II)盐的盐的4,6-二叠氮基-N-硝基-1,3,5-三嗪-2-胺的金属盐。
    • 10. 发明公开
    • Pyrotechnic millisecond delay charge for industrial detonators with delay time of explosion of 25 to 1,000 ms from initiation, the way of manufacture of the delay charge, and electric and non-electric detonator
    • 烟火毫秒延迟收费Industriezündkapseln与爆炸的延迟时间从起始25-1000毫秒,产生延迟的充电和非电雷管的方法
    • EP2589582A3
    • 2016-01-06
    • EP12466011.9
    • 2012-06-26
    • Austin Detonator s.r.o.
    • Valenta, PavelHnat, Igor
    • C06C5/06C06C7/00
    • C06C5/06C06C7/00
    • Pyrotechnic delay charge that contains FeSiZr as combustible and Bi 2 O 3 as oxidizer in proportion 50 ± 15 wt. % FeSiZr and 50 ± 15 wt. % Bi 2 O 3 . FeSiZr is an alloy of dominant elements Si, Zr, Fe and Ti with content of trace impurities originating from aluminosillicates. The limit representation of dominant elements in FeSiZr is as follows: Si at least 30 wt. %, Zr at least 10 wt. %, Fe at the most 25 wt. %, Ti at least 1 wt. %. The controller of combustion speed is the additive TiO 2 in the amount of up to 5 wt. % of the total weight.
      The way of manufacture of the pyrotechnic millisecond delay charge in which FeSiZr with limit representation of dominant elements Si at least 30 wt. %, Zr at least 10 wt. %, Fe at the most 25 wt. % and Ti at least 1 wt. %, are prepared in the physical process of grinding to the particle size in the range of 1-10 µm, Bi 2 O 3 to the particle size in the range of 1- 10 µm, whereupon these two components in proportion 50 ± 10 wt. % FeSiZr and 50 ± 10 wt. % Bi 2 O 3 are mechanically homogenized nad pelletized with pressure of 255 MPa, and after that are crushed to grading of 0.2 - 0.8 mm grain size. Finally, the charge is pressed into the delay tube with pressure of 280 MPa with column height of 5 up to 40 mm.
      Industrial non-electric detonator has an enclosure in shape of a shell (1) with inserted detonation tube. In the enclosure there is created a space at least for the primary explosive and for the delay charge. The shell (1) closed at the bottom side has in its bottom part created a space (11) for the secondary explosive, which is from above closed with delay tube (12), in the cylindrical box of which there is placed primary explosive (13) and delay charge (14) above it. Over the delay charge (12) in shell (1) is inserted a sleeve (15) with amplifying charge (16) closed with cover (17), and inserted from the upper part into shell (1) there is the detonation tube (19), fitted with insulation (18) against the enclosure of the shell (1).
      Industrial electric detonator has in shell (2) the fusehead (25) inserted, with in-lead wires (26) fitted with insulation (27) against enclosure of the shell (2).
    • 烟火延迟电荷确实FeSiZr含有作为可燃性和Bi 2 O 3作为氧化剂的比例50%±15%(重量)和FeSiZr 50±15重量的Bi 2 O 3。 FeSiZr是占主导地位的元素Si,锆,Fe和Ti与微量杂质从aluminosillicates始发的含量的合金。 在FeSiZr主导元件的极限表示如下:...的Si的至少30%重量%的Zr至少10重量%,Fe至多25重量%,钛的至少1重量%。 燃烧速度的控制器是在至多5%(重量)的总重量的量的添加剂的TiO 2。 制造烟火毫秒延迟的电荷的方式,其中主导元素Si的至少30%重量,Zr的至少10%(重量),铁至多25重量%和Ti的至少1重量的FeSiZr withLimit表示。 %,在研磨至1-10微米的范围内的粒径的物理过程来制备,的Bi 2 O 3的粒径在1- 10微米的范围内,其中,当在比例这两个组件50±10重量 。FeSiZr%和50±10重量%的Bi 2 O 3均化机械NAD 255兆帕的压力造粒,并做后粉碎至0.2分级。 - 0.8毫米晶粒尺寸。 最后,批料被压入在用由5达40毫米柱高度280兆帕的压力延迟管。 工业非电雷管具有在外壳(1)具有插入爆震管的形状到外壳。 在外壳有创建至少一个空间用于初级炸药和用于延迟的电荷。 壳(1)在底部封闭侧已在其底部部分创建的二次炸药的空间(11),所有这些是从上方与延迟管(12)关闭时,(其中的圆筒形盒上放置初级炸药 13)和延迟电荷(14)在它上面。 在壳上的延迟电荷(12)套筒(1)被插入与盖(17)一(15)与放大电荷(16)闭合,并且从上部到壳插入(1)存在爆震管(19 ),装上绝缘(18)抵靠壳体(1)的外壳。 工业电雷管在壳(2)插入时,用安装有绝缘(27),引线(26)的引信头(25)抵靠壳体的外壳(2)。