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1. 发明授权

EP1268056B1 A PROCESS FOR PRODUCING HYDROCARBONS, AND A CATALYST SUITABLE FOR USE IN THE PROCESS 有权
标题翻译：用于生产碳氢化合物和在此过程中适当的催化剂
公开(公告)号：EP1268056B1
公开(公告)日：2004-08-18
申请号：EP01933809.4
申请日：2001-04-06
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： VAN DEN BRINK, Peter, John , GEERLINGS, Jacobus, Johannes, Cornelis , HUISMAN, Hans, Michiel
IPC分类号： B01J23/74 , B01J23/76 , B01J23/84 , B01J23/847 , C07C1/04
CPC分类号： B01J23/8892 , B01J23/8472 , B01J23/889 , B01J27/16 , C07C1/0435 , C07C2521/06 , C07C2523/22 , C07C2523/34 , C07C2523/36 , C07C2523/46 , C07C2523/75 , C07C2527/167
摘要： The invention relates to a novel process for producing hydrocarbons, which process comprises contacting a mixture of carbon monoxide and hydrogen at elevated temperature and pressure with a catalyst comprising a Group VIII metal supported on a carrier, which Group VIII metal is present at least partly in metallic form, and which catalyst further comprises inorganic phosphate in a quantity of at least 0.05 %w, calculated as elemental phosphorus relative to the weight of the catalyst; a novel catalysts which comprises, supported on a carrier, a Group VIII metal selected from nickel, cobalt, iron and ruthenium, and a further metal selected from manganese, vanadium, zirconium and rhenium, which catalyst further comprises inorganic phosphate in a quantity of at least 0.05 %w, calculated as elemental phosphorus relative to the weight of the catalyst; and a process for preparing the novel catalyst composition.

2. 发明公开

EP0905122A3 Verfahren zur Herstellung von Aminen 审中-公开
标题翻译：一种用于胺的制备方法
公开(公告)号：EP0905122A3
公开(公告)日：2001-09-05
申请号：EP98118029.2
申请日：1998-09-23
申请人： BASF AKTIENGESELLSCHAFT
发明人： Wulff-Döring, Joachim, Dr. , Hesse, Michael, Dr. , Melder, Johann-Peter, Dr. , Buskens, Philipp, Dr. , Voit, Guido, Dr. , Funke, Frank, Dr.
IPC分类号： C07C209/16 , B01J23/74 , B01J23/84
CPC分类号： C07D295/023 , B01J23/755 , B01J23/8892 , B01J23/8898 , C07C209/16 , Y02P20/582
摘要： Herstellung von Aminen aus primären oder sekundären Alkoholen und Stickstoffverbindungen, ausgewählt aus der Gruppe Ammoniak, primäre und sekundäre Amine, bei Temperaturen von 80 bis 250 °C und Drücken von 0,1 bis 40 MPa mit Wasserstoff in Gegenwart eines Katalysators enthaltend Zirkonium, Kupfer und Nickel, dadurch gekennzeichnet, daß die katalytisch aktive Masse 20 bis 85 Gew.-% sauerstoffhaltige Verbindungen des Zirkoniums, berechnet als ZrO 2 , 1 bis 30 Gew.-% sauerstoffhaltige Verbindungen des Kupfers, berechnet als CuO, 14 bis 70 Gew.-% sauerstoffhaltige Verbindungen des Nickels, berechnet als NiO, wobei das Molverhältnis von Nickel zu Kupfer größer 1 ist, 0 bis 10 Gew.-% sauerstoffhaltige Verbindungen des Aluminiums und/oder Mangans, berechnet als Al 2 O 3 bzw. MnO 2 , und keine sauerstoffhaltigen Verbindungen des Cobalts oder Molybdäns enthält.

3. 发明公开

EP0905122A2 Verfahren zur Herstellung von Aminen 审中-公开
公开(公告)号：EP0905122A2
公开(公告)日：1999-03-31
申请号：EP98118029.2
申请日：1998-09-23
申请人： BASF AKTIENGESELLSCHAFT
发明人： Wulff-Döring, Joachim, Dr. , Hesse, Michael, Dr. , Melder, Johann-Peter, Dr. , Buskens, Philipp, Dr. , Voit, Guido, Dr. , Funke, Frank, Dr.
IPC分类号： C07C209/16 , B01J23/74 , B01J23/84
CPC分类号： C07D295/023 , B01J23/755 , B01J23/8892 , B01J23/8898 , C07C209/16 , Y02P20/582
摘要： Herstellung von Aminen aus primären oder sekundären Alkoholen und Stickstoffverbindungen, ausgewählt aus der Gruppe Ammoniak, primäre und sekundäre Amine, bei Temperaturen von 80 bis 250 °C und Drücken von 0,1 bis 40 MPa mit Wasserstoff in Gegenwart eines Katalysators enthaltend Zirkonium, Kupfer und Nickel, dadurch gekennzeichnet, daß die katalytisch aktive Masse

20 bis 85 Gew.-% sauerstoffhaltige Verbindungen des Zirkoniums, berechnet als ZrO 2 ,
1 bis 30 Gew.-% sauerstoffhaltige Verbindungen des Kupfers, berechnet als CuO,
14 bis 70 Gew.-% sauerstoffhaltige Verbindungen des Nickels, berechnet als NiO, wobei das Molverhältnis von Nickel zu Kupfer größer 1 ist,
0 bis 10 Gew.-% sauerstoffhaltige Verbindungen des Aluminiums und/oder Mangans, berechnet als Al 2 O 3 bzw. MnO 2 ,
und keine sauerstoffhaltigen Verbindungen des Cobalts oder Molybdäns enthält.
摘要翻译：通过含有锆，铜，镍和任选的铝和/或锰的含氧化合物的催化剂，可以从醇，氮化合物和氢气中制备胺。胺的制备涉及使伯或仲醇，选自氨和伯胺或仲胺的氮化合物与至少含有锆，铜和镍的催化剂在80-250℃和0.1-40MPa的氢气反应。具体地说，催化活性物质包含Zr（20-85wt。％，ZrO2），Cu（1-30wt％，CuO），Ni（14-70wt。％，NiO）和任选地铝和/或镁（0-10重量％，作为Al 2 O 3和/或MnO 2）。 Ni / Cu的摩尔比≥1，催化剂不含钴或钼的氧化物。还包括形成的催化剂的独立权利要求。

4. 发明授权

EP0586599B1 HYDROGENATION CATALYST, PROCESS FOR PREPARING AND PROCESS OF USING SAID CATALYST 失效
标题翻译：氢化方法为催化剂的使用制备及方法
公开(公告)号：EP0586599B1
公开(公告)日：1997-05-28
申请号：EP92913950.9
申请日：1992-04-16
申请人： ENGELHARD CORPORATION
发明人： THAKUR, Deepak, S. , PALKA, Eugene , SULLIVAN, Thomas, J. , NEBESH, Eugene , ROBERTS, Brian, D.
IPC分类号： B01J37/03 , B01J35/10 , B01J23/85 , B01J23/84 , C07C29/141 , C07C29/145 , C07C29/149
CPC分类号： C07C51/36 , B01J23/847 , B01J23/8472 , B01J23/85 , B01J23/868 , B01J23/8892 , B01J35/0026 , B01J35/023 , B01J35/1014 , B01J35/108 , B01J37/03 , C07C29/141 , C07C29/145 , C07C29/149 , C07C31/125
摘要： Catalyst in powdered form comprising a major amount of the oxides of a first metal selected from copper or zinc, a second metal selected from chromium, molybdenum, tungsten and vanadium, and optionally, a minor amount of the oxide of a promoter metal. The average particle diameter is from 6 to 20 microns and the particle surface area is from 20 to 70 m2/g. Process for preparing said catalyst which comprises the steps of: (A) adding to a first vessel, (1) a first aqueous solution comprising a copper or zinc salt, and (2) a second aqueous solution comprising a soluble base, or (3) a third aqueous solution comprising a soluble salt of at least one second metal, (B) advancing at least a portion of the aqueous slurry from the first vessel to a second vessel; (C) recovering the solids from the second vessel; and (D) calcining the recovered solids. Catalysts of the invention are useful in both fixed bed and slurry phase reactions for hydrogenating aldehydes, ketones, carboxylic acids and carboxylic acid esters.

5. 发明授权

EP0510493B1 Process for producing N-alkyl-N-methylamine or N-alkenyl-N-methylamine 失效
标题翻译：一种用于制备N-烷基-N-甲胺或N-链烯基-N-甲胺过程
公开(公告)号：EP0510493B1
公开(公告)日：1996-02-21
申请号：EP92106429.1
申请日：1992-04-14
申请人： KAO CORPORATION
发明人： Abe, Hiroshi , Taniguchi, Hideki , Nishimoto, Yoshifumi , Sotoya, Kohshiro
IPC分类号： C07C209/16 , B01J23/80 , B01J23/76 , B01J23/84 , B01J23/89 , C07C211/08
CPC分类号： B01J29/068 , C07C209/16

6. 发明授权

EP0498976B1 Method of preparation of a cobalt-rhenium catalysts for hydrocarbon synthesis 失效
标题翻译：一种生产用于烃合成钴 - 铼催化剂的方法。
公开(公告)号：EP0498976B1
公开(公告)日：1995-07-05
申请号：EP91301093.0
申请日：1991-02-12
申请人： EXXON RESEARCH AND ENGINEERING COMPANY
发明人： Mauldin, Charles Harrison
IPC分类号： B01J23/84 , C07C1/04
CPC分类号： B01J23/8896 , C07C1/0435 , C07C2521/06 , C07C2523/36 , C07C2523/75 , C07C2523/889

7. 发明公开

EP0639553A1 Catalyst and method for producing phenols 失效
标题翻译： Katalysator和Verfahren zur Herstellung von Phenolen。
公开(公告)号：EP0639553A1
公开(公告)日：1995-02-22
申请号：EP94112072.7
申请日：1994-08-02
申请人： NKK CORPORATION
发明人： Miki, Jun, c/o Intellectual Property Dept. , Asanuma, Minoru, c/o Intellectual Property Dept. , Konishi, Takeshi, c/o Intellectual Property Dept. , Tachibana, Yakudo, c/o Intellectual Property Dept. , Shikada, Tsutomu, c/o Intellectual Property Dept. , Watanabe, Aiko
IPC分类号： C07C37/56 , C07C39/04 , B01J23/84 , B01J23/88
CPC分类号： B01J23/8472 , B01J23/8872 , C07C37/56 , Y02P20/52 , C07C39/04 , C07C39/07
摘要： A catalyst for producing phenols consists essentially of;
an iron oxide;
a nickel oxide;
at least one first oxide selected from the group consisting of a vanadium oxide and a molybdenum oxide; and
at least one second oxide selected from the group consisting of an alkali metal oxide and an alkaline earth metal oxide.
The catalyst is used to produce phenols from benzoic acid or an alkyl benzoic acid.
摘要翻译：用于生产酚的催化剂基本上由以下组成：氧化铁; 氧化镍; 选自氧化钒和氧化钼的至少一种第一氧化物; 和选自碱金属氧化物和碱土金属氧化物的至少一种第二氧化物。催化剂用于从苯甲酸或烷基苯甲酸生产苯酚。

8. 发明授权

EP0474761B1 CATALYST FOR HETEROGENEOUS CATALYSIS CONSISTING OF AN ALLOY OF TRANSITION METALS 失效
标题翻译：催化剂多相催化过渡金属的合金的事件是。
公开(公告)号：EP0474761B1
公开(公告)日：1994-11-30
申请号：EP90909216.5
申请日：1990-05-18
申请人： BASF Aktiengesellschaft
发明人： SOLBU, Erik
IPC分类号： B01J23/84 , B01D53/36
CPC分类号： B01D53/8609 , B01J23/866 , B01J25/00 , F02B1/04
摘要： A catalyst for heterogenic catalyzation through reactions with a gaseous substance with a reduction or oxidation agent, also in a gaseous state. The catalyst comprises an alloy of a number of transition metals, whereby both the specific properties of the different alloying components and their mutual coaction provide a catalyst which has a low activation temperature, high activity and a long effective life.

9. 发明授权

EP0255625B1 A method for preparing rare earth metal catalysts with honeycomb-like alloy as supports. 失效
标题翻译：制备方法fürSeltenerdmetall催化剂用的金属甲板近似值蜂窝状载体的材料。
公开(公告)号：EP0255625B1
公开(公告)日：1994-04-20
申请号：EP87110139.0
申请日：1987-07-14
申请人： Beijing Polytechnic University , China National Machinery and Equipment Import and Export Corporation
发明人： Jinghang, Xu
IPC分类号： B01D53/36 , B01J23/84 , B01J23/89 , B01J23/78
CPC分类号： B01D53/945 , B01D53/86 , B01D53/944 , B01J23/10 , Y02A50/2324 , Y02T10/22 , Y10S502/524 , Y10S502/525
摘要： This invention relates to a method for preparing rare earth metal catalysts with a honeycomb-like alloy as support and catalysts obtained thereby, which method comprises the following steps: coating a solution of mixture of rare earth metal salts onto the surfaces of support tapes; drying said support tapes quickly; decomposing said rare earth metal salts; and oxidizing the rare earth metals into catalytic materials having the desired chemical structures.

10. 发明公开

EP0569098A3 Conversion of cycloalkanone into lactone 失效
标题翻译：环链烷酮转化为内酯
公开(公告)号：EP0569098A3
公开(公告)日：1994-02-09
申请号：EP93201286.7
申请日：1993-05-06
申请人： DSM N.V.
发明人： van Geem, Paul Christiaan
IPC分类号： C07D315/00 , C07C45/41 , C07C51/235 , B01J23/34 , B01J23/84 , B01J37/03
CPC分类号： C07D315/00 , B01J23/34 , B01J23/8892 , C07C45/41 , C07C51/255 , C07C47/54 , C07C63/06
摘要： The invention relates to a process for the oxidation of a cycloalkanone containing 6-12 carbon atoms to the corresponding lactone in the presence of a benzaldehyde with the aid of an oxygen-containing gas, the benzoic acid that is formed in the oxidation being hydrogenated to benzaldehyde and the benzaldehyde thus obtained being used again in the oxidation of cycloalkanone. A catalyst that is very suitable for the conversion of a benzoic acid into the corresponding benzaldehyde can be obtained via coprecipitation of a manganese salt, a salt from which an acid support is formed at a pH between 7 and 10 in the presence of a zinc salt and optionally a copper salt, through calcination, after precipitation, at a temperature of between 300 and 700°C and then reduction with the aid of a hydrogen-containing gas mixture.
摘要翻译：本发明涉及一种在苯甲醛存在下借助含氧气体将含6-12个碳原子的环烷酮氧化为相应的内酯的方法，氧化形成的苯甲酸被氢化成苯甲醛和由此得到的苯甲醛再次用于环烷酮的氧化。非常适合将苯甲酸转化为相应的苯甲醛的催化剂可以通过锰盐的共沉淀来获得，所述锰盐是在锌盐存在下，在7至10的pH下形成酸载体的盐和任选的铜盐，沉淀后，通过煅烧，在300-700℃的温度下，然后借助含氢气体混合物还原。

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