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    • 6. 发明公开
    • ESTER FOR REFRIGERATION OIL AND WORKING FLUID COMPOSITION FOR REFRIGERATION OIL
    • 酯用于制冷油和工作流体组合物用于制冷油
    • EP3305878A1
    • 2018-04-11
    • EP16807425.0
    • 2016-06-06
    • NOF Corporation
    • YOSHIKAWA fumitakaKAJIKI TakeshiYAMADA MunehiroUEDA Seita
    • C10M105/42C10N20/00C10N30/06C10N30/08C10N40/30
    • C10M105/42C10M2207/301C10N2220/302C10N2230/08C10N2240/30
    • An ester for a refrigerator oil is obtained from the following components (A), (B), (C) and (D). The ester contains a unit derived from the component (B) in a ratio of 0.1 to 0.4 mole, a unit derived from the component (C) in a ratio of 0.8 to 2.8 mole and a unit derived from the component (D) in a ratio of 0.3 to 2,3 mole with respect to 1.0 mole of a unit derived from said component (A). The ester has a hydroxyl value of 5 to 40 mgKOH/g and satisfies the formulas (1) and (2). (A) neopentyl glycol; (B) a linear dihydric alcohol having 2 to 6 carbon atoms including carbons at both terminals and hydroxyl groups connected to the carbons at both terminals, respectively; (C) a linear dicarboxylic acid having 4 to 10 carbon atoms including carbons at both terminals and carboxyl groups connected to the carbons at both terminals, respectively; (D) a monohydric alcohol having 6 to 12 carbon atoms; 0.08 ≦ B OH/ (A OH +B OH )≦ 0.15 ···(1); [B OH /(A OH +B OH )] /[B mol /(A mol +B mol )] ≦ 0.9 ... (2); (A OH represents a molar number of terminal hydroxyl groups derived from the component (A); B OH represents a molar number of terminal hydroxyl groups derived from the component (B); A mol represents a molar number of the unit derived from said component (A); and B mol represents a molar number of the unit derived from the component (B))]
    • 由以下组分(A),(B),(C)和(D)获得用于冷冻机油的酯。 该酯含有比例为0.1-0.4摩尔的来自组分(B)的单元,来自组分(C)的比例为0.8-2.8摩尔的单元和来自组分(D)的单元 相对于来自所述成分(A)的单元1.0摩尔,为0.3〜2.3摩尔。 该酯的羟基值为5〜40mgKOH / g,满足式(1)和(2)。 (A)新戊二醇; (B)具有2至6个碳原子的线性二元醇,其分别包括两端的碳和两端连接至碳的羟基; (C)两末端碳原子数分别为4〜10的直链状二羧酸和两末端碳原子分别与羧基连接的羧基; (D)具有6至12个碳原子的一元醇; 0.08≤BOH/(AOH + BOH)≤0.15...(1); [BOH /(AOH + BOH)] / [Bmol /(Amol + Bmol)]≤0.9...(2); (AOH表示源自成分(A)的末端羟基的摩尔数,BOH表示源自成分(B)的末端羟基的摩尔数,Amol表示源自上述成分(A)的单元的摩尔数, ; Bmol表示源自组分(B)的单元的摩尔数)]