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    • 5. 发明公开
    • Two-zone fluid bed combustion/gasification
    • 两区流化床燃烧/气化
    • EP0003117A3
    • 1979-08-22
    • EP79100039
    • 1979-01-08
    • BATTELLE DEVELOPMENT CORPORATION
    • Nack, HermanLiu, Ke-Tien
    • B01J08/32B01J08/28C10J03/54F23D19/00F22B31/00
    • F23C10/10B01J8/32B01J8/388C10B49/22C10J3/54C10J3/56C10J2300/093C10J2300/0956C10J2300/0959C10J2300/0966C10J2300/0976Y10S423/16
    • A method of operating a fluidized bed system in a single vessel, typically as a combustor system for power or steam generation burning high-sulfur coal or as a gasifier for high-sulfur coal, which comprises forming an entrained fluidized bed in a first space region containing a first solid bed particle component, such as sand or hematite ore containing over 90% Fe 2 O 3 , forming in a limited space region partially within the first region a dense fluidized bed containing a second solid bed particle component, such as larger particles of the hematite, effecting division of the dense fluidized bed into upper and lower zones, providing a recirculation path such as through a cyclone separator and particle reservoir for the first particle component from the first space region through the upper zone of the dense fluidized bed in the more limited space region, operating the fluidized bed system at a velocity such that the second component particles are effectively retained in the dense fluidized bed in the more limited space region, whereas the first component particles recirculate and interpenetrate through the upper zone thereof commingling with the second component particles, and maintaining different temperatures in the upper and lower zones of the dense fluidized bed.
    • 在单个容器中操作流化床系统的方法,其通常用作用于燃烧高硫煤的动力或蒸汽发生燃烧器系统或用作高硫煤的气化器,其包括在第一空间区域中形成夹带的流化床 含有第一固体颗粒组分,例如含有超过90%Fe 2 O 3的砂或赤铁矿,在有限的空间区域内部分地在第一区域内形成含有第二固体床颗粒组分的致密流化床,例如较大的赤铁矿颗粒 使致密流化床进入上部和下部区域,提供再循环路径,例如通过旋风分离器和第一颗粒组分的第一颗粒组分的颗粒储存器从第一空间区域通过更密集的流化床的上部区域 空间区域,以使得第二组分颗粒有效地保留在致密流化中的速度操作流化床系统 在较有限的空间区域中床,而第一组分颗粒通过其与第二组分颗粒混合的上部区域再循环并互穿,并且在致密流化床的上部和下部区域保持不同的温度。
    • 10. 发明公开
    • A method for producing a methane-lean synthesis gas from petroleum coke
    • 从石油焦生产甲烷 - 精细合成气的方法
    • EP0024792A3
    • 1981-07-15
    • EP80301984
    • 1980-06-12
    • TOSCO CORPORATION
    • Schulman, Bernard L.
    • C10J03/54
    • C10J3/54C10J2300/0943C10J2300/0986
    • A methane-lean synthesis gas is produced from the steam gasification of petroleum coke in a fluidized bed at temperatures of between 650 and 790°C and pressures of between 1.75 and 14 kgicm 2 using a potassium or sodium salt to catalyze the steam-gasification reaction. The synthesis gas produced contains less than about 3 volume % methane and less than 40% volume of steam. Because of its low methane content the gas may be used to produce methanol or a high purity product gas containing substantially only hydrogen and carbon dioxide which, in turn, may be scrubbed to produce a gas containing at least 95 volume % hydrogen. If the methane lean gas produced from the gasification reactor contains nitrogen, e.g. when air is used to combust the coke to maintain the temperature of the fluidized bed, then the methane lean gas may be used to produce high purity ammonia.
    • 使用钾盐或钠盐在650至790℃的温度和1.75至14kg / cm 2的压力之间的蒸发床中的石油焦炭的蒸汽气化产生贫烷烃合成气,以催化 蒸汽气化反应。 产生的合成气包含小于约3体积%的甲烷和小于40体积%的蒸汽。 由于其甲烷含量低,气体可用于生产基本上仅含有氢气和二氧化碳的甲醇或高纯度产物气体,而这些气体又可被洗涤以产生含有至少95体积%氢气的气体。 如果从气化反应器产生的贫烷气体含有氮气, 当使用空气来燃烧焦炭以保持流化床的温度时,可以使用贫烷气来生产高纯氨。