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1. 发明授权

EP0409828B1 PROCESS FOR THE RECOVERY OF ALCOHOLS USING A PERFLUORINATED IONOMER MEMBRANE 失效
标题翻译：使用全氟化离子膜恢复酒精的方法
公开(公告)号：EP0409828B1
公开(公告)日：1993-07-28
申请号：EP88902007.9
申请日：1988-02-01
申请人： EXXON CHEMICAL PATENTS INC.
发明人： COHEN, Abraham, David , DIANA, William, Daniel , BAIEL, James, Joseph
IPC分类号： C07C29/76 , C07C29/06 , C07C31/12 , C07C31/10
CPC分类号： B01D61/362 , B01D61/246 , B01D71/32 , B01J19/2475 , B01J2219/00103 , B01J2219/00159 , B01J2219/00162 , B01J2219/00164 , C07C29/76 , C07C31/10 , C07C31/12
摘要： Alcohols are recovered from aqueous acid solution by permeation of the alcohol through a perfluorinated ionomer membrane. An improved process for the manufacture of alcohols by acid absorption of olefins is also disclosed, the improvements residing in the use of a perfluorinated ionomer membrane to selectively permeate alcohols from the concentrated aqueous strong acid solution thereof co-produced in their synthesis from olefins.

2. 发明公开

EP0023379A3 Method for the preparation of cyclohexanol and/or cyclohexanone 有权
标题翻译：环己烷和/或环己酮的制备方法
公开(公告)号：EP0023379A3
公开(公告)日：1981-02-11
申请号：EP80200725
申请日：1980-07-25
申请人： STAMICARBON B.V.
发明人： van Geem, Paul Christiaan , de Graaf, Theodorus Franciscus Maria , Knol, Dirk , Plantema, Otto Gerrit
IPC分类号： C07C45/34 , C07C45/39 , C07C49/403 , C07C29/06 , C07C29/05 , C07C29/08 , C07C35/08 , C07C05/11 , C07C13/20
CPC分类号： C07C45/34 , C07C5/11 , C07C29/04 , C07C29/05 , C07C29/06 , C07C29/08 , C07C45/39 , C07C2523/46 , C07C2601/14 , C07C2601/16 , Y02P20/52 , C07C13/20 , C07C49/403 , C07C35/08
摘要： The invention relates to a method for the preparation of cyclohexanol and/or cyclohexanone by hydrogenating benzene to cyclohexene, hydrating the cyclohexene to cyclohexanol and/or oxidating it to cyclohexanone, recovering the cyclohexanol and/or cyclohexanone, and returning unconverted benzene and/or cyclohexene to the hydrogenating step. The method according to the invention is characterized in that the mixture of cyclohexane with benzene and/or cyclohexene, which has also been obtained during the separation of cyclohexanol from the reaction mixture of the hydration step and,or of cyclohexanone from the reaction mixture of the oxidation step, is subjected to a dehydrogenation reaction, and the benzene thus obtained is returned to the hydrogenation step. The method according to the invention has the great advantage that the difficult separation of cyclohexane from mixtures with benzene and / or cyclohexene can be dispensed with. Losses of expensive extractive distillation agent are avoided. Neither is any cyclohexane left as by-product for wich a use will have to be found. In the hydrogenation step a higher degree of benzene conversion can be applied, so that economic process operation has become possible.
摘要翻译：一种从苯制备环己醇和/或环己酮的改进方法。环己醇和/或环己酮是通过氢化苯形成含有环己烯，未反应的苯和副产物环己烷的氢化反应混合物，由此得到的环己烯水解形成含有环己醇，未反应的苯和副产物的水合反应混合物环己烷和/或氧化该环己烯以形成含有环己酮，未反应苯和副产物环己烷的氧化反应混合物，从所述水合反应混合物中回收环己醇产物和/或从所述氧化反应混合物回收环己酮产物和含有未反应的苯和副产物环己烷，并将未转化的苯循环到苯加氢步骤。改进之处在于将含有未反应苯和副产物环己烷的有机相引入脱氢区，其中将副产物环己烷脱氢成苯并与未反应的苯一起再循环到氢化步骤。

3. 发明公开

EP1628734A4 METHOD FOR PURIFYING SPENT ACID 有权
标题翻译：用于清洁酸消耗的方法
公开(公告)号：EP1628734A4
公开(公告)日：2007-11-21
申请号：EP04759992
申请日：2004-04-15
申请人： RHODIA
发明人： LIU RICHARD WAI-CHUN , HILL PHILIP DEAN , PRUITT THOMAS EDWIN , SANDERS FORREST LEE , YANG ALBERT YI
IPC分类号： B01D37/00 , B01D17/02 , B01D21/26 , B01D33/15 , B03D1/02 , B03D1/26 , C01B17/58 , C01B17/92 , C02F1/00 , C07C29/06 , C07C29/88 , C07C45/00 , C07C67/20
CPC分类号： B03D1/26 , B01D17/02 , B03D1/02 , C01B17/58 , C01B17/92 , C07C29/06 , C07C29/88 , C07C45/002 , C07C67/20 , C07C49/10 , C07C69/54 , C07C31/10 , C07C31/12
摘要： A method for purifying a spent acid catalyst from an acid catalyzed chemical reaction that generates a mixture of a product, spent acid and tar, includes the steps of separating the mixture of product, spent acid, and tar into a product fraction and a spent acid fraction, said spent acid fraction comprising a mixture of spent acid and tas, and separating the spent acid fraction, by flotation separation, centrifugation, or Iiquid-Iiquid coalescence, into a tar fraction and a de tarred spent acid fraction. The fluidized tar and the de tarred spent acid can each be further processed to produce concentrated acid.

4. 发明公开

EP1538142A4 AMINE DERIVATIVE 审中-公开
标题翻译： AMINDERIVAT
公开(公告)号：EP1538142A4
公开(公告)日：2006-07-26
申请号：EP03795320
申请日：2003-09-09
申请人： NIPPON CHEMIPHAR CO
发明人： TENDO ATSUSHI , TAKAHASHI TOSHIHIRO , YAMAKAWA TOMIO
IPC分类号： C07C217/08 , C07C29/06 , C07C211/02 , C07C213/08
CPC分类号： C07C217/08
摘要： The invention relates to (1S)-1-isobutoxymethyl-3- methylbutylamine useful as an intermediate in the synthesis of sodium (2S, 3S)-3-[[(1S)-1-isobutoxymethyl-3-methylbutyl]- carbamoyl]oxirane-2-carboxylate and a process for production thereof. The process comprises reacting L-leucinol with a compound represented by the following general formula: [wherein X is a leaving group] in the presence of a base and reducing the obtained (1S)-1-(2-methyl-2-propenoxymethyl)-3-methylbutylamine.

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