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1. 发明公开

EP0821702A4 AN ACETYLENIC CARBON ALLOTROPE 失效
标题翻译： EIN乙烯基KOHLENSTOFF-ALLOTROP
公开(公告)号：EP0821702A4
公开(公告)日：1998-04-29
申请号：EP96904455
申请日：1996-01-17
申请人： LAGOW RICHARD J
发明人： LAGOW RICHARD J
IPC分类号： B32B9/00 , C01B31/02 , C07C11/22 , C07C15/48 , C07C15/50 , C07C21/22 , C07C255/09 , C08F4/50 , C09D11/02 , C10L5/00 , C10M125/02 , C10M127/02 , D01F9/12 , D01F9/127 , H01B1/04 , H01L39/12 , C08F38/02 , B32B27/14 , C01B31/00 , C08F138/02 , C08F281/00 , C09D11/00 , H01B1/00 , H01L39/00
CPC分类号： B82Y10/00 , B82Y30/00 , C07C11/22 , C07C15/50 , C07C21/22 , C07C255/09 , D01F9/12 , H01B1/04 , Y10T428/24802 , Y10T428/2913 , Y10T428/2918 , Y10T428/30
摘要： A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.
摘要翻译：描述了第四种同素异形体碳，即炔属碳同素异形体。本发明的炔属碳同素异构体在许多常见的有机溶剂中比其它已知的碳同素异构体更易溶解并且具有其它所需的特性，例如，高电子密度，清洁燃烧的能力和导电性能。这里描述了这种第四种同素异形体的许多用途。

2. 发明公开

EP0733609A1 Procédé de conversion thermique d'hydrocarbures aliphatiques saturés ou insaturés en hydrocarbures acétyléniques 失效
标题翻译：一种用于脂族饱和或不饱和烃，在炔属烃的热转化过程
公开(公告)号：EP0733609A1
公开(公告)日：1996-09-25
申请号：EP96400485.7
申请日：1996-03-08
申请人： INSTITUT FRANCAIS DU PETROLE
发明人： Busson, Christian , Alagy, Jacques , Broutin, Paul , Chevron, François
IPC分类号： C07C11/22 , C07C4/04 , C10G9/24
CPC分类号： B01J19/24 , B01J12/005 , B01J19/0013 , B01J2219/00081 , B01J2219/00135 , B01J2219/00155 , C07C4/04 , C10G2400/24 , C07C11/22
摘要： L'invention concerne un procédé d'obtention d'au moins un hydrocarbure acétylénique par pyrolyse, d'au moins un hydrocarbure aliphatique saturé ou insaturé possédant au moins deux atomes de carbone par molécule, dans lequel on opère en présence de vapeur d'eau, sous une pression comprise entre 1 et 15 bar (0,1 et 1,5 MPa), le rapport pondéral eau/hydrocarbure étant compris entre 0,55 et 20.
摘要翻译：制备方法。烃（S）通过的SAD热解的炔。或unsatd。具有至少2个C的脂族烃（S）在水蒸汽的1-15巴（0.1-1.5兆帕）时，水的重量比的压力下的存在下进行。烃（一个或多个）为0.55-20。

3. 发明公开

EP0044558A1 Method for the preparation of alkyne-1 compounds 失效
标题翻译：一种用于1-炔化合物的制备方法。
公开(公告)号：EP0044558A1
公开(公告)日：1982-01-27
申请号：EP81105710.8
申请日：1981-07-20
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Ishihara, Toshinobu , Yamamoto, Akira , Taguchi, Kenichi
IPC分类号： C07C11/22 , C07C11/28 , C07C1/26 , C07C1/32 , C07B17/00 , B01J27/10
CPC分类号： C07C1/326 , C07C2527/122 , C07C11/28
摘要： The invention provides a novel synthetic method for the preparation of an alkyne-1 compound of the general formula R(CH 2 ) n C≡CH, in which R is a monovalent hydrocarbon group and n is an integer of 4, 5 or 6, which compound is useful as an intermediate of various organic compounds or, in particular, of several sexual pheromone compounds of noxious insects expected to give a promising means for the extermination of the insects. The method comprises reacting an ω-bromo-1-alkyne compound of the formula Br(CH 2 ) n C≡CH, e.g. 8-bromo-l-octyne, with a Grignard reagent of the formula RMgX, e.g. cis-3-octenylmagnesium chloride, in tetrahydrofuran, preferably, in the presence of a catalyst which is dilithium copper tetrachloride or lithium copper dichloride.

4. 发明公开

EP0022618A3 Photoresistive compositions, process and article using them 无效
标题翻译：光电组合物，使用它们的方法和文章
公开(公告)号：EP0022618A3
公开(公告)日：1981-03-18
申请号：EP80301924
申请日：1980-06-09
申请人： UNIVERSITY PATENTS, INC.
发明人： Garito, Anthony Frank
IPC分类号： G03C01/68 , C07C11/22 , C08F38/00
CPC分类号： B82Y20/00 , B05D1/202 , B82Y30/00 , B82Y40/00 , C07C57/18 , C07C57/52 , C07C205/37 , C08F138/00 , G02F1/0018 , G02F1/3515 , G02F1/3615 , G02F1/3618 , G02F1/377 , G02F3/00 , G03F7/025
摘要： Photographic and Photolithographic systems are provided which utilize diacetylenic materials as components thereof. Such materials, which include at least two acetylenic bonds in conjugation with one another, provide a combination of both high sensitivity and high resolving power, thus resulting in superior photographic and photolithographic properties. In accordance with a preferred embodiment of the invention, a substrate is coated with at least one layer of a polymerizable composition comprising a diacetylenic species, said layer being organized into a plurality of domains having a substantially regular array of the diacetylenic species. In other embodiments, covalent bonding of the diacetylenic layer to the substrate is accomplished through the use of suitably constituted silane species, thus to provide a highly beneficial adhesion of substrate and photo-or photolithographic layer.

5. 发明授权

EP2670767B1 UNNATURAL AMINO ACIDS COMPRISING A CYCLOOCTYNYL OR TRANS-CYCLOOCTENYL ANALOG GROUP AND USES THEREOF 有权转让
标题翻译：包含环庚三烯或反环庚烯基类似物的非天然氨基酸及其用途
公开(公告)号：EP2670767B1
公开(公告)日：2017-12-20
申请号：EP12702538.5
申请日：2012-02-03
申请人： European Molecular Biology Laboratory
发明人： LEMKE, Edward , SCHULTZ, Carsten , PLASS, Tilman , MILLES, Sigrid , KOEHLER, Christine
IPC分类号： C07K14/00 , C07C11/00 , C07C11/22
CPC分类号： C07C271/22 , C07B2200/09 , C07C271/34 , C07C2601/18 , C07C2602/24 , C07C2602/42 , C07K1/13 , C07K2/00 , C12P21/00 , C12P21/02

6. 发明公开

EP2670767A1 UNNATURAL AMINO ACIDS COMPRISING A CYCLOOCTYNYL OR TRANS-CYCLOOCTENYL ANALOG GROUP AND USES THEREOF 有权转让
标题翻译： UNNATÜRLICHEAMINOSÄURENMIT EINER CYCLOOCTYNYL-ODER TRANS-CYCLOOCTENYL-ANALOGGRUPPE UND VERWENDUNGEN DAVON
公开(公告)号：EP2670767A1
公开(公告)日：2013-12-11
申请号：EP12702538.5
申请日：2012-02-03
申请人： EMBL
发明人： LEMKE, Edward , SCHULTZ, Carsten , PLASS, Tilman , MILLES, Sigrid , KOEHLER, Christine
IPC分类号： C07K14/00 , C07C11/00 , C07C11/22
CPC分类号： C07C271/22 , C07B2200/09 , C07C271/34 , C07C2601/18 , C07C2602/24 , C07C2602/42 , C07K1/13 , C07K2/00 , C12P21/00 , C12P21/02
摘要： The present invention relates to unnatural amino acids comprising a cyclooctynyl or trans- cyclooctenyl analog group and having formula (I) or an acid or base addition salt thereof. The invention also relates to the use of said unnatural amino acids, kits and processes for preparation of polypeptides that comprise one or more than one cyclooctynyl or trans- cyclooctenyl analog group. These polypeptides can be covalently modified by in vitro or in vivo reaction with compounds comprising an azide, nitrile oxide, nitrone, diazocarbonyl or 1,2,4,5- tetrazine group.
摘要翻译：本发明涉及包含环辛炔基或反式环辛烯基类似物并具有式（I）的非天然氨基酸或其酸或碱加成盐。本发明还涉及所述非天然氨基酸，试剂盒和方法用于制备包含一个或多于一个环辛炔基或反式环辛烯基类似物的多肽的用途。这些多肽可以通过与包含叠氮化物，氧化腈，硝酮，重氮羰基或1,2,4,5-四嗪基的化合物的体外或体内反应共价修饰。

7. 发明授权

EP0044558B1 Method for the preparation of alkyne-1 compounds 失效
标题翻译：制备碱金属化合物的方法
公开(公告)号：EP0044558B1
公开(公告)日：1984-05-02
申请号：EP81105710.8
申请日：1981-07-20
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Ishihara, Toshinobu , Yamamoto, Akira , Taguchi, Kenichi
IPC分类号： C07C11/22 , C07C11/28 , C07C1/26 , C07C1/32 , C07B17/00 , B01J27/10
CPC分类号： C07C1/326 , C07C2527/122 , C07C11/28

8. 发明授权

EP0015436B1 Verfahren zur stereospezifischen Herstellung von Verbindungen der Vitamin K1- und K2-Reihe sowie neue Ausgangsprodukte in diesem Verfahren 失效
标题翻译：维生素K1-和K2系列化合物的立体制备方法，作为新工艺的新起始材料
公开(公告)号：EP0015436B1
公开(公告)日：1982-02-03
申请号：EP80100822.8
申请日：1980-02-19
申请人： F. HOFFMANN-LA ROCHE & CO. Aktiengesellschaft
发明人： Dötz, Karl Heinz, Dr.
IPC分类号： C07C50/14 , C07C46/06 , C07C37/11 , C07C11/22
CPC分类号： C07F11/00 , C07C1/326 , C07C11/28 , C07C46/06 , C07C50/14

9. 发明公开

EP3097080A1 PROCESS FOR THE CYCLOADDITION OF A HALOGENATED 1,3-DIPOLE COMPOUND WITH A (HETERO)CYCLOALKYNE 审中-公开
标题翻译：具有（杂环）环烷烃的卤化1,3-二苯醚化合物的环加成方法
公开(公告)号：EP3097080A1
公开(公告)日：2016-11-30
申请号：EP15703641.9
申请日：2015-01-26
申请人： SynAffix B.V.
发明人： VAN DELFT, Floris Louis , VAN GEEL, Remon , WIJDEVEN, Maria Antonia , HEESBEEN, Ryan
IPC分类号： C07D225/02 , C07D225/08 , C07D321/12 , C07H13/00 , C07C11/22 , C07H19/00 , A61K47/48
CPC分类号： C07D249/16 , C07C247/04 , C07C247/12 , C07C247/18 , C07D225/02 , C07D225/08 , C07D321/12 , C07H1/00 , C07H13/00 , C07H13/12 , C07H19/00 , C07H19/10 , C07K16/32 , C07K2317/24
摘要： The present invention relates to a cycloaddition process comprising the step of reacting a halogenated aliphatic 1,3-dipole compound with a (hetero)cycloalkyne according to Formula (1): Preferably, the (hetero)cycloalkyne according to Formula (1) is a (hetero)cyclooctyne. The invention also relates to the cycloaddition products obtainable by the process according to the invention. The invention further relates to halogenated aliphatic 1,3- dipole compounds, in particular tohalogenated aliphatic 1,3-dipole compounds comprising N-acetylgalactosamine-UDP (GalNAc-UDP),and to halogenated 1,3- dipole compounds comprising (peracylated) N-acetylglucosamine(GlcNAc), N- acetylgalactosamine(GalNAc), N-acetylmannosamine(ManNAc)and N- acetylneuraminic acid(NeuNAc).
摘要翻译：本发明涉及包括使卤代脂族1,3-偶极化合物与根据式（1）的（杂）环炔反应的步骤的环加成方法：优选地，根据式（1）的（杂）环炔是（杂）环辛炔。本发明还涉及通过根据本发明的方法可获得的环加成产物。本发明进一步涉及卤化脂族1,3-偶极化合物，特别是涉及包含N-乙酰半乳糖胺-UDP（GalNAc-UDP）的卤化1,3-偶极化合物化合物以及包含（过酰化）N （GlcNAc），N-乙酰半乳糖胺（GalNAc），N-乙酰甘露糖胺（ManNAc）和N-乙酰神经氨酸（NeuNAc）。

10. 发明公开

EP2960228A4 METHOD FOR PRODUCING METHACRYLIC ACID ESTER 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG VONMETHACRYLSÄUREESTER
公开(公告)号：EP2960228A4
公开(公告)日：2016-10-19
申请号：EP14775559
申请日：2014-03-19
申请人： SUMITOMO CHEMICAL CO
发明人： SEKI KOHEI , SUZUTA TETSUYA , MIURA NAOKI
IPC分类号： C07C67/38 , C07C1/24 , C07C5/25 , C07C11/14 , C07C11/22 , C07C69/54
CPC分类号： C07C67/38 , C07C1/2076 , C07C1/24 , C07C5/2506 , C07C2521/04 , C07C2521/08 , C07C2523/04 , Y02P20/582 , C07C69/54 , C07C11/24 , C07C11/14
摘要： The method for producing a methacrylic acid ester of the present invention comprises a dehydration reaction step of having acetone undergo a dehydration reaction in the presence of a dehydration reaction catalyst to obtain a reaction mixture; a propyne/propadiene separation step of separating a mixture containing propyne and propadiene as main components from the obtained reaction mixture; a propyne purification step of separating the separated mixture containing propyne and propadiene as main components into a liquid, gas, or gas-liquid mixture containing propyne as a main component, and a liquid, gas, or gas-liquid mixture containing propadiene as a main component; and a carbonylation reaction step of bringing the obtained liquid, gas, or gas-liquid mixture containing propyne as a main component into contact with carbon monoxide and an alcohol having 1 to 3 carbon atoms in the presence of a catalyst containing at least one selected from the group consisting of Group 8 metal elements, Group 9 metal elements, and Group 10 metal elements to obtain a methacrylic acid ester. According to the method of the present invention, it is possible to provide a method for producing a methacrylic acid ester, which is less likely to receive location restrictions and is also economically and industrially advantageous.
摘要翻译：本发明的甲基丙烯酸酯的制造方法包括在脱水反应催化剂的存在下进行脱水反应的脱水反应工序，得到反应混合物; 丙烯/丙二烯分离步骤，从得到的反应混合物中分离含有丙炔和丙二烯作为主要成分的混合物; 将以丙炔和丙二烯为主要成分的分离混合物分离成含有丙炔作为主要成分的液体，气体或气液混合物的丙炔纯化步骤，以丙二烯为主要原料的液体，气体或气液混合物零件; 以及羰基化反应步骤，将含有丙炔作为主要成分的所得液体，气体或气液混合物与一氧化碳和具有1至3个碳原子的醇在含有至少一种选自由8族金属元素，9族金属元素和10族金属元素组成的组，得到甲基丙烯酸酯。根据本发明的方法，可以提供一种生产甲基丙烯酸酯的方法，其不太可能获得位置限制，并且在经济和工业上也是有利的。

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