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    • 4. 发明公开
    • CONDUCTIVE COMPOSITION
    • 导电组合物
    • EP2907164A1
    • 2015-08-19
    • EP12886806.4
    • 2012-10-15
    • Dow Global Technologies LLC
    • ZHANG, Yong WWANG, William ZSHI, SusanFOLKENROTH, Jason J
    • H01L31/0224H01L31/042H01L31/04H01B1/22
    • H01L31/022425H01B1/22H01B13/0016H01B13/30Y02E10/50
    • Disclosed is a conductive composition useful for the preparation of electrically conductive structures on a substrate comprising a plurality of metal particles, a plurality of glass particles and a vehicle comprising at least one cellulose derivative and at least one solid organopolysiloxane resin dissolved in a mutual organic solvent. The solid organopolysiloxane resin acts as adhesion promoter and assists in stably dispersing the metal and glass particles to avoid an agglomeration of such particles without degrading the rheological properties. From such conductive compositions uniform well adherent electrically conductive structures essentially free from defects in the form of cracks, bubbles or coarse particulates can be prepared on dielectric or semiconductor substrates such as silicon wafers in an efficient and cost-saving manner e.g. by screen printing, drying and sintering while inducing only low warping of the substrate. These characteristics render said conductive compositions particularly useful for the fabrication of electrodes of a semiconductor solar cell helping to increase the cell conversion efficiency.
    • 公开了一种导电组合物,其用于在包含多个金属颗粒,多个玻璃颗粒和载体的载体上制备导电结构,所述载体包含至少一种纤维素衍生物和至少一种固体有机聚硅氧烷树脂,所述固体有机聚硅氧烷树脂溶解于相互有机溶剂 。 该固体有机聚硅氧烷树脂充当粘合促进剂并有助于稳定地分散金属和玻璃颗粒以避免这种颗粒聚集而不降低流变性质。 从这样的导电组合物可以在电介质或半导体衬底如硅晶片上以有效且节约成本的方式制备基本上没有裂纹,气泡或粗颗粒形式的缺陷的均匀的良好附着的导电结构, 通过丝网印刷,干燥和烧结,同时仅引起基材的低翘曲。 这些特性使得所述导电组合物特别适用于制造有助于提高电池转换效率的半导体太阳能电池的电极。
    • 6. 发明公开
    • TRANSPARENT CONDUCTOR AND METHOD FOR PRODUCING SAME
    • VERFAHREN ZU SEINER HERSTELLUNG的传真机
    • EP2738776A1
    • 2014-06-04
    • EP12834716.8
    • 2012-09-21
    • Kyushu University, National University CorporationToray Industries, Inc.
    • IMAZU, NaokiWATANABE, OsamuNAKASHIMA, NaotoshiFUJIGAYA, Tsuyohiko
    • H01B13/00B32B7/02B32B9/00H01B5/14
    • H01B13/30B82Y30/00C03C17/3441C03C2217/42H01B1/02H01B1/04H01L51/0048H01L51/5203Y10T428/30
    • A method for producing a transparent conductor wherein an electrically conductive laminate structure is formed on at least one surface of the transparent substrate by spreading a dispersion containing carbon nanotubes on a transparent substrate and drying the dispersion to form an electrically conductive layer, is provided. This method includes the step of forming an undercoat layer containing a hole doping compound at a proportion of 0.2 to 20% by weight on the transparent substrate before forming the electrically conductive layer, or the step of forming an overcoat layer containing a hole doping compound at a proportion of 0.2 to 20% by weight after forming the electrically conductive layer. Also provided is a transparent conductor having an undercoat layer containing a hole doping compound at a proportion of 0.2 to 20% by weight and an electrically conductive layer containing carbon nanotubes in this order, or an electrically conductive layer containing carbon nanotubes and an overcoat layer containing a hole doping compound at a proportion of 0.2 to 20% by weight in this order, on at least one surface of the transparent substrate. A simple and productive method capable of forming a carbon nanotube transparent conductor having excellent transparent electrical conductivity is provided.
    • 提供一种透明导体的制造方法,其中通过将含有碳纳米管的分散体铺展在透明基板上并干燥该分散体以形成导电层,在透明基板的至少一个表面上形成导电层压结构。 该方法包括在形成导电层之前在透明基板上形成含有占位掺杂化合物的比例为0.2〜20重量%的底涂层的步骤,或者在形成导电层的步骤中形成含有空穴掺杂化合物的外涂层 在形成导电层之后的比例为0.2〜20重量%。 还提供了一种透明导体,其具有底涂层,该底涂层含有占0.2重量%至20重量%的比例的空穴掺杂化合物和含有碳纳米管的导电层,或含有碳纳米管和外涂层的导电层, 在透明基材的至少一个表面上,以0.2〜20重量%的比例依次形成空穴掺杂化合物。 提供了能够形成具有优异透明导电性的碳纳米管透明导体的简单而有效的方法。
    • 7. 发明公开
    • SUPERCONDUCTING WIRE
    • SUPRALEITED DRAHT
    • EP2725586A1
    • 2014-04-30
    • EP13808940.4
    • 2013-06-26
    • Furukawa Electric Co., Ltd.
    • HIGUCHI, MasaruSAKAMOTO, HisakiORITA, NobuakiSHIBAYAMA, Norihisa
    • H01B12/06H01B13/00
    • H01B12/06H01B13/30H01L39/125H01L39/24H01L39/2461
    • A superconducting wire is provided which allows an appropriate critical current property to be obtained while maintaining high adhesive strength based on smoothness of a substrate surface that can be achieved without mechanical polishing or the like. A first intermediate layer 21 is formed by coating a material solution on a substrate 10 with a maximum height roughness Rz of 10 nm or more. This improves surface smoothness of the first intermediate layer 21, improves orientation and smoothness of a second intermediate layer 22 formed on the first intermediate layer 21, and increases a critical current in an oxide superconducting layer 30. Furthermore, the first intermediate layer 21 is formed of a plurality of thin coating film layers 21i. The thin coating film layers 21i are deposited such that an uppermost thin coating film layer has a smaller film thickness than a lowermost thin coating film layer and/or a material solution used for the uppermost thin coating film layer has a lower viscosity than a material solution used for the lowermost thin coating film layer. This improves the surface smoothness of the first intermediate layer 21.
    • 提供了一种超导线,其允许在基于在不进行机械抛光等的情况下可以实现的基板表面的平滑度的同时保持高粘合强度的同时获得适当的临界电流特性。 第一中间层21通过以10nm以上的最大高度粗糙度Rz在基板10上涂布材料溶液而形成。 这提高了第一中间层21的表面平滑度,改善了形成在第一中间层21上的第二中间层22的取向和平滑度,并且增加了氧化物超导层30中的临界电流。此外,形成第一中间层21 的多个薄膜层21i。 沉积薄的涂膜层21i,使得最薄的涂膜层的膜厚比最薄的涂膜层薄,和/或用于最上面的薄涂层层的材料溶液具有比材料溶液更低的粘度 用于最薄的薄膜层。 这提高了第一中间层21的表面平滑度。