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    • 8. 发明公开
    • ELECTROLYTIC REDUCTION OF METAL OXIDES SUCH AS TITANIUM DIOXIDE AND PROCESS APPLICATIONS
    • 法如二氧化钛及其使用金属氧化物的电解还原
    • EP1257679A1
    • 2002-11-20
    • EP01905924.5
    • 2001-02-20
    • QinetiQ Limited
    • WARD-CLOSE, Charles, MalcolmDERA FarnboroughGODFREY, Alistair, BryanDERA Farnborough
    • C22B34/12C25F1/16C25C3/28C22B5/00
    • C25C5/04B22F9/20B22F2999/00C22B4/06C22B5/00C22B5/02C22B34/1263C22B34/129C22C47/04C22C47/14C25C3/00C25C3/28
    • A method of removing oxygen from a solid metal, metal compound or semi-metal M1O by electrolysis in a fused salt of M2Y or a mixture of salts, which comprises conducting electrolysis under conditions such that reaction of oxygen rather than M2 deposition occurs at an electrode surface and that oxygen dissolves in the electrolyte M2Y and wherein, M1O is in the form of (sintered) granules or is in the form of a powder which is continuously fed into the fused salt. Also disclosed is a method of producing a metal foam comprising the steps of fabricating a foam-like metal oxide preform, removing oxygen from said foam structured metal oxide preform by electrolysis in a fused salt of M2Y or a mixture of salts, which comprises conducting electrolysis under conditions such that reaction of oxygen rather than M2 deposition occurs at an electrode surface. The method is advantageously applied for the production of titanium from Ti-dioxide.
    • 检查从固体金属,金属化合物或半金属M1O通过电解在M2Y的熔融盐或盐的混合物,其包括导电的条件下电解除去氧的方法,做了氧的反应,而不是M2沉积发生在在电极 在电解质M2Y和worin表面和没有氧溶解,M1O处于(烧结的)颗粒形式或为粉末所有这一切都被连续地供给到熔融盐的形式。 因此游离缺失盘是制造金属泡沫,其包含一种制造泡沫状金属氧化物预成型件,通过电解在M2Y的熔融盐或盐的混合物中除去从所述泡沫结构的金属氧化物预成型件的氧的步骤的方法, 它包括导电的条件下电解检查没有氧的反应,而不是M2沉积在发生在电极surface.The方法有利地应用于从二氧化钛生产钛。 所以圆盘游离缺失是生产金属基质复合材料的方法和纤维增强金属复合材料,金属基体的worin通过电解还原制备所述复合结构之后形成。