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    • 3. 发明公开
    • Method for producing a skin layer of a flexible, elastomeric, thermoset, phase-separated polyurethane material
    • 一种用于制造柔性的,弹性的,热固性的,相分离的聚氨酯材料的表层处理
    • EP2365012A1
    • 2011-09-14
    • EP10002295.3
    • 2010-03-05
    • RECTICEL Automobilsysteme GmbH
    • Vanlandschoot, KoenMispelon, JurgenHaelterman BartSnellings Geert
    • C08G18/18C08G18/28C08G18/32C08G18/48C08G18/66C08G18/75
    • C08G18/283C08G18/1825C08G18/2835C08G18/3203C08G18/3206C08G18/3271C08G18/3275C08G18/3287C08G18/329C08G18/4808C08G18/4837C08G18/4891C08G18/6688C08G18/755C08G18/792
    • The thermoset, phase-separated polyurethane material of the flexible skin layer is produced from a reactive mixture which is made of one or more isocyanate compounds and isocyanate reactive compounds which comprise one or more polyol compounds, flexibilisers, chain extenders and/or crosslinkers and amine-initiators. Apart from at least one crosslinking amine-initiator, these amine-initiators further comprise at least one extender amine-initiator which has a functionality of 2 and a molecular weight of less than 300 and which corresponds to formula (I)

               HR 1 N-R 2 -OH     (I)

      wherein:
      R 1 is H or a cyclic or acyclic hydrocarbon chain, which is substituted or not and which comprises one or more hetero-atoms or not, R 1 being preferably H or a C1 to C6 alkyl group; and
      R 2 is a hydrocarbon chain which is substituted or not, which comprises a hetero-atom or not and which comprises a backbone linking the amino group with the hydroxyl group and containing at least two carbon atoms.

      The combination of the flexibiliser and the extender amine-initiator was found to have an increased effect on the flexural modulus and the softening temperature of the polyurethane material whilst maintaining the required mechanical properties at a satisfactory level.
    • 柔性表层的热固性的,相分离的聚氨酯材料从反应混合物中产生所有它是由一种或多种异氰酸酯化合物和异氰酸酯,其包含一种或多种多元醇化合物,增韧剂,增链剂和/或交联剂和胺反应性化合物 -initiators。 除了至少一种交联胺 - 引发剂,论文胺 - 引发剂进一步包含至少一种扩链剂胺 - 引发剂这对的2和功能的小于300且对应于式(I)€ƒ€ƒ€分子量 ƒ€ƒ€ƒ€ƒ€ƒ€ƒHR 1 NR 2 -OH€ƒ€ƒ€ƒ€ƒ€ƒ(I)其中:R 1是H或环状的或无环的烃链,其是被取代的或不和 其包括一个或多个杂原子或不中,R 1优选为H或C1-C6烷基; 且R 2是被取代或未被取代的烃链,其包含一个杂原子或不和它包括一个主链与羟基基团的氨基酸基团连接和含有至少两个碳原子。 所述的Flexi防盗的组合和扩链剂胺 - 引发剂其中发现有在上的挠曲模量和聚氨酯材料的软化温度,同时在令人满意的水平维持所需的机械性能提高的效果。