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    • 5. 发明公开
    • COVER GLASS FOR PHOTOELECTRIC CONVERTER AND PROCESS FOR PRODUCING SAME
    • 盖玻璃用于生产光电转换器和方法
    • EP2511738A4
    • 2017-01-04
    • EP10835645
    • 2010-11-05
    • NIPPON SHEET GLASS CO LTD
    • KOYO MIZUHOYAMAMOTO TORUKAWAZU MITSUHIROKIDO MASAATSU
    • G02B1/11H01L31/042
    • G02B1/113G02B1/115H01L31/02168Y02E10/50Y10T428/24421
    • In order to eliminate non-uniformity in the appearance of a cover glass for photoelectric conversion devices, the reflectance curve of the cover glass is extremely flattened. Provided is a cover glass for photoelectric conversion devices that includes a glass sheet having an uneven surface such as a figured glass, and a reflection-reducing film formed on the uneven surface. The reflection-reducing film includes silica fine particles and a binder for the silica fine particles. The silica fine particles are arranged in a single layer on the top portion of the uneven surface of the glass sheet, while the silica fine particles are arranged in stacks to a thickness equivalent to at least three layers on the bottom portion of the uneven surface. The uneven surface of the glass sheet has an average spacing Sm of at least 0.4 mm but not more than 2.5 mm and an arithmetic average roughness Ra of 0.5 µm to 5 µm. The cover glass has a reflectance of at least 1.5% but not more than 3% over the entire wavelength range of 380 nm to 780 nm for incident light from the side on which the reflection-reducing film is formed.
    • 为了消除在一护罩玻璃的光电转换装置的外观不均匀,覆盖玻璃的反射率曲线是极其平坦化。 提供了一种用于光电转换装置的盖玻璃并包括具有不平整的表面上的玻璃板:如型板玻璃,以及反射抑制薄膜形成的不平坦表面上。 反射抑制薄膜包括二氧化硅细颗粒和二氧化硅细颗粒的粘合剂。 二氧化硅细颗粒排列在玻璃板的表面凹凸的顶部部分中的单个层,而二氧化硅微粒在堆叠布置成厚度相当于至少三个层上的不平坦表面的底部部分。 玻璃板的表面凹凸对的至少0.4mm的平均间隔Sm微米,但不大于2.5毫米,在0.5至5微米算术平均粗糙度Ra。 盖玻璃具有至少1.5%的在整个波长范围为380至780nm,从在其上反射抑制薄膜是形成在侧反射,但不超过3%的入射光。
    • 7. 发明公开
    • COVER GLASS FOR PHOTOELECTRIC CONVERSION DEVICE
    • DECKGLASFÜRFOTOELEKTRISCHE UMWANDLUNGSVORRICHTUNG
    • EP2881765A4
    • 2016-03-02
    • EP13825709
    • 2013-07-09
    • NIPPON SHEET GLASS CO LTD
    • KONDO FUMIYOSHIYABUTA TAKESHIKAWAZU MITSUHIRO
    • G02B5/02G02B1/11G02B1/111G02B1/113G02B1/118H01L31/04H01L31/048
    • G02B5/0226G02B1/113G02B1/118G02B5/0268G02B5/0278G02B5/0294H01L31/042H02S40/20H02S40/22Y02B10/12Y02E10/52Y10T428/24421
    • A cover glass of the present invention for photoelectric conversion devices includes a glass sheet having surface asperities and a reflection-reducing film formed over the surface asperities of the glass sheet. The surface asperities of the glass sheet have an average spacing Sm of 0.3 mm or more and 2.5 mm or less and an arithmetic average roughness Ra of 0.3 µm to 5 µm. The reflection-reducing film includes fine silica particles having an average particle diameter of 50 to 200 nm and a binder for the fine silica particles, and the fine silica particles are uniformly arranged in a single layer on peak portions of the surface asperities in such a manner that a filling fraction F is 35 to 65%. A transmittance gain is 2.37% or more, the transmittance gain being obtained by subtracting an average transmittance of the glass sheet as measured when light having wavelengths ranging from 380 to 1100 nm are incident on a face of the glass sheet that has the surface asperities, from an average transmittance of the cover glass as measured when light having the wavelengths are incident on a reflection-reducing film side of the cover glass. Thus, a cover glass for photoelectric conversion devices that exhibits a high transmittance gain is provided.
    • 用于光电转换装置的本发明的玻璃罩包括具有表面粗糙度的玻璃板和在玻璃板的表面粗糙度上形成的减反射膜。 玻璃板的表面粗糙度的平均间隔Sm为0.3mm以上且2.5mm以下,算术平均粗糙度Ra为0.3μm〜5μm。 减反射膜包括平均粒径为50〜200nm的二氧化硅微粒和二氧化硅微粒的粘结剂,二氧化硅微粒在这样的表面粗糙度的峰部上均匀地排列在单层中 填充率F为35〜65%。 透光率增益为2.37%以上,透射增益通过减去玻璃板的平均透射率而得到,该平均透射率是在具有380〜1100nm波长的光入射到具有表面粗糙度的玻璃板的表面上时测量的, 从当具有波长的光入射到覆盖玻璃的减反射膜侧时测量的玻璃的平均透射率。 因此,提供了具有高透射率增益的用于光电转换装置的遮光玻璃。