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    • 2. 发明公开
    • Removal of ammonia from wastewater
    • 从废水中去除氨
    • EP0200834A3
    • 1988-04-06
    • EP85308709
    • 1985-11-29
    • ADVANCED SEPARATION TECHNOLOGIES INCORPORATED
    • Berry, W. WesErickson, William R.
    • C02F01/28
    • C02F1/586B01J39/14B01J47/11C02F1/281
    • A process for the continuous removal of ammonia from wastewater which converts the otherwise undesirable ammonia to a commercially useful end product such as ammonium phosphate. The process is carried out in an Advanced Separation Device which comprises a plurality of chambers (14) moving in a circular path in periodic fluid communication with a plurality of fixed feed ports (12) and discharge ports (16). The chambers (14) are filled with a zeolite adsorbent which effectively adsorbs the ammonium ions contained in the wastewater at low pH levels but which, when contacted with an alkaline regeneration solution, releases the previously adsorbed ammonia in the form of ammonia gas. Acidic materials may be added to the wastewater in an intra-stage fashion i.e. during the adsorption step, so as to optimize process efficiency. Similarly, intra-stage addition of alkaline materials during the regeneration step results in increased process efficiency. The process may be practided with both industrial and municipal wastewaters.
    • 公开了用于从废水中连续除去氨的方法,其将否则不希望的氨转化为商业上有用的最终产物如磷酸铵。 该过程在高级分离装置中进行,该高级分离装置包括围绕与多个固定进料和排出口周期性流体连通的圆形路径移动的多个室。 这些腔室填充有沸石吸附剂,该沸石吸附剂在低pH值水平下有效地吸附在废水中的铵离子,但当与碱性再生溶液接触时,释放先前吸附的氨气形式的铵,沸石具有 没有亲和力。 通过ASD设计,可以以阶段内的方式,即在吸附步骤期间向废水中加入酸性物质,以便优化处理效率。 类似地,在再生步骤期间阶段内添加碱性材料导致提高的工艺效率。 该过程可以与工业和城市废水一起实施。
    • 7. 发明公开
    • A fluid distribution apparatus an artificial moving bed, and a continuous adsorption method
    • Eine Fluidum Verteilungsvorrichtung,ein similiertes bewgendes Bett und eine kontinueierliche Adsorptionsmethode。
    • EP0655266A1
    • 1995-05-31
    • EP93402896.0
    • 1993-11-30
    • Tsukishima Kikai Co. Ltd.
    • Morita, MinoruOhno, Jun
    • B01D15/02B01J47/10
    • B01D15/1842B01D15/14B01J47/11Y10T137/86533
    • The artificial moving bed of this invention includes a fluid distribution apparatus consisting of an upper fluid distributor and a lower fluid distributor, and a plurality of processing chambers held and fixed between the upper and lower fluid distributors. Each fluid distributor has a rotary valve held in a slidable condition between a fixed supply valve and a pipe fixing plate. These fluid distributors are formed with fluid passages therein. The processing chambers are divided into several groups, each assigned a specific process. Using this artificial moving bed, the processing chambers are operated simultaneously and when the process is finished in each group of processing chambers, the fluid distribution apparatus is rotated clockwise when viewed from above so that each group of chambers proceeds to the next process, thus allowing continuous adsorption operation.
    • 本发明的人造移动床包括由上部流体分配器和下部流体分配器组成的流体分配装置,以及保持并固定在上部和下部流体分配器之间的多个处理室。 每个流体分配器具有保持在固定供给阀和管固定板之间的可滑动状态的旋转阀。 这些流体分配器在其中形成有流体通道。 处理室分为几组,每组分配一个具体过程。 使用这种人造移动床,处理室同时操作,并且当在每组处理室中完成处理时,流体分配装置从上方观察时顺时针旋转,使得每组室进行到下一个处理,从而允许 连续吸附操作。