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    • 3. 发明公开
    • CARBONATE PRECURSORS FOR LITHIUM NICKEL MANGANESE COBALT OXIDE CATHODE MATERIAL AND THE METHOD OF MAKING SAME
    • 锂镍锰钴氧化物阴极材料的碳酸盐前体及其制备方法
    • EP3204972A1
    • 2017-08-16
    • EP15848741.3
    • 2015-09-30
    • UmicoreUmicore Korea Ltd.
    • HU, JinHONG, HeonPyoPAULSEN, JensOH, JinDooNELIS, DaniëlROBERT, Eric
    • H01M4/525H01M4/505H01M4/485
    • H01M4/1391C01G53/006C01G53/44C01P2002/52C01P2002/54C01P2002/72C01P2004/32C01P2004/51C01P2004/61C01P2006/11C01P2006/12C01P2006/40H01M4/0471H01M4/485H01M4/505H01M4/525H01M10/052Y02T10/7011
    • A method for producing a M-carbonate precursor of a Li-M oxide cathode material in a continuous reactor, wherein M=NixMnyCozAn, A being a dopant, with x>0, y>0, 0≦z≦0.35, 0≦n≦0.02 and x+y+z+n=1, the method comprising the steps of: —providing a feed solution comprising Ni-, Mn-, Co- and A-ions, and having a molar metal content M″ feed, —providing an ionic solution comprising either one or both of a carbonate and a bicarbonate solution, the ionic solution further comprising either one or both of Na- and K-ions, —providing a slurry comprising seeds comprising M′-ions and having a molar metal content M′ seeds, wherein M′=Nix′Mny′Coz′A′n′, A′ being a dopant, with 0≦x′≦1, 0≦y′≦1, 0≦z′≦1, 0≦n′≦1 and x′+y′+z′+n′=1, and wherein the molar ratio M′ seeds/M″ feed is between 0.001 and 0.1, —mixing the feed solution, the ionic solution and the slurry in the reactor, thereby obtaining a reactive liquid mixture, —precipitating a carbonate onto the seeds in the reactive liquid mixture, thereby obtaining a reacted liquid mixture and the M-carbonate precursor, and —separating the M-carbonate precursor from the reacted liquid mixture.
    • 在连续反应器中生产Li-M氧化物阴极材料的M-碳酸盐前体的方法,其中M = NixMnyCozAn,A是掺杂剂,其中x> 0,y>0,0≤z≤0.35,0≤n ≤0.02和x + y + z + n = 1,所述方法包括以下步骤: - 提供包含Ni-,Mn-,Co-和A-离子并且具有摩尔金属含量M“进料的进料溶液, 提供包含碳酸盐和碳酸氢盐溶液中的一种或两种的离子溶液,所述离子溶液进一步包含Na-和K-离子中的一种或两种, - 提供包含含有M'-离子并且具有摩尔金属 内容M'种子,其中M'= Nix'Mny'Coz'A'n',A'为掺杂剂,0≤x'≤1,0≤y'≤1,0≤z'≤1,0≤≤ n'≤1且x'+ y'+ z'+ n'= 1,并且其中M'种子/ M“进料的摩尔比在0.001和0.1之间, - 将进料溶液,离子溶液和浆液混合 由此获得反应性液体混合物, - 将碳酸盐沉淀到反应性液体混合物中的种子上 从而获得反应后的液体混合物和M-碳酸盐前体,并且从反应后的液体混合物中分离出M-碳酸盐前体。