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1. 发明公开

EP0602933A3 Hydrosilylative compositions and hydrosilylation reaction processes 失效
标题翻译：通过硅氢加成固化成分和硅氢化。
公开(公告)号：EP0602933A3
公开(公告)日：1995-03-15
申请号：EP93310070.3
申请日：1993-12-14
申请人： SHIN-ETSU CHEMICAL CO., LTD. , NIPPON PAINT CO., LTD.
发明人： Takarada, Mitsuhiro , Yoshikawa, Yuji , Ohsugi, Hiroharu , Eguchi, Yoshio
IPC分类号： C08L101/00 , C08L83/05 , C08K5/09 , C08K5/05 , C08K5/56
CPC分类号： C08L67/06 , C08K5/0025 , C08L63/00 , C08L83/10 , C08L101/00 , C08L83/00
摘要： A blend of (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule, (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule, and (C) a hydrosilylaion catalyst is blended with (D) an organic iron or aluminum compound to form a hydrosilylative composition. Component (D) scavenges a catalyst poison, permitting components (A) and (B) to undergo hydrosilylation reaction with the aid of catalyst (C).

2. 发明公开

EP0602933A2 Hydrosilylative compositions and hydrosilylation reaction processes 失效
标题翻译：氢化硅烷化组合物和氢化硅烷化反应过程
公开(公告)号：EP0602933A2
公开(公告)日：1994-06-22
申请号：EP93310070.3
申请日：1993-12-14
申请人： SHIN-ETSU CHEMICAL CO., LTD. , NIPPON PAINT CO., LTD.
发明人： Takarada, Mitsuhiro , Yoshikawa, Yuji , Ohsugi, Hiroharu , Eguchi, Yoshio
IPC分类号： C08L101/00 , C08L83/05 , C08K5/09 , C08K5/05 , C08K5/56
CPC分类号： C08L67/06 , C08K5/0025 , C08L63/00 , C08L83/10 , C08L101/00 , C08L83/00
摘要： A blend of (A) an acrylic, polyester or epoxy resin having at least two alkenyl or alkynyl groups in a molecule, (B) an organic silicon compound having at least two hydrogen atoms each directly attached to a silicon atom in a molecule, and (C) a hydrosilylaion catalyst is blended with (D) an organic iron or aluminum compound to form a hydrosilylative composition. Component (D) scavenges a catalyst poison, permitting components (A) and (B) to undergo hydrosilylation reaction with the aid of catalyst (C).
摘要翻译：（A）在分子中具有至少两个烯基或炔基的丙烯酸，聚酯或环氧树脂的共混物，（B）具有至少两个直接连接到分子中的硅原子的氢原子的有机硅化合物，和（C）将氢化硅烷化催化剂与（D）有机铁或铝化合物混合以形成氢化硅烷化组合物。组分（D）清除催化剂毒物，允许组分（A）和（B）借助催化剂（C）进行氢化硅烷化反应。

3. 发明公开

EP0450844A3 Curable resin compositions 失效转让
标题翻译：可固化树脂组合物
公开(公告)号：EP0450844A3
公开(公告)日：1992-03-25
申请号：EP91302665.4
申请日：1991-03-27
申请人： Shin-Etsu Chemical Co., Ltd. , NIPPON PAINT CO., LTD.
发明人： Takarada, Mitsuhiro , Yoshikawa, Yuji , Yamamoto, Kenji , Ohsugi, Hiroharu , Ohgaki, Atsushi , Takagawa, Ryozo
IPC分类号： C09D201/00 , C09D183/05 , C08L101/00 , C08K5/54
CPC分类号： C08K5/5419 , C08L101/02 , C08L83/00
摘要： A curable resin composition comprises (a) an organic resin containing at least two alkenyl groups per molecule, and havinv a number average molecular weight of 500-100,000, (b) an organohydrogen-polysiloxane containing no less than two Si-H bonds per molecule, and (c) a platinum catalyst. Component (a) is preferably chosen from at least one of acrylic, polyester and epoxy resins. The preferred amount of component (b) is such that there are 0.8-4 hydrogen atoms bonded to silicon atoms per alkenyl group of component (a). The compositions can be cured at low temperatures without shrinking to give a product having good water and chemical resistance, and recoatability.

4. 发明授权

EP0602933B1 Hydrosilylative compositions and hydrosilylation reaction processes 失效
标题翻译：通过氢化硅烷化可固化的组合物和硅氢化
公开(公告)号：EP0602933B1
公开(公告)日：1998-04-29
申请号：EP93310070.3
申请日：1993-12-14
申请人： SHIN-ETSU CHEMICAL CO., LTD. , NIPPON PAINT CO., LTD.
发明人： Takarada, Mitsuhiro , Yoshikawa, Yuji , Ohsugi, Hiroharu , Eguchi, Yoshio
IPC分类号： C08L101/00 , C08L83/05 , C08K5/09 , C08K5/05 , C08K5/56
CPC分类号： C08L67/06 , C08K5/0025 , C08L63/00 , C08L83/10 , C08L101/00 , C08L83/00

5. 发明公开

EP0450844A2 Curable resin compositions 失效转让
标题翻译：可固化树脂组合物
公开(公告)号：EP0450844A2
公开(公告)日：1991-10-09
申请号：EP91302665.4
申请日：1991-03-27
申请人： Shin-Etsu Chemical Co., Ltd. , NIPPON PAINT CO., LTD.
发明人： Takarada, Mitsuhiro , Yoshikawa, Yuji , Yamamoto, Kenji , Ohsugi, Hiroharu , Ohgaki, Atsushi , Takagawa, Ryozo
IPC分类号： C09D201/00 , C09D183/05 , C08L101/00 , C08K5/54
CPC分类号： C08K5/5419 , C08L101/02 , C08L83/00
摘要： A curable resin composition comprises (a) an organic resin containing at least two alkenyl groups per molecule, and havinv a number average molecular weight of 500-100,000, (b) an organohydrogen-polysiloxane containing no less than two Si-H bonds per molecule, and (c) a platinum catalyst. Component (a) is preferably chosen from at least one of acrylic, polyester and epoxy resins. The preferred amount of component (b) is such that there are 0.8-4 hydrogen atoms bonded to silicon atoms per alkenyl group of component (a).
The compositions can be cured at low temperatures without shrinking to give a product having good water and chemical resistance, and recoatability.
摘要翻译：（a）每分子含有至少两个链烯基并具有500-100,000的数均分子量的有机树脂，（b）每分子含有不少于两个Si-H键的有机氢聚硅氧烷，和（c）铂催化剂。组分（a）优选选自丙烯酸类，聚酯和环氧树脂中的至少一种。组分（b）的优选量是组分（a）每个链烯基有0.8-4个与硅原子键合的氢原子。该组合物可以在低温下固化而不收缩，从而得到具有良好的耐水性和耐化学性以及重涂性的产品。

6. 发明授权

EP0450844B1 Curable resin compositions 失效转让
标题翻译：固化性树脂组合物
公开(公告)号：EP0450844B1
公开(公告)日：1995-12-20
申请号：EP91302665.4
申请日：1991-03-27
申请人： Shin-Etsu Chemical Co., Ltd. , NIPPON PAINT CO., LTD.
发明人： Takarada, Mitsuhiro , Yoshikawa, Yuji , Yamamoto, Kenji , Ohsugi, Hiroharu , Ohgaki, Atsushi , Takagawa, Ryozo
IPC分类号： C09D201/00 , C09D183/05 , C08L101/00 , C08K5/54
CPC分类号： C08K5/5419 , C08L101/02 , C08L83/00

7. 发明授权

EP0204456B1 A hydrolyzable resin composition and an antifouling coating composition containing the same 失效
标题翻译：可水解的树脂组合物和含有它的防粘涂料组合物
公开(公告)号：EP0204456B1
公开(公告)日：1991-10-09
申请号：EP86303760.2
申请日：1986-05-16
申请人： Nippon Paint Co., Ltd.
发明人： Yamamori, Naoki , Ohsugi, Hiroharu , Eguchi, Yoshio , Yokoi, Junji
IPC分类号： C08F30/04 , C08G63/68 , C08G59/14 , C09D5/14
CPC分类号： C08G59/1433 , C08F30/04 , C08G63/68 , C09D5/165

8. 发明公开

EP0331266A1 Coating composition 失效
标题翻译：涂料组合物
公开(公告)号：EP0331266A1
公开(公告)日：1989-09-06
申请号：EP89200496.1
申请日：1989-02-28
申请人： NIPPON PAINT CO., LTD.
发明人： Takagawa, Ryozo , Tanabe, Hisaki , Ohsugi, Hiroharu , Eguchi, Yoshio , Asakura, Koji
IPC分类号： C09D133/00
CPC分类号： C09D133/14 , C08L61/20 , C08L101/00 , C08L2666/14
摘要： The invention provide a coating composition comprising

(a) a film-forming polymer having a functional group which is reactive with the under-mentioned crosslinking agent,
(b) an organic liquid diluent ,and
(c) a crosslinking agent , which is characterized by that said film-forming polymer is an acrylic homo - or co-polymer having at least one side chain of the formula:
in which n is a positive number of 3 - 50. contains metallic or non-metallic pigment ,and also a coating composition comprising the abovementioned

(a),(b),(c) and (d) crosslinked polymer microparticles obtained by an emulsion polymerization of two or more ethylenically unsaturated monomers in the presence of a resin having in its molecule a group of the formula:
in which R is a substituted or unsubstituted alkylene having 1 to 6 carbon atoms or phenylene and Y is -COOH or -S0 3 H.

These compositions are specifically useful as a top coat for automobile body, appliances or the like.
摘要翻译：本发明提供了一种涂料组合物，其包含（a）具有可与下述交联剂反应的官能团的成膜聚合物，（b）有机液体稀释剂和（c）交联剂，其特征在于：所述成膜聚合物是具有下式的至少一个侧链的丙烯酸均聚物或共聚物：其中n为3〜50的正数。含有金属或非金属颜料，以及涂料组合物（a），（b），（c）和（d）交联聚合物微粒，所述交联聚合物微粒通过在分子中具有下式基团的树脂存在下通过两种或更多种烯属不饱和单体的乳液聚合获得：其中R是具有1至6个碳原子的取代或未取代的亚烷基或亚苯基，并且Y是-COOH或-SO 3 H. 这些组合物特别用作汽车车身，器具等的面漆。

9. 发明公开

EP0329260A2 Resinous composition for coating use 失效
标题翻译： Harzususenszung zur Verwendung beiUeberzügen。
公开(公告)号：EP0329260A2
公开(公告)日：1989-08-23
申请号：EP89200415.1
申请日：1989-02-20
申请人： NIPPON PAINT CO., LTD. , SHINETSU CHEM. IND. LTD.
发明人： Ohsugi, Hiroharu , Kanakura, Akihiro , Umemoto, Hirotoshi , Okamura, Yoshio , Takarada, Mitsuhiro , Yamamoto, Kenji c/o Shinetsu Chem. Ind. Ltd.
IPC分类号： C08L83/06 , C09D183/04 , C08L101/06
CPC分类号： C09D183/06 , C08L83/06 , C09D133/06 , C09D201/06 , C08L2666/14 , C08L2666/04
摘要： A resinous composition for coating use comprising

(a) 3 to 70% by weight of organopolysiloxane represented by the formula: R¹ n R² m SiO (4-n-m)/2
wherein R¹ represents hydrogen, allyloxy group, an alkoxy group having 1 to 20 carbon atoms, an aryl group, methyl group, or an organic group having 2 to 100 carbon; R² is a hydroxyl group bearing organic group having 2 to 100 carbon atoms; m and n each represents a positive number fulfiling the requirements of 0
(b) 97 to 30% by weight of hydroxyl group containing resin having a hydroxyl value of 20 to 300, and
(c) crosslinking agent which is reactive with hydroxyl group
This composition is particularly useful in the area in where durability and weather resistance of the formed coating are specifically required.
摘要翻译：一种用于涂料用途的树脂组合物，其包含（a）3-70重量％由下式表示的有机聚硅氧烷：R 1 nR 2 mSiO（4-nm）/ 2其中R 1表示氢，烯丙氧基，碳原子数1〜20的烷氧基，芳基，甲基或碳原子数2〜100的有机基团; R 2是具有2至100个碳原子的带羟基的有机基团; m和n各自表示满足0

10. 发明公开

EP0320537A1 A vinyl polymer containing silicons and preparation thereof 失效
标题翻译： Silikon enthaltende Vinylpolymere und deren Herstellung。
公开(公告)号：EP0320537A1
公开(公告)日：1989-06-21
申请号：EP87202584.6
申请日：1987-12-18
申请人： Nippon Paint Co., Ltd.
发明人： Ohsugi, Hiroharu , Eguchi, Yoshio , Urano, Satoshi , Mizuguchi, Ryuzo
IPC分类号： C08F8/42 , C08F230/08
CPC分类号： C08F8/42 , C08F230/08
摘要： A novel class of vinyl polymers containing silicons having in its molecule at least one constitutent unit of the formula
wherein R 1 is a substituted or unsubstituted monovalent hydrocarbon residue; R 2 is
R 3 is hydrogen or methyl group; R 4 is a substituent directly bonded to silicon atom and is selected from a substituted or unsubstituted alkylene, or a substituted or unsubstituted alkylene containing hetero atoms; m and n each is a positive number, which will fulfil the requirement of 2≦ m+n ≦4; A is a direct bond,

phenylene or substituted phenylene; B is
R 5 and R 6 each represents an alkylene, providing that when A is-
, m±n is 2.
The present vinyl polymers are very useful in various technical fields including preparation of lens and other molding products, paints and various instrial resins.
摘要翻译：一类含有硅酮的乙烯基聚合物，其分子中至少有一个式CHEM的组分单元，其中R 1是取代或未取代的一价烃残基; R 2是氢或甲基; R 4是与硅原子直接键合的取代基，其选自取代或未取代的亚烷基，或取代或未取代的含有杂原子的亚烷基; m和n每个都是正数，这将满足2

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