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    • 6. 发明公开
    • ZINC-PLATED STEEL SHEET FOR HOT PRESSING HAVING OUTSTANDING SURFACE CHARACTERISTICS, HOT-PRESSED MOULDED PARTS OBTAINED USING THE SAME, AND A PRODUCTION METHOD FOR THE SAME
    • VERZINKTES STAHLBLECH ZUR HEISSPRESSUNG MIT AUSGEZEICHNETENOBERFLÄCHENEIGENSCHAFTEN,DAMIT ERHALTENE HEISSGEPRESSTE FORMTEILE UND HERSTELLUNGSVERFAHRENDAFÜR
    • EP2520686A4
    • 2017-08-30
    • EP10841224
    • 2010-12-28
    • POSCO
    • SOHN IL-RYOUNGKIM JONG-SANGPARK JOONG-CHULCHO YEOL-RAEOH JIN-KEUNCHO HAN-GUCHUNG BONG-HOONLEE JONG-SEOG
    • C23C8/10C22C38/00C22C38/04C23C2/02C23C2/06C23C2/28C23C2/40
    • C23C2/28C22C38/001C22C38/04C23C2/02C23C2/06C23C2/40C23C8/10Y10T428/12799Y10T428/12917Y10T428/12924Y10T428/12931Y10T428/12937Y10T428/12951Y10T428/12958
    • In one aspect of the present invention, provided is a zinc-plated steel sheet for hot pressing having outstanding surface characteristics, comprising: a steel foundation plate comprising a metal surface diffusion layer of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr, to a depth of 1 µm from the surface; an aluminium-rich layer containing at least 30 wt.% of aluminium formed on the surface diffusion layer of the metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr; and a zinc plating layer formed on the aluminium-rich layer; wherein annealing oxides having a mean thickness of no more than 150 nm are distributed in a non-continuous fashion between the surface diffusion layer and the aluminium-rich layer, and there is a content of at least 0.1 wt.% of the metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr, to a depth of 1 µm from the surface of the steel foundation plate. In this way, a metal having a low affinity for oxygen is coated to an effective thickness prior to annealing and thus the creation of annealing oxides at the surface of the steel sheet is suppressed and a uniform zinc plating layer is formed, and alloying of the zinc plating layer is promoted during press-processing heat treatment such that the melting temperature of the zinc plating layer is increased within a short time, thereby making it possible to prevent deterioration of the plating layer and to minimise the occurrence of internal oxides formed after hot press moulding. Also, according to another aspect of the present invention, an oxide layer able to prevent deterioration of the zinc plating layer is formed on the surface of the plating layer during hot press heating, and a three element phase of Zn, Fe and the metal is formed in the plating layer such that the zinc plating layer can be kept stable, good surface conditions are ensured and the phosphatability is outstanding, the plating properties during electrodeposition plating and film adhesion can be ensured even without carrying out a separate phosphating process, and workability can be improved as cracking in the steel foundation plate during hot press moulding is prevented.
    • 在本发明的一个方面中,提供具有突出表面特性的用于热压的镀锌钢板,其包括:钢基础板,其包含金属表面扩散层,其中氧化期间每摩尔氧的吉布斯自由能下降是 小于Cr的深度,距离表面1μm的深度; 在金属的表面扩散层上形成的含有至少30重量%铝的富铝层,其中在氧化过程中每摩尔氧的吉布斯自由能降低小于Cr的摩尔数; 以及在富铝层上形成的镀锌层; 其中平均厚度不超过150nm的退火氧化物以不连续的方式分布在表面扩散层和富铝层之间,并且其中金属的含量至少为0.1重量% 氧化期间每摩尔氧的吉布斯自由能降低小于Cr的自由能降低至距钢基板表面1μm的深度。 这样,在退火之前将对氧的亲和力低的金属涂覆成有效厚度,从而抑制了钢板表面处的退火氧化物的产生,并形成了均匀的镀锌层,并且合金化了 在压制加工热处理期间促进镀锌层,使得镀锌层的熔化温度在短时间内增加,由此使得能够防止镀层的劣化并且使热后形成的内部氧化物的发生最小化 压模成型。 此外,根据本发明的另一方面,在热压加热过程中,在镀层的表面上形成能够防止镀锌层劣化的氧化物层,并且Zn,Fe和金属的三元素相为 形成在镀层中,使得锌镀层能够保持稳定,确保良好的表面条件,并且可磷化性优异,即使不进行单独的磷化处理也可以确保电沉积镀覆和膜附着期间的镀覆性能,并且可加工性 可以防止热压成型时钢基板的开裂。