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    • 1. 发明公开
    • Polyether phosphate esters
    • 聚醚磷酸酯
    • EP0551760A2
    • 1993-07-21
    • EP92311752.7
    • 1992-12-23
    • OCEANFLOOR LIMITED
    • Cracknell, Robert BrianMoore, Anthony James
    • C08G65/32C10M107/34
    • C08G65/327C10M137/04C10M137/06C10M2209/103C10M2209/104C10M2209/105C10M2209/107C10M2215/042C10M2221/043C10M2223/04C10M2223/042C10M2225/00C10M2225/02C10N2220/02C10N2240/08C10N2240/10C10N2240/101C10N2240/102C10N2240/103C10N2240/104C10N2240/106
    • A polyalkylene glycol ether phosphate ester, or salt thereof, having the formula:



              R w -P(O)(OH) 3-w    (I)



      wherein w is an integer from 1 to 3, and
         R is an oil-soluble polyether moiety having the formula:



              R¹X[(C x H 2x O) n (C y H 2y O) p ] m    (II)



      wherein R¹ is either an alkyl or an alkyl phenyl group having from 7 to 30 carbon atoms,
         X is either O, S, or N
         x is an integer from 2 to 4,
         y is an integer from 6 to 30,
         m is 1 when X is O or S and m is 2 when X is N,
         n and p are such that the polyether moiety contains between 1 and 35% by weight of (C y H 2y O) units and between 35 and 80% by weight of (C x H 2x O) units, and the molecular weight of the polyalkylene glycol moiety is between 500 and 5000 is disclosed.
      The phosphate ester can be prepared by reacting a polyether with a phosphating agent, e.g. phosphorus pentoxide and water. Lubricating oil compositions comprising the phosphate ester or salt thereof are also disclosed. The phosphate esters and salts thereof are useful as extreme pressure/anti-wear additives.
    • 具有下式的聚亚烷基二醇醚磷酸酯或其盐:Rw-P(O)(OH)3-w(I)其中w是1至3的整数,R是油溶性聚醚部分, 其中R 1是具有7至30个碳原子的烷基或烷基苯基,X是O,S或N,X是整数,其中R 1是具有7至30个碳原子的烷基或烷基苯基, 2至4,y是6至30的整数,当X是O或S时m是1,当X是N时m是2,n和p使得聚醚部分含有1至35重量%的 (CyH2yO)单元和35-80重量%的(CxH2xO)单元,并且聚亚烷基二醇部分的分子量为500-5000。 磷酸酯可以通过使聚醚与磷化剂例如磷酸盐反应来制备。 五氧化二磷和水。 还公开了包含磷酸酯或其盐的润滑油组合物。 磷酸酯及其盐可用作极压/抗磨添加剂。