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    • 9. 发明公开
    • PROPYLENE RANDOM BLOCK COPOLYMER, RESIN COMPOSITIONS CONTAINING THE COPOLYMER, AND MOLDINGS OF BOTH
    • 统计学友好型丙烯酸酯聚合物,DAS共聚物ENTHALTENDE HARZZUSAMMENSETZUNGEN UNDFORMKÖRPERAUS BEIDEN
    • EP2006314A2
    • 2008-12-24
    • EP07739740.4
    • 2007-03-27
    • Mitsui Chemicals, Inc.Prime Polymer Co., Ltd.
    • ITAKURA, KeitaHASHIZUME, SatoshiTAKESUE, KunihikoFUNAYA, Munehito
    • C08F297/08C08L53/00
    • C08F297/083C08L23/142C08L2207/02C08L23/16
    • The invention provides a propylene random block copolymer (A) that has a melt flow rate from 0.1 to 100 g/10 min and a melting point from 100 to 155°C and includes 90 to 60% by weight of a portion insoluble (D insol ) in n-decane at room temperature and 10 to 40% by weight of a portion soluble (D sol ) in n-decane at room temperature, wherein the D insol satisfies the following requirements (1) through (3) and the D sol satisfies the following requirements (4) through (6). The invention further provides molded articles such as sheets, films, injection molded articles, hollow molded articles, injection blow molded articles and fibers, which are formed of the propylene random block copolymer (A) or a propylene resin composition containing the propylene random block copolymer (A). (1) The molecular weight distribution (Mw/Mn) obtained by GPC of the D insol is from 1.0 to 3.5, (2) the content of skeletons derived from ethylene in the D insol is from 0.5 to 13% by mole, (3) the total amount of 2,1- and 1,3-propylene units in the D insol is 0.2% by mole or less, (4) the molecular weight distribution (Mw/Mn) obtained by GPC of the D sol is from 1.0 to 3.5, (5) the intrinsic viscosity [η] in decalin at 135°C of the D sol is from 1.5 to 4 dl/g and (6) the content of skeletons derived from ethylene in the D sol is from 15 to 35% by mole.
    • 本发明提供一种丙烯无规嵌段共聚物(A),其熔体流动速率为0.1-100g / 10min,熔点为100-155℃,包括90-60wt%不溶部分(D insol )和在室温下在正癸烷中的10〜40重量%的可溶解(D sol)部分,其中D insol满足以下要求(1)〜(3),D sol 满足以下要求(4)〜(6)。 本发明还提供了由丙烯无规嵌段共聚物(A)形成的成型制品,例如片材,薄膜,注塑制品,中空成型制品,注塑吹塑制品和纤维,或含丙烯无规嵌段共聚物 (一个)。 (1)D insol的GPC得到的分子量分布(Mw / Mn)为1.0〜3.5,(2)D insol中的来自乙烯的骨架的含量为0.5〜13摩尔%,(3 )D insol中2,1-和1,3-丙烯单元的总量为0.2摩尔%以下,(4)通过D sol的GPC得到的分子量分布(Mw / Mn)为1.0 至3.5,(5)D sol的135℃萘烷中的特性粘度[η]为1.5〜4dl / g,(6)D sol中衍生自乙烯的骨架含量为15〜35 %摩尔。