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    • 1. 发明公开
    • Method for controlling oxidation in flue gas desulfurization
    • 在阿巴斯特里弗弗隆,维尔法赫恩zur Oxidationskontrolle
    • EP1386654A1
    • 2004-02-04
    • EP03024625.0
    • 1997-06-26
    • MITSUBISHI JUKOGYO KABUSHIKI KAISHA
    • Iwashita, KoichiroOkino, SusumuUkawa, NaohikoSakamoto, Masaru
    • B01D53/34G01N27/416
    • B01D53/501B01D53/346Y10S423/05
    • There is provided a method for flue gas desulfurization which is capable of conducting minute control of oxidation and which is capable of maintaining the concentration of sulfurous acid in an absorbent liquid within a proper range in a highly reliable and efficient manner, even in the case where an abrupt change occurs in the operational conditions of the system. In the method for controlling the oxidation in flue gas desulfurization, the value of proportional sensitivity (K) in the feed back control process, which is based primarily on the oxidation-reduction potential (ORP), is increased depending on the deviation (ε) in a region where the detected value (PV) is below the target value (SV) in correspondence with the characteristic change of the oxidation-reduction potential against the concentration of sulfurous acid (PN).
    • 提供了一种烟气脱硫方法,其能够进行微小的氧化控制,并且能够以高度可靠和有效的方式将吸收液中的亚硫酸浓度保持在适当范围内,即使在 系统的运行状况发生突然变化。 在烟气脱硫控制方法中,反馈控制过程中主要依赖氧化还原电位(ORP)的比例灵敏度(K)值取决于偏差(ε), 在与氧化还原电位相对于亚硫酸浓度(PN)的特征变化对应的检测值(PV)低于目标值(SV)的区域中。
    • 2. 发明公开
    • Wet flue gas desulfurization system
    • Vorrichtung zur Nassentschwefelung von Rauchgas
    • EP0793994A1
    • 1997-09-10
    • EP97610002.4
    • 1997-02-06
    • MITSUBISHI JUKOGYO KABUSHIKI KAISHA
    • Tatani, AtsushiOkazoe, KiyoshiNakayama, YoshioIwashita, Koichiro
    • B01D53/50
    • B01D53/504B01D61/025B01D61/027B01D61/08B01D61/12C02F1/42C02F1/44C02F1/441C02F1/442Y02A20/131
    • This invention provides a wet flue gas desulfurization system for removing sulfur dioxide present in flue gas by absorption into an absorbent slurry, which comprises an absorption tower (1) having at the bottom thereof a tank (2) for holding an absorbent slurry; a circulating pump (4) for feeding the absorbent slurry within the tank to a flue gas inlet section (la) in the upper part of the absorption tower and bringing the absorbent slurry into contact with flue gas; and a slurry preparation compartment (22) provided on one side of the tank of the absorption tower and separated from the flue gas passage section (26) by a partition wall (21) having its lower end submerged below the surface of the absorbent slurry, whereby an absorbent and water constituting the absorbent slurry are directly introduced into the slurry preparation compartment. Thus, the absorbent supply system is improved to achieve a marked simplification of the equipment.
    • 本发明提供了一种用于通过吸收到吸收剂浆料中来除去烟道气中存在的二氧化硫的湿式烟道气脱硫系统,该吸收剂浆料包括吸收塔(1),该吸收塔在其底部具有用于保持吸收剂浆料的罐(2) 循环泵(4),用于将容器内的吸收剂浆料供给到吸收塔上部的烟道气入口部分(1a),并使吸收剂浆料与烟气接触; 以及设置在所述吸收塔的所述槽的一侧上并且通过分隔壁(21)与所述烟道气体通道部分(26)分离的浆料制备室(22),所述分隔壁的下端浸没在所述吸收剂浆料的表面下方, 由此将构成吸收剂浆料的吸收剂和水直接引入浆料制备室。 因此,改进吸收剂供应系统以实现设备的显着简化。
    • 5. 发明公开
    • Boiler flue gas desulfuriser with heat recovery means
    • EntschwefelungsvorrichtungfürHeizkesselrauchgase mitWärmerückgewinnungsmitteln
    • EP0768108A1
    • 1997-04-16
    • EP96610039.8
    • 1996-10-11
    • MITSUBISHI JUKOGYO KABUSHIKI KAISHA
    • Iijima, MasakiTatani, AtsushiKimura, KazuakiIwashita, KoichiroYajima, SatoshiTakashina, Toru, Mitsubishi Jukogyo K.K.Okino, Susumu Mitsubishi Jukogyo K.K.
    • B01D53/50
    • B01D53/504
    • This invention relates to a flue gas desulfurizer (7) having an absorption tower (21) for bringing untreated flue gas into gas-liquid contact with an absorbent slurry, wherein there is provided heat recovery means (12) for recovering heat from the flue gas passing through the flue gas inlet section (21a) of the absorption tower prior to gas-liquid contact, and to a boiler equipment including such a flue gas desulfurizer (7), heat transport means (13), and heat releasing the recovered heat to heat utilization equipment (11). This invention also relates to thermal electric power generation equipment including extraction feedwater heaters (121-128) for heating boiler feedwater with steam from steam turbines (103, 106, 108, 109), a flue gas desulfurizer (7) using an absorbent slurry, and means for recovering heat (161) from the flue gas passing through the flue gas desulfurizer and/or the absorbent slurry within the flue gas desulfurizer, whereby boiler feedwater is preheated by the recovered heat and then introduced into the extraction feedwater heaters.
    • 本发明涉及一种具有吸收塔(21)的烟道气脱硫器(7),该吸收塔用于将未经处理的烟道气与吸收剂浆料气液接触,其中设置有用于从烟道气中回收热量的热回收装置(12) 在气液接触之前通过吸收塔的烟道气体入口部分(21a),以及包括这种烟道气脱硫器(7)的锅炉设备,热传输装置(13),并将回收的热量释放到 热利用设备(11)。 本发明还涉及一种热发电设备,其包括用于使用蒸汽轮机(103,106,108,109)的蒸汽加热锅炉给水的提取给水加热器(121-128),使用吸收剂浆料的烟道气脱硫器(7) 以及用于从通过烟道气脱硫器和/或烟道气脱硫器内的吸收剂浆料的烟道气回收热量(161)的装置,由锅炉给水通过回收的热量预热,然后引入提取给水加热器。