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1. 发明公开

EP1452550A4 CURABLE COMPOSITION 审中-公开
标题翻译： HÄRTBAREZUSAMMENSETZUNG
公开(公告)号：EP1452550A4
公开(公告)日：2005-03-30
申请号：EP02803115
申请日：2002-11-13
申请人： KANEKA CORP
发明人： OHSHIRO NOBUAKI , TSUJI RYOTARO , HIIRO TOMOKI
IPC分类号： C08F2/38 , C08F8/42 , C08F220/00 , C08L101/00 , C08L101/10
CPC分类号： C08L101/10 , C08F2/38 , C08F220/00
摘要： The invention provides a curable composition comprising a polymer A bearing crosslinkable silyl groups and a condensation catalyst B. This polymer A is produced by a process which comprises the step of conducting radical polymerization of radical-polymerizable monomers in the presence of a thiocarbonylthio compound, specifically, a process which comprises the step i of initiating the polymerization of a radical-polymerizable monomer by reversible addition -fragmentation chain transfer in the presence of a thiocarbonylthio compound and the step ii of adding an unsaturated compound having a crosslinkable silyl group at the stage wherein the consumption of the radical-polymerizable monomer by the polymerization reaches 80 % or above and subjecting the resulting mixture to copolymerization.
摘要翻译：本发明提供了一种可固化组合物，其包含带有可交联甲硅烷基的聚合物A和缩合催化剂B.该聚合物A通过包括在硫代羰基硫代化合物存在下进行自由基可聚合单体的自由基聚合的步骤包括步骤i：在硫代羰基硫代化合物存在下通过可逆加成 - 断裂链转移引发可自由基聚合单体的聚合，和步骤ii：在步骤ii中加入具有可交联甲硅烷基的不饱和化合物，通过聚合消耗自由基聚合性单体达到80％以上并使所得混合物共聚。

2. 发明公开

EP0857746A4 PROCESS FOR THE PREPARATION OF SILOXANE COPOLYMERS AND RESIN COMPOSITIONS CONTAINING THE SILOXANE COPOLYMERS PREPARED BY THE PROCESS 失效
标题翻译：工艺通过该方法和含有该硅氧烷共聚物树脂组合物制备得到的硅氧烷共聚物
公开(公告)号：EP0857746A4
公开(公告)日：1999-11-24
申请号：EP97935799
申请日：1997-08-15
申请人： KANEKA CORP
发明人： HIIRO TOMOKI , OHSHIMA KOJI , AOYAMA TAIZO
IPC分类号： C08G63/695 , C08G64/18 , C08G77/445 , C08G77/448 , C08L83/10
CPC分类号： C08G64/186 , C08G63/6956 , C08G77/445 , C08G77/448
摘要： A process for the preparation of siloxane copolymers by reacting at least one silicon compound of general formula (I) or (II) with at least one diol and at least one dicarbonate in the presence of an esterification or transesterification catalyst, wherein R , R , R and R are each independently hydrogen or an optionally substituted organic group; X and Y are each independently hydrogen or an optionally substituted organic group; a is an integer of 0 to 5000; and b is an integer of 3 to 20.

3. 发明公开

EP1887041A4 RESIN COMPOSITION 审中-公开
标题翻译：树脂组合物
公开(公告)号：EP1887041A4
公开(公告)日：2008-08-13
申请号：EP06746899
申请日：2006-05-26
申请人： KANEKA CORP
发明人： TANAKA KATSUYUKI , KAWABATA HIROSUKE , HIIRO TOMOKI
IPC分类号： C08L33/06 , C08F8/48
CPC分类号： C08L33/24 , C08F8/32 , C08F8/48 , C08F2800/20 , C08L35/06 , C08L2666/04 , C08F120/14 , C08F220/14
摘要： Disclosed is a resin composition wherein birefringence is controlled. Specifically disclosed is a resin composition essentially containing a resin (A) containing a glutarimide unit and an acrylate unit, and another resin (B) containing a glutarimide unit, an acrylate unit and an aromatic vinyl unit. This resin composition can be easily produced at low cost, and is excellent in transparency and heat resistance. In particular, orientational birefringence can be easily controlled in this resin composition. This resin composition can be used for molded bodies for optical applications which require transparency and heat resistance.

4. 发明公开

EP1375531A4 PROCESS FOR PRODUCING VINYL POLYMER HAVING ALKENYL GROUP AT END, VINYL POLYMER, AND CURABLE COMPOSITION 审中-公开
标题翻译：用于生产乙烯基聚合物链烯基封端的，乙烯基聚合物和固化性组合物
公开(公告)号：EP1375531A4
公开(公告)日：2006-02-08
申请号：EP02700691
申请日：2002-02-21
申请人： KANEKA CORP
发明人： TSUJI RYOTARO , HIIRO TOMOKI
IPC分类号： C08K5/00 , C08F2/38 , C08F2/44 , C08F8/00 , C08F8/30 , C08F8/32 , C08F8/34 , C08F8/42 , C08F257/02 , C08F261/04 , C08F265/04 , C08F273/00 , C08F283/00 , C08F290/04 , C08F290/06 , C08F291/00 , C08F299/00 , C08L55/00 , C08L83/05
CPC分类号： C08F291/00 , C08F2/38 , C08F8/30 , C08F8/32 , C08F8/34 , C08F8/42 , C08F257/02 , C08F261/04 , C08F265/04 , C08F273/00 , C08F283/008 , C08F290/04 , C08F290/06
摘要： A process for easily producing an alkenyl-terminated vinyl polymer without using a metal compound necessitating a complicated purification step; and a curable composition containing the vinyl polymer. An alkenyl group is incorporated into an end of a vinyl polymer having a thiocarbonylthio structure at the end to produce an alkenyl-terminated vinyl polymer. Mixing this vinyl polymer with a compound having a hydrogen-silicon bond and a hydrosilylation catalyst gives the curable composition.

5. 发明公开

EP3163334A1 RESIN COMPOSITION FOR OPTICAL APPLICATIONS, AND FILM 有权
标题翻译： HARZZUSAMMENSETZUNGFÜROPTISCHE ANWENDUNGEN UND FILM
公开(公告)号：EP3163334A1
公开(公告)日：2017-05-03
申请号：EP15814533
申请日：2015-06-29
申请人： KANEKA CORP
发明人： KITAYAMA FUMINOBU , KOYAMA HARUKI , HIIRO TOMOKI
IPC分类号： G02B5/30 , C08F265/06 , C08L33/00 , C08L51/00
CPC分类号： C08L33/00 , C08F265/06 , C08J5/18 , C08J2333/00 , C08L51/00 , C08L2203/16 , G02B1/04 , G02B1/14 , G02B5/30 , G02B5/3033
摘要： Provided is an optical resin composition from which a film with improved adhesion to a polyvinyl alcohol-based film and improved flex resistance can be obtained while keeping high film transparency. The provided optical resin composition includes: 99 to 50 % by weight of an acrylic resin having a glass transition temperature of not lower than 110 °C; and 1 to 50 % by weight of a particulate (meth)acrylic multilayer structure graft copolymer. The (meth)acrylic multilayer structure graft copolymer contains: an innermost layer made of a polymer containing a methacrylic acid ester as its main monomer; a middle layer made of a polymer containing, as its main monomer, an acrylic acid alkyl ester having an alkyl group with 4 to 12 carbon atoms; and an outermost layer made of a polymer containing a methacrylic acid ester as its main monomer. A graft ratio of the (meth)acrylic multilayer structure graft copolymer is not less than 40 %.
摘要翻译：本发明提供一种光学用树脂组合物，能够在保持高的膜透明性的同时获得与聚乙烯醇系膜的密合性提高，耐弯曲性提高的膜。提供的光学树脂组合物包含：99至50重量％的玻璃化转变温度不低于110℃的丙烯酸树脂; 和1至50重量％的粒状（甲基）丙烯酸多层结构接枝共聚物。（甲基）丙烯酸类多层结构体接枝共聚物含有：以含有甲基丙烯酸酯作为主要单体的聚合物构成的最内层，由含有具有4-12个碳原子的烷基的丙烯酸烷基酯作为其主要单体的聚合物制成的中间层; 和由含有甲基丙烯酸酯作为其主要单体的聚合物制成的最外层。（甲基）丙烯酸多层结构接枝共聚物的接枝率不小于40％。

6. 发明公开

EP1403291A4 PROCESS FOR PRODUCING POLYMER HAVING CROSSLINKABLE SILYL GROUP AND CURABLE COMPOSITION 有权
标题翻译：工艺制备聚合物可交联甲硅烷基和可固化组合物
公开(公告)号：EP1403291A4
公开(公告)日：2006-02-08
申请号：EP02724789
申请日：2002-05-14
申请人： KANEKA CORP
发明人： TSUJI RYOTARO , HIIRO TOMOKI
IPC分类号： C08F2/00 , C08F2/38 , C08F8/42 , C08G18/24 , C08G18/62 , C08G18/71
CPC分类号： C08F8/42 , C08F2/38 , C08F2438/03 , C08G18/242 , C08G18/6287 , C08G18/718 , C08L27/06 , C08L33/12 , C08L67/02 , C08L69/00 , C08L2666/04 , C08L2666/12
摘要： A process for producing a crosslinkable-silyl-containing polymer which is excellent in oil resistance, heat resistance, weatherability, and compression set properties and less apt to be fouled. It comprises the step of radical-polymerizing a vinyl monomer in the presence of a compound of a specific structure having a thiocarbonylthio group and the step of incorporating crosslinkable silyl groups. Also provided is a curable composition which contains the polymer and is easy to handle.
摘要翻译：交联聚合物含甲硅烷基的制备包括：（A）在含有硫代羰基（I）和（II），（B）将所述聚合物中的硫代羰基引入巯基和（c）的化合物的存在下乙烯基系单体进行自由基聚合聚合物偶联用含有交联甲硅烷基和异氰酸酯基团的化合物（A），通过巯基。交联聚合物含甲硅烷基的制备包括：（A）在含有结构式（I）和（II），（B）将所述硫代羰基所得到的聚合物中的成巯基和硫代羰基的化合物的存在下乙烯基系单体进行自由基聚合（c）中通过巯基交联甲硅烷基和异氰酸酯基耦合。具有一个或多个碳原子上[图像] R1> p价有机基团，所述有机基团含有选自N，O，S，卤素，硅，磷或金属原子worin原子，或者是聚合物; Z1> H，具有一个或多个碳原子的卤素，或单价有机基团，所述有机基团含有选自N，O，S，卤素，硅，磷或金属原子worin原子，或者是聚合物; 号码：1或更大; R2>含有一个或多个碳原子，worin一价有机基团含有选自N，O，S，卤素，硅，磷或金属原子原子，或者是聚合物的一价有机基团; 和q：2或更大。因此独立权利要求中包括了以下内容：（1）获得的聚合物，和（2）固化组合物，含有该聚合物。

7. 发明公开

EP0992519A4 BLOCK COPOLYMER 有权
标题翻译：嵌段共聚物
公开(公告)号：EP0992519A4
公开(公告)日：2001-04-11
申请号：EP99917208
申请日：1999-04-28
申请人： KANEKA CORP
发明人： NAKAGAWA YOSHIKI , FUJITA MASAYUKI , KITANO KENICHI , HIIRO TOMOKI , KIMURA KATSUHIKO
IPC分类号： C08F4/40 , C08F290/02 , C08F293/00 , C08F297/00 , C08F2/38 , C08F4/00 , C08K5/00 , C08L53/00
CPC分类号： C08F290/02 , C08F293/005 , C08F297/00 , C08F2438/01
摘要： A block copolymer which comprises any of various polymers and a polymer formed by radical living polymerization or cationic living polymerization and can be easily produced without the need of the difficult optimization of polymerization conditions, etc. The block copolymer is produced by adding a polymer (I) having an alkenyl group to a radical living polymerization system or cationic living polymerization system.

8. 发明公开

EP3163334A4 RESIN COMPOSITION FOR OPTICAL APPLICATIONS, AND FILM 有权
公开(公告)号：EP3163334A4
公开(公告)日：2018-01-17
申请号：EP15814533
申请日：2015-06-29
申请人： KANEKA CORP
发明人： KITAYAMA FUMINOBU , KOYAMA HARUKI , HIIRO TOMOKI
IPC分类号： G02B5/30 , C08F265/06 , C08L33/00 , C08L51/00
CPC分类号： C08L33/00 , C08F265/06 , C08J5/18 , C08J2333/00 , C08L51/00 , C08L2203/16 , G02B1/04 , G02B1/14 , G02B5/30 , G02B5/3033
摘要： Provided is an optical resin composition from which a film with improved adhesion to a polyvinyl alcohol-based film and improved flex resistance can be obtained while keeping high film transparency. The provided optical resin composition includes: 99 to 50 % by weight of an acrylic resin having a glass transition temperature of not lower than 110 °C; and 1 to 50 % by weight of a particulate (meth)acrylic multilayer structure graft copolymer. The (meth)acrylic multilayer structure graft copolymer contains: an innermost layer made of a polymer containing a methacrylic acid ester as its main monomer; a middle layer made of a polymer containing, as its main monomer, an acrylic acid alkyl ester having an alkyl group with 4 to 12 carbon atoms; and an outermost layer made of a polymer containing a methacrylic acid ester as its main monomer. A graft ratio of the (meth)acrylic multilayer structure graft copolymer is not less than 40 %.

9. 发明公开

EP1411070A4 BLOCK COPOLYMER 审中-公开
标题翻译：嵌段共聚物
公开(公告)号：EP1411070A4
公开(公告)日：2005-06-29
申请号：EP02741383
申请日：2002-07-01
申请人： KANEKA CORP
发明人： TSUJI RYOTARO , HIIRO TOMOKI
IPC分类号： C08F2/00 , C08F293/00 , C08L53/00
CPC分类号： C08L53/00 , C08F293/00 , C08F293/005
摘要： A block copolymer which is excellent in heat resistance, weatherability, oil resistance, flame retardancy, and cold resistance, can be economically produced, and has at least one polymer block consisting mainly of acrylonitrile or methacrylonitrile units; and a thermoplastic resin composition and elastomer composition each containing the block copolymer. The block copolymer is one obtained by the reversible addition−elimination chain transfer polymerization method in the presence of a compound having a thiocarbonylthio group.
摘要翻译：可以经济地制造耐热性，耐气候性，耐油性，阻燃性和耐寒性优异的嵌段共聚物，并且具有至少一个主要由丙烯腈或甲基丙烯腈单元组成的聚合物嵌段; 以及各自含有嵌段共聚物的热塑性树脂组合物和弹性体组合物。嵌段共聚物是在具有硫代羰基硫基的化合物存在下通过可逆加成 - 消除链转移聚合方法获得的嵌段共聚物。

10. 发明公开

EP1398353A4 THERMOPLASTIC RESIN COMPOSITION 有权
标题翻译：热塑性树脂组合物
公开(公告)号：EP1398353A4
公开(公告)日：2005-06-15
申请号：EP02769600
申请日：2002-05-14
申请人： KANEKA CORP
发明人： KANEDA YUTAKA , CHIBA TAKESHI , HIIRO TOMOKI
IPC分类号： C08F293/00 , C08F297/02 , C08L23/04 , C08L23/08 , C08L53/00 , C08L67/02 , C08L69/00 , C08L77/00 , C08L101/00
CPC分类号： C08L67/02 , C08F293/005 , C08F297/026 , C08L23/04 , C08L23/0815 , C08L53/00 , C08L69/00 , C08L77/00 , C08L101/00 , C08L2666/06 , C08L2666/02 , C08L2666/04 , C08L2666/14 , C08L2666/24
摘要： A thermoplastic resin composition which comprises a thermoplastic resin (a) and a block copolymer (b) comprising a methacrylic polymer block (A) and an acrylic polymer block (B).

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