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    • 3. 发明公开
    • NMR dectection probe
    • NMR探空仪
    • EP2700969A2
    • 2014-02-26
    • EP13181383.4
    • 2013-08-22
    • Jeol Resonance Inc.Kyoto University
    • Takegoshi, KiyonoriMizuno, Takashi
    • G01R33/31
    • G01R33/34G01R33/30G01R33/307G01R33/31G01R33/3403
    • There is disclosed a cooled NMR detection probe including a detection coil and an internal structure. If the internal structure shrinks, the position of the detection coil can be maintained. The detection coil is cooled sufficiently. The internal structure (65) mounted in a vacuum vessel (58) includes a radiation shield assembly (68), a connecting member (74), and a heat exchanger (80). The internal structure (65) is secured to the vacuum vessel (58) by a holding member (66). The holding member (66) has an elongated portion extending in an up-and-down direction such that inflow of heat via the holding member (66) is reduced to a minimum. A shield body (70) and the connecting member (74) exist in the heat conduction path going from the holding member (66) to the first heat exchanger (80). If the internal structure shrinks during cooling, the position of an upper portion of the first heat exchanger (80) hardly varies, thus suppressing displacement of a core module (54). The elongated portion can deform as the internal structure (65) shrinks (i.e., decreases in diameter).
    • 公开了包括检测线圈和内部结构的冷却的NMR检测探针。 如果内部结构收缩,则能够维持检测线圈的位置。 检测线圈被充分冷却。 安装在真空容器(58)中的内部结构(65)包括辐射屏蔽组件(68),连接构件(74)和热交换器(80)。 内部结构(65)通过保持构件(66)固定到真空容器(58)。 保持构件(66)具有沿上下方向延伸的细长部分,使得经由保持构件(66)的热量流入减少到最小。 在从保持构件(66)到第一热交换器(80)的热传导路径中存在屏蔽体(70)和连接构件(74)。 如果内部结构在冷却期间收缩,则第一热交换器(80)的上部的位置几乎不变化,从而抑制芯部模块(54)的位移。 当内部结构(65)收缩(即直径减小)时,细长部分可以变形。
    • 6. 发明公开
    • NMR detection module
    • 核磁共振Detektionsmodul
    • EP2700970A2
    • 2014-02-26
    • EP13181388.3
    • 2013-08-22
    • Kyoto UniversityJeol Resonance Inc.
    • Takegoshi, KiyonoriMizuno, Takashi
    • G01R33/31
    • G01R33/3403G01R33/307G01R33/31G01R33/34053
    • An NMR (nuclear magnetic resonance) detection module (such as an NMR probe) mounted in a vacuum vessel is offered. This module permits a transmit/receive coil to be cooled efficiently and to be placed closer to a sample container. The NMR detection module includes a core module (detection module) (54) consisting of a refrigerant block (118) and a transmit/receive coil formed on the inner surface of a detection hole (130). A sleeve (cylindrical partition wall) (122) forming a part of the vacuum vessel is inserted in the detection hole (130). A sample tube (56) is inserted in the sleeve (122). The refrigerant block (118) is connected to a heat exchanger via a support member (82). Since it is not necessary to form a bobbin inside the transmit/receive coil, the distance between the coil and the sample can be set small. Because the coil is entirely surrounded by the refrigerant block, the coil is cooled efficiently.
    • 提供安装在真空容器中的NMR(核磁共振)检测模块(如NMR探针)。 该模块允许发射/接收线圈被有效地冷却并且被放置得更靠近样品容器。 NMR检测模块包括由制冷剂块(118)和形成在检测孔(130)的内​​表面上的发射/接收线圈组成的核心模块(检测模块)(54)。 形成真空容器的一部分的套筒(圆筒形分隔壁)122被插入到检测孔130中。 样品管(56)插入套筒(122)中。 制冷剂块118经由支撑部件82与热交换器连接。 由于不需要在发送/接收线圈内部形成线轴,所以可以将线圈和样本之间的距离设定得较小。 由于线圈被制冷剂块完全包围,所以线圈被有效地冷却。
    • 7. 发明公开
    • Production of spectra with improved signal-to-noise ratio
    • Erzeugung von Spektren mit verbicultem Signal-zu-Rausch-Verhältnis
    • EP2388611A1
    • 2011-11-23
    • EP11166759.8
    • 2011-05-19
    • Jeol Resonance Inc.
    • Takegoshi, KiyonoriNishiyama, Yusuke
    • G01R33/46
    • G01R33/4625G01N24/08G01N2201/1245G01R33/5608
    • A spectrometer producing spectra with improved S/N. The spectrometer has: accumulation means for performing a measurement to obtain a data set containing N data points, repeating the measurement M times to obtain M spectral data sets or time-domain data sets S1 (d1 to dN) to SM (d1 to dN), and accumulating the M spectral data sets or time-domain data sets; means for creating sets S1 (dn) to SM (dn) of the data points contained in the M spectral data sets or time-domain data sets S1 (d1 to dN) to SM (d1 to dN) such that the data points of each one of the sets S1 (dn) to SM (dn) have the same ordinal number dn; correlation computing means for finding correlations between the sets S1 (dn) to SM(dn) to thereby find a correlation data set C(c1 to cN) indicating correlation strengths about the data points of the ordinal numbers; and computing means for finding either the product of an accumulated or anticipated spectrum having the N data points and obtained from the accumulation means or of a time-domain data set Sav(d1 to dN) and the correlation data set C(c1 to cN).
    • 光谱仪产生具有改进的S / N的光谱。 光谱仪具有:用于执行测量以获得包含N个数据点的数据集的累积装置,重复测量M次以获得M个频谱数据集或时域数据组S1(d1至dN)至SM(d1至dN) 并累积M个频谱数据集或时域数据集; 用于创建包含在M个频谱数据集或时域数据组S1(d1至dN)至SM(d1至dN)中的数据点的集合S1(dn)至SM(dn)的装置,使得每个 集合S1(dn)至SM(dn)中的一个具有相同的序数dn; 相关计算装置,用于找出集合S1(dn)至SM(dn)之间的相关性,从而找到指示关于序数的数据点的相关强度的相关数据集C(c1至cN) 以及用于查找具有N个数据点并从积累装置或时域数据集Sav(d1至dN)和相关数据集合C(c1至cN)获得的累积或预期频谱的乘积的计算装置, 。