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1. 发明公开

EP2772509A1 METHOD FOR PRODUCING EXPANDED POLYLACTIC ACID RESIN PARTICLE 有权
标题翻译：生产膨化聚乳酸树脂颗粒的方法
公开(公告)号：EP2772509A1
公开(公告)日：2014-09-03
申请号：EP12841440.6
申请日：2012-09-21
申请人： JSP Corporation
发明人： SHINOHARA Mitsuru , OIKAWA Masaharu
IPC分类号： C08J9/18 , C08L101/16
CPC分类号： C08J9/18 , C08J9/12 , C08J9/232 , C08J2300/16 , C08J2367/04
摘要： A process for producing polylactic acid-based resin expanded beads by releasing foamable resin particles, which are in a softened state and dispersed in a dispersing medium contained in a pressure resisting closed vessel, to an atmosphere having a pressure lower than that in the closed vessel together with the dispersing medium to foam and expand the foamable particles. The foamable resin particles are obtained by impregnating a physical blowing agent into resin particles which are formed of a modified polylactic acid resin modified with an epoxide and showing specific physical properties when melted.
摘要翻译：通过将处于软化状态并分散在耐压密闭容器中所含的分散介质中的可发泡树脂颗粒释放到压力低于密闭容器中的气氛的气氛中来生产聚乳酸基树脂发泡珠粒的方法与分散介质一起发泡并使可发泡颗粒膨胀。发泡性树脂颗粒通过将物理发泡剂浸渍到树脂颗粒中而获得，所述树脂颗粒由用环氧化物改性的改性聚乳酸树脂形成，并在熔融时显示出特定的物理性质。

2. 发明公开

EP2824136A1 POLYPROPYLENE RESIN FOAMED PARTICLES AND MOULDED ARTICLE OF POLYPROPYLENE RESIN FOAMED PARTICLES 有权
标题翻译：高分子聚丙烯酸树脂
公开(公告)号：EP2824136A1
公开(公告)日：2015-01-14
申请号：EP13758661.6
申请日：2013-02-08
申请人： JSP Corporation
发明人： CHIBA Takuya , OIKAWA Masaharu , SHINOHARA Mitsuru
IPC分类号： C08J9/16 , C08J9/228
CPC分类号： H01B1/24 , B29B9/06 , B29K2023/06 , B29K2023/12 , B29K2105/04 , B29K2507/04 , B29K2995/0005 , C08J9/224 , C08J2201/038 , C08J2323/12 , C08J2423/06
摘要： An electrostatic dissipative, polypropylene-based resin expanded bead having an expanded core layer of a polypropylene-based resin, and a cover layer that covers the expanded core layer and that is composed of a mixed resin containing electrically conductive carbon black, wherein the mixed resin includes a polypropylene resin which forms a continuous phase and a polyethylene resin which forms dispersed phases dispersed in the continuous phase, with the electrically conductive carbon black being unevenly distributed to the dispersed phases side. In-mold molding of the expanded beads gave a molded article.
摘要翻译：一种具有聚丙烯类树脂发泡芯层的静电耗散型聚丙烯类树脂发泡珠，覆盖该发泡芯层并由含有导电性炭黑的混合树脂构成的覆盖层，其中，混合树脂包括形成连续相的聚丙烯树脂和形成分散在连续相中的分散相的聚乙烯树脂，导电炭黑不均匀地分布在分散相侧。发泡珠的模内成型得到模塑制品。

3. 发明公开

EP2573133A1 EXPANDED PARTICLES OF POLYLACTIC ACID-BASED RESIN, AND MOLDINGS OF THE EXPANDED PARTICLES 有权
标题翻译：多达GEFORMTEGEGENSTÄNDE的EXPANDIERTEPOLYMILCHSÄURE-HARZPARTIKEL
公开(公告)号：EP2573133A1
公开(公告)日：2013-03-27
申请号：EP11783328.5
申请日：2011-03-24
申请人： JSP Corporation
发明人： SHINOHARA Mitsuru , OIKAWA Masaharu
IPC分类号： C08J9/16
CPC分类号： C08J9/122 , C08J9/16 , C08J9/18 , C08J9/232 , C08J2205/052 , C08J2367/02 , Y10T428/2989
摘要： The present invention is aimed at the provision of polylactic resin expanded beads that are suited to be molded in a mold and that permit stable production of a polylactic resin expanded beads-molded article having excellent fuse-bonding between the expanded beads without being restricted by the desired shape of the expanded beads-molded article. The polylactic resin expanded bead is formed of a polylactic resin as a base resin and is characterized in that an endothermic calorific value (Br:endo) [J/g] of the whole expanded bead, an endothermic calorific value (Brs:endo) [J/g] of a surface region of the expanded bead and an endothermic calorific value (Brc:endo) [J/g] of a center region of the expanded bead, as determined under specific Condition 1 in accordance with heat flux differential scanning calorimetry stipulated in JIS K7122(1987), meet the following formulas (1) and (2): Br : endo > 25 Brc : endo > Brs : endo ≥ 0
摘要翻译：本发明的目的在于提供适合于在模具中成型的聚乳酸树脂发泡珠粒，并且能够稳定地生产具有优异的膨胀珠粒之间的熔融粘合的聚乳酸树脂发泡珠粒成型体，而不受所需形状的发泡珠成型制品。聚乳酸树脂膨胀珠由聚乳酸树脂作为基础树脂形成，其特征在于，整个发泡珠的吸热量（Br：endo）[J / g]，吸热热值（Brs：endo）[ J / g]和根据热通量差示扫描量热法在特定条件1下测定的发泡珠的中心区域的吸热量（Brc：endo）[J / g] 在JIS K7122（1987）中规定，符合下列公式（1）和（2）：Br：endo> 25 Brc：endo> Brs：endo‰¥0

4. 发明授权

EP2824136B1 POLYPROPYLENE RESIN FOAMED PARTICLES AND MOULDED ARTICLE OF POLYPROPYLENE RESIN FOAMED PARTICLES 有权
标题翻译：聚丙烯树脂发泡颗粒及聚丙烯发泡颗粒成型制品
公开(公告)号：EP2824136B1
公开(公告)日：2017-12-06
申请号：EP13758661.6
申请日：2013-02-08
申请人： JSP Corporation
发明人： CHIBA Takuya , OIKAWA Masaharu , SHINOHARA Mitsuru
IPC分类号： C08J9/224 , H01B1/24
CPC分类号： H01B1/24 , B29B9/06 , B29K2023/06 , B29K2023/12 , B29K2105/04 , B29K2507/04 , B29K2995/0005 , C08J9/224 , C08J2201/038 , C08J2323/12 , C08J2423/06
摘要： An electrostatic dissipative, polypropylene-based resin expanded bead having an expanded core layer of a polypropylene-based resin, and a cover layer that covers the expanded core layer and that is composed of a mixed resin containing electrically conductive carbon black, wherein the mixed resin includes a polypropylene resin which forms a continuous phase and a polyethylene resin which forms dispersed phases dispersed in the continuous phase, with the electrically conductive carbon black being unevenly distributed to the dispersed phases side. In-mold molding of the expanded beads gave a molded article.

5. 发明授权

EP2573133B1 POLYLACTIC RESIN EXPANDED BEADS AND MOLDED ARTICLE OF THE EXPANDED BEADS 有权
标题翻译：膨胀的聚乳酸树脂颗粒和制品形状的物体
公开(公告)号：EP2573133B1
公开(公告)日：2016-08-10
申请号：EP11783328.5
申请日：2011-03-24
申请人： JSP Corporation
发明人： SHINOHARA Mitsuru , OIKAWA Masaharu
IPC分类号： C08J9/12 , C08J9/18 , C08J9/16 , C08J9/232
CPC分类号： C08J9/122 , C08J9/16 , C08J9/18 , C08J9/232 , C08J2205/052 , C08J2367/02 , Y10T428/2989

6. 发明授权

EP2657279B1 POLYLACTIC ACID RESIN EXPANDED BEADS AND MOLDED ARTICLE OF POLYLACTIC ACID RESIN EXPANDED BEADS 有权
标题翻译：膨胀的聚乳酸树脂PEARLS膨化聚乳酸树脂珍珠成型
公开(公告)号：EP2657279B1
公开(公告)日：2016-04-20
申请号：EP11851369.6
申请日：2011-10-21
申请人： JSP Corporation
发明人： SHINOHARA Mitsuru , OIKAWA Masaharu
IPC分类号： C08J9/18 , C08L101/16
CPC分类号： C08G63/06 , C08J9/18 , C08J9/232 , C08J2203/04 , C08J2203/06 , C08J2205/04 , C08J2367/04 , Y10T428/2982

7. 发明公开

EP2799473A1 POLYPROPYLENE-BASED RESIN FOAMED PARTICLES, METHOD FOR PRODUCING SAME, AND MOLDED ARTICLE OF POLYPROPYLENE-BASED RESIN FOAMED PARTICLES 有权
标题翻译：发泡粒子聚丙烯树脂，其制造工艺和形状的身体从发泡颗粒聚丙烯树脂
公开(公告)号：EP2799473A1
公开(公告)日：2014-11-05
申请号：EP12861315.5
申请日：2012-12-06
申请人： JSP CORPORATION
发明人： CHIBA Takuya , OIKAWA Masaharu , SHINOHARA Mitsuru
IPC分类号： C08J9/18 , C08K3/04 , C08L23/04 , C08L23/10
CPC分类号： H01B1/24 , B29B7/002 , B29C44/005 , B29K2023/0625 , B29K2023/065 , B29K2023/12 , B29K2105/0002 , B29K2105/0023 , B29K2105/046 , B29K2995/0013 , C08J9/0061 , C08J9/0066 , C08J9/122 , C08J9/16 , C08J9/18 , C08J9/232 , C08J2201/034 , C08J2203/06 , C08J2323/12 , C08J2323/14 , C08J2423/06 , C08J2423/08 , C08K3/04 , C08L23/04 , C08L23/10 , H01R13/6485 , C08L23/06 , C08L23/0807
摘要： An electrostatic dissipative, polypropylene-based resin expanded bead containing electrically conductive carbon black, having an apparent density of 10 to 120 kg/m 3 and formed of a base resin which includes a polypropylene resin forming a continuous phase, and a polyethylene resin forming dispersed phases dispersed in the continuous phase, with the carbon black being unevenly distributed to the dispersed phases side. The polyethylene resin is an ethylene homopolymer or a copolymer of ethylene and C 4 to C 6 α-olefinand a weight ratio of the polypropylene resin to the polyethylene resin is 99.5:0.5 to 65:35. A molded article obtained by in-mold molding of such expanded beads exhibits electrostatic dissipative properties with a surface resistivity in the range of 1×10 5 to 1×10 10 Ω in a stable manner.

8. 发明公开

EP2657279A1 POLYLACTIC ACID RESIN FOAM PARTICLE AND POLYLACTIC ACID RESIN FOAM PARTICLE MOLDING 有权
标题翻译：膨化聚氨酯硬脂酸酯
公开(公告)号：EP2657279A1
公开(公告)日：2013-10-30
申请号：EP11851369.6
申请日：2011-10-21
申请人： JSP Corporation
发明人： SHINOHARA Mitsuru , OIKAWA Masaharu
IPC分类号： C08J9/18 , C08L101/16
CPC分类号： C08G63/06 , C08J9/18 , C08J9/232 , C08J2203/04 , C08J2203/06 , C08J2205/04 , C08J2367/04 , Y10T428/2982
摘要： The present invention has its object provision of polylactic acid resin expanded beads having a controlled crystalline state and exhibiting excellent fusion bonding at the time of in-mold molding. The expanded beads have such a crystal structure that gives a first time DSC curve when heated according to heat flux differential scanning calorimetry referenced in JIS K7122(1987) and a second time DSC curve when thereafter cooled and then again heated, the second time DSC curve having a fusion peak having a reference peak temperature and the first time DSC curve having a fusion peak with a peak temperature that is on a higher temperature side than the reference peak temperature and another fusion peak with a peak temperature that is on a lower temperature side than the reference peak temperature.
摘要翻译：本发明的目的在于提供具有受控结晶状态的聚乳酸树脂发泡珠，并且在模内成型时具有优异的熔融粘合性。发泡珠具有这样的晶体结构，当根据JIS K7122（1987）中引用的热通量差示扫描量热法进行加热时得到第一次DSC曲线，并且随后冷却然后再次加热第二次DSC曲线，第二次DSC曲线具有具有参考峰值温度的熔融峰，并且第一次DSC曲线具有峰值温度在比参考峰值温度高的温度侧的熔融峰，另一个具有在较低温度侧的峰值温度的熔融峰比参考峰值温度高。

9. 发明授权

EP2772509B1 METHOD FOR PRODUCING EXPANDED POLYLACTIC ACID RESIN PARTICLE 有权
公开(公告)号：EP2772509B1
公开(公告)日：2019-01-02
申请号：EP12841440.6
申请日：2012-09-21
申请人： JSP Corporation
发明人： SHINOHARA Mitsuru , OIKAWA Masaharu
IPC分类号： C08J9/18 , C08L101/16

10. 发明授权

EP2799473B1 POLYPROPYLENE-BASED RESIN FOAMED PARTICLES, METHOD FOR PRODUCING SAME, AND MOLDED ARTICLE OF POLYPROPYLENE-BASED RESIN FOAMED PARTICLES 有权
标题翻译：基于聚丙烯的树脂发泡颗粒，其制备方法以及聚丙烯基树脂发泡颗粒的成型制品
公开(公告)号：EP2799473B1
公开(公告)日：2018-03-21
申请号：EP12861315.5
申请日：2012-12-06
申请人： JSP CORPORATION
发明人： CHIBA Takuya , OIKAWA Masaharu , SHINOHARA Mitsuru
IPC分类号： C08J9/16 , H01B1/24 , C08L23/12 , C08L23/06
CPC分类号： H01B1/24 , B29B7/002 , B29C44/005 , B29K2023/0625 , B29K2023/065 , B29K2023/12 , B29K2105/0002 , B29K2105/0023 , B29K2105/046 , B29K2995/0013 , C08J9/0061 , C08J9/0066 , C08J9/122 , C08J9/16 , C08J9/18 , C08J9/232 , C08J2201/034 , C08J2203/06 , C08J2323/12 , C08J2323/14 , C08J2423/06 , C08J2423/08 , C08K3/04 , C08L23/04 , C08L23/10 , H01R13/6485 , C08L23/06 , C08L23/0807
摘要： An electrostatic dissipative, polypropylene-based resin expanded bead containing electrically conductive carbon black, having an apparent density of 10 to 120 kg/m 3 and formed of a base resin which includes a polypropylene resin forming a continuous phase, and a polyethylene resin forming dispersed phases dispersed in the continuous phase, with the carbon black being unevenly distributed to the dispersed phases side. The polyethylene resin is an ethylene homopolymer or a copolymer of ethylene and C 4 to C 6 ±-olefinand a weight ratio of the polypropylene resin to the polyethylene resin is 99.5:0.5 to 65:35. A molded article obtained by in-mold molding of such expanded beads exhibits electrostatic dissipative properties with a surface resistivity in the range of 1×10 5 to 1×10 10 © in a stable manner.

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