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1. 发明公开

EP2669301A1 a-OLEFIN POLYMER AND METHOD FOR PRODUCING SAME 审中-公开
标题翻译：阿尔法 - 奥林匹克 - 低音炮VERFAHREN ZU SEINER HERSTELLUNG
公开(公告)号：EP2669301A1
公开(公告)日：2013-12-04
申请号：EP11842583.4
申请日：2011-11-24
申请人： Idemitsu Kosan Co., Ltd.
发明人： KANAMARU, Masami , FUJIMURA, Takenori , MINAMI, Yutaka
IPC分类号： C08F10/14 , C08F8/04 , C08F8/50 , C09D11/00 , C10M107/02 , C10M143/00 , G03G9/08
CPC分类号： C08F6/04 , C08F4/65908 , C08F8/04 , C08F8/50 , C08F10/14 , C08F2800/10 , C08F2810/10 , C08K5/14 , C09D11/00 , C09D11/108 , C10M107/10 , C10M2205/028 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2230/08 , C10N2260/02 , C10N2270/00 , G03G9/08704 , G03G9/08795 , G03G9/08797 , C08F110/14 , C08F2500/02 , C08F2500/03 , C08F2500/15 , C08F210/14 , C08F210/08 , C08L23/20 , C08L23/24 , C08F8/06 , C08F4/65927 , C08F210/06
摘要： An α-olefin polymer satisfying the following (1) to (4): (1) the average carbon-atom number of α-olefins constituting the polymer is 6.0 or more and 14 or less; (2) the molecular weight distribution (Mw/Mn) ≦2.0; (3) 3000≦weight average molecular weight (Mw)≦600000; and (4) (Log 10 Mp-Log 10 M1)-(Log 10 M2-Log 10 Mp)≧0.2; wherein, in a chart measured by gel permeation chromatography, M1 is the molecular weight at the starting point of the peak, Mp is the molecular weight at the peak top; and M2 is the molecular weight at the end point of the peak.
摘要翻译：满足以下（1）〜（4）的α-烯烃聚合物：（1）构成聚合物的±烯烃的平均碳原子数为6.0以上且14以下; （2）分子量分布（Mw / Mn）‰| 2.0; （3）3000‰|重均分子量（Mw）‰| 600000; 和（4）（Log 10 Mp-Log 10 M1） - （Log 10 M2-Log 10 Mp）‰§0.2; 其中，在通过凝胶渗透色谱法测定的图中，M1是峰起始处的分子量，Mp是峰顶处的分子量; 而M2是峰的终点处的分子量。

2. 发明公开

EP2578607A1 TERMINALLY UNSATURATED POLYOLEFIN, AND MANUFACTURING METHOD THEREOF 无效
标题翻译：终端不粘胶聚乙烯（HERMTELLUNGSVERFAHRENDAFÜR）
公开(公告)号：EP2578607A1
公开(公告)日：2013-04-10
申请号：EP11786290.4
申请日：2011-05-17
申请人： Idemitsu Kosan Co., Ltd.
发明人： MACHIDA, Shuji , TATSUMI, Tomio , FUJIMURA, Takenori
IPC分类号： C08F8/50 , C08F8/42 , C08F10/00 , C08F290/04 , C08L23/00 , C08L55/00 , C08L101/00 , C09D123/00 , C09D155/00 , C09D201/00 , C09J123/00 , C09J155/00 , C09J201/00 , C09K3/12
CPC分类号： C08F10/06 , C08F8/00 , C08F8/50 , C08F110/06 , C08F210/06 , C08F290/042 , C08F2810/40 , C08L23/12 , C08L23/142 , C08L23/22 , C09D155/00 , C09J123/12 , C09J123/142 , C09J123/22 , C09J155/00 , C09K3/10 , C09K2200/0617 , C09K2200/0642 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F210/08 , C08F210/16
摘要： A terminally unsaturated polyolefin satisfying the following (1) to (4):
(1) the mesopentad fraction [mmmm] of propylene chain unit or butene-1 chain unit is 20 to 80 mol%;
(2) the number of terminal vinylidene groups per molecule is 1.3 to 2.5;
(3) the weight-average molecular weight Mw is 500 to 100,000; and
(4) the molecular weight distribution Mw/Mn is 1.1 to 2.6.
摘要翻译：满足以下（1）〜（4）的末端不饱和的聚烯烃：（1）丙烯链单元或丁烯-1链单元的连接成分[mmmm]为20〜80摩尔％（2）每分子末端亚乙烯基的数量为1.3〜2.5; （3）重均分子量Mw为500〜100,000; 和（4）分子量分布Mw / Mn为1.1〜2.6。

3. 发明公开

EP1961776A1 HIGHLY CRYSTALLINE HIGHER -OLEFIN POLYMER AND PROCESS FOR PRODUCTION THEREOF 有权
标题翻译： HOCHKRISTALLINES POLYMER AUF BASIS VONHÖHERENALPHA-OLEFINEN UND HERSTELLUNGSVERFAHRENDAFÜR
公开(公告)号：EP1961776A1
公开(公告)日：2008-08-27
申请号：EP06833593.4
申请日：2006-11-29
申请人： Idemitsu Kosan Co., Ltd.
发明人： FUJIMURA, Takenori , KANAMARU, Masami , OKAMOTO, Takuji , MINAMI, Yutaka
IPC分类号： C08F10/14 , C08F4/6592
CPC分类号： C08F110/14 , C08F2500/01 , C08F2500/20 , C08F2500/03
摘要： A highly crystalline higher α-olefin polymer that is excellent in compatibility with a thermoplastic resin, particularly a polyolefin, compatibility with a lubricant oil, a fuel oil and wax, mixing property with an inorganic filler, and secondary working property, and a process for production thereof are provided. The highly crystalline higher α-olefin polymer is obtained by polymerizing a monomer containing 80% by mol or more of a higher α-olefin having from 22 to 40 carbon atoms, and satisfies the following items (1) and (2). (1) The melting point (Tm), which is observed, by using a differential scanning calorimeter (DSC), from a melting endothermic curve obtained by maintaining a specimen at 190°C for 5 minutes under a nitrogen atmosphere, cooling the specimen to -10°C at a rate of 5°C/min, maintaining at -10°C for 5 minutes, and then elevating a temperature thereof to 190°C at a rate of 10°C/min, is from 55 to 100°C. (2) Standards weight average molecular weight (Mw) measured by a gel permeation chromatography (GPC) based on polystyrene is from 1,000 to 5,000,000, and the molecular weight distribution (Mw/Mn) measured thereby is 5.0 or less.
摘要翻译：与热塑性树脂，特别是聚烯烃，与润滑油，燃料油和蜡的相容性，与无机填料的混合性能和二次加工性能的相容性优异的高度结晶的高级α-烯烃聚合物，以及提供其生产。通过使包含80摩尔％以上的具有22〜40个碳原子的高级α-烯烃的单体聚合得到高结晶性高分子量的α-烯烃聚合物，满足下述（1）和（2）。（1）通过使用差示扫描量热计（DSC）观察到的熔点（Tm），通过在氮气氛下将样品在190℃下保持5分钟而获得的熔融吸热曲线，将样品冷却至 -10℃，以5℃/分钟的速度，在-10℃保持5分钟，然后以10℃/ min的速度升温至190℃，为55〜100℃ C。（2）通过基于聚苯乙烯的凝胶渗透色谱法（GPC）测定的标准重均分子量（Mw）为1,000〜5,000,000，由此测定的分子量分布（Mw / Mn）为5.0以下。

4. 发明授权

EP2452954B1 POLYMERIZATION CATALYSTS AND METHOD FOR PRESERVATION OF SAME 有权
标题翻译：聚合催化剂和保存过程FOR
公开(公告)号：EP2452954B1
公开(公告)日：2015-08-19
申请号：EP10796987.5
申请日：2010-06-10
申请人： Idemitsu Kosan Co., Ltd.
发明人： KANAMARU, Masami , FUJIMURA, Takenori , YABUKAMI, Minoru
IPC分类号： C08F10/00 , C08F110/06 , C08F4/6592 , C08F110/14 , C08F4/649
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/65927 , C08F110/06 , C08F110/14 , Y10S526/943 , C08F2500/17 , C08F4/6492

5. 发明授权

EP1498434B1 PROCESS FOR PRODUCTION OF MODIFIED PROPYLENE POLYMERS AND MODIFIED PROPYLENE POLYMERS PRODUCED BY THE PROCESS 有权
标题翻译：用于生产改性丙烯聚合物并生产改性丙烯聚合物
公开(公告)号：EP1498434B1
公开(公告)日：2013-10-09
申请号：EP03746459.1
申请日：2003-04-11
申请人： IDEMITSU KOSAN CO., LTD.
发明人： KANAMARU, Masami , MINAMI, Yutaka , ABURATANI, Ryo , TATSUMI, Tomio , FUJIMURA, Takenori
IPC分类号： C08F8/46 , C08F255/02 , C09J123/26 , C09J151/06
CPC分类号： C09J123/12 , C08L2023/42 , C08L2666/02 , C09J123/10
摘要： The present invention relates to a method for producing a modified propylene-based polymer containing modifying a propylene-based polymer by a radical initiator and an organic acid, a modified propylene-based polymer obtained by the method, and an adhesive composition containing the modified propylene-based polymer. The propylene-based polymer is a propylene homopolymer satisfying the conditions of (a) mmmm = 20 to 60 mol%, (b) Ärrrr/(1-mmmm)Ü 2.5 mol%, (d) mmxrr/(mr) C-NMR measurement is 55 to 90 mol%. The modified propylene-based polymer of the invention can make a polyolefin, etc. more adhesive, stronger, or flexible, to be useful for a high-adhesive sealant or an polyolefin with increased compatibility to an inorganic filler, etc., particularly as a resin for a hot-melt adhesive.

6. 发明公开

EP2113521A1 -OLEFIN POLYMER AND PROCESS FOR PRODUCTION THEREOF 有权
标题翻译： ALPHA-OLEFINPOLYMER UND HERSTELLUNGSVERFAHRENDAFÜR
公开(公告)号：EP2113521A1
公开(公告)日：2009-11-04
申请号：EP08711486.4
申请日：2008-02-18
申请人： Idemitsu Kosan Co., Ltd.
发明人： FUJIMURA, Takenori , KANAMARU, Masami , MINAMI, Yutaka , OKAMOTO, Takuji
IPC分类号： C08F10/14 , C08F4/6592
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65912 , C08F110/14 , C08F210/14 , Y10S526/904 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/6492 , C08F2500/20 , C08F2500/03 , C08F2500/02 , C08F2500/17
摘要： Provided is an α-olefin polymer having an excellent balance between a molecular weight and a melting point, which is a polymer of one or more kinds of α-olefins having 20 to 40 carbon atoms, and wh ich meets the following requirements (1) to (4): (1) the α-olefin polymer has a molecular weight distribution (Mw/Mn) determined from its weight average molecular weight (Mw) and number average molecular weight (Mn) in terms of polystyrene measured by a GPC method of 2 or less, and has an Mw of 5,000 or less; (2) measurement of a melting point (Tm) of the α-olefin polymer with DSC shows one melting peak, a melting heat absorption (ΔH) calculated from an area of the melting peak is 20 J/g or more, and the melting peak has a half value width of 10°C or less; (3) when the Mw falls within a range of 1,000 to 5,000 and an average number of carbon atoms (Cn) of the α-olefins falls within a range of 20 to 40, the Mw, the Cn, and the Tm measured with the DSC satisfy the relationship, 0.0025×Mw+(Cn×3.3812-29.5)≤Tm≤0.0025≤Mw+((Cn+1)×3.3812-29.5); and (4) a stereoregularity index [M 2 ] derived from a chain of the α-olefins each having 20 to 40 carbon atoms is 20% by mol or more.
摘要翻译：本发明提供一种具有20〜40个碳原子的一种以上的±烯烃的聚合物的分子量和熔点之间的平衡良好的±α-烯烃聚合物，满足以下要求（1）至（4）：（1）所述α-烯烃聚合物的分子量分布（Mw / Mn）由其通过GPC法测定的聚苯乙烯换算的重均分子量（Mw）和数均分子量（Mn）为2以下，Mw为5000以下。（2）用DSC表示的±α-烯烃聚合物的熔点（Tm）测定显示一个熔融峰，由熔融峰面积计算出的熔融热吸收（“H”）为20J / g以上，熔融峰的半值宽度为10℃以下; （3）当Mw落在1,000〜5000的范围内时，± - 烯烃的平均碳原子数（Cn）在20〜40的范围内，Mw，Cn和Tm DSC满足关系，0.0025×Mw +（Cn×3.3812-29.5）‰¤Tm‰¤0.0025‰¤Mw+（（Cn + 1）×3.3812-29.5）; 和（4）衍生自各自具有20〜40个碳原子的±烯烃链的立构规整性指数[M 2]为20摩尔％以上。

7. 发明公开

EP1681333A8 HEAT-STORAGE MATERIAL COMPOSITION 有权
标题翻译：储热材料组合物
公开(公告)号：EP1681333A8
公开(公告)日：2006-10-11
申请号：EP04793035.9
申请日：2004-10-27
申请人： IDEMITSU KOSAN CO., LTD.
发明人： SERA, Masanori , MINAMI, Yutaka , FUJIMURA, Takenori
IPC分类号： C09K5/06
CPC分类号： C09K5/063
摘要： The present invention relates to a heat storage material composition comprising 20 to 100 % by weight of a heat storage material, 80 to 0 % by weight of crystalline polyolefin (B) and 50 to 0 % by weight of an elastomer (C), and the heat storage material described above contains a side chain-crystalline polymer (A), wherein the heat storage material described above comprises preferably a higher α-olefin polymer (a) containing 50 mole % or more of higher α-olefin having 10 or more carbon atoms and a petroleum wax (b) in which a melting point (Tm) is higher by 10°C or more than that of the polymer (a). Provided is a heat storage material composition which has less bleeding and stickiness and is excellent in stability at high temperature and which can meet a change in temperature such as a difference in room temperature when applied to a material for floor heating and can avoid a heating state deviated to high temperature or low temperature.
摘要翻译：本发明涉及一种储热材料组合物，其包含20至100重量％的储热材料，80至0重量％的结晶聚烯烃（B）和50至0重量％的弹性体（C），以及上述蓄热材料含有侧链结晶性聚合物（A），其中上述蓄热材料优选包含含有50摩尔％以上的具有10个以上的高级α-烯烃的高级α-烯烃聚合物（a）碳原子和石油蜡（b），其中熔点（Tm）比聚合物（a）高10℃或更多。本发明提供一种蓄热材料组合物，其具有较少的渗出和发粘性，并且在高温下的稳定性优异，并且能够满足当应用于地板加热用材料时的室温差等温度变化，并且能够避免加热状态偏向高温或低温。

8. 发明公开

EP2578605A1 CATALYST COMPOSITION AND PROCESS FOR PRODUCTION OF OLEFIN POLYMERS USING THE CATALYST COMPOSITION 审中-公开
标题翻译：催化剂组合物及其制备方法催化剂组合物，烯烃HELP
公开(公告)号：EP2578605A1
公开(公告)日：2013-04-10
申请号：EP11786667.3
申请日：2011-05-25
申请人： Idemitsu Kosan Co., Ltd.
发明人： YABUKAMI, Minoru , KANAMARU, Masami , FUJIMURA, Takenori , MINAMI, Yutaka
IPC分类号： C08F4/646 , C08F4/6592
CPC分类号： C08F4/65922 , C08F4/65908 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F110/14 , C08F2410/01 , C08F4/65912 , C08F4/65927 , C08F4/6494 , C08F4/6495
摘要： The present invention provides a catalyst composition and a method for producing an olefin polymer using the catalyst composition. The catalyst composition is prepared by bringing (A) a transition metal compound, (B) a solid boron compound capable of forming an ion pair with the component (A), (C) an organometallic compound and (D) a compound represented by the following general formula (XIV) and/or the following general formula (XV) into contact with each other in a hydrocarbon solvent, and enables a high catalyst concentration.

Z 5 R 14 R 15 (XIV)

Z 6 R 14 R 15 R 16 (XV)

[In the formulae, Z 5 represents an oxygen atom, etc.; Z 6 represents a nitrogen atom, etc.; R 14 to R 16 each independently represent an organic group, and at least one of those organic groups is an organic group having at least 3 carbon atoms, and R 14 to R 16 may bond to each other to form a ring.]
摘要翻译：本发明提供的催化剂组合物以及使用该催化剂组合物在烯烃聚合物生产的方法。所述催化剂组合物是通过使（A）的过渡金属化合物，（B），能够在离子对与组分（A）形成的固体硼化合物，（C）有机金属化合物和（D）由表示的化合物制备下述通式（XIV）和/或下述通式（XV）到在烃溶剂中与海誓山盟接触，并且能够实现高催化剂浓度。 €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒZ5 R 14 R 15€ƒ€ƒ€ƒ€ƒ€ƒ（XIV）€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒZ 6 R 14 R 15 R 16€€ƒƒƒ€€€ƒƒ（XV）[式中，Z 5 darstellt氧原子等; Z 6表示氮原子等; R 14至R 16各自表示unabhängig有机基团，并且至少其中的一个有机基团的是具有至少3个碳原子，和R 14至R 16可以相互键合而形成环的有机基团。]

9. 发明公开

EP2253648A1 POLYOLEFIN GRAFT COPOLYMER AND ADHESIVE COMPOSITION 审中-公开
标题翻译：聚烯烃接枝共聚物和粘合剂组合物
公开(公告)号：EP2253648A1
公开(公告)日：2010-11-24
申请号：EP09719280.1
申请日：2009-03-12
申请人： Idemitsu Kosan Co., Ltd.
发明人： FUJIMURA, Takenori , ABURATANI, Ryo , MACHIDA, Shuji , NAKAMURA, Shinichi
IPC分类号： C08F255/00 , C08F4/6592 , C08L51/06 , C09J151/00
CPC分类号： C08L51/003 , C08F4/65908 , C08F4/65912 , C08F110/06 , C08F255/04 , C08L51/06 , C08L2666/02 , C09J151/003 , C09J151/06 , C08F4/65927 , C08F222/06 , C08F220/18 , C08F230/08 , C08F2500/15 , C08F2500/17 , C08F2500/02
摘要： A graft copolymer is provided that is useful as an adhesive composition that is excellent in adhesion strength between polyolefins and between a polyolefin and another member (for example, a metal, a resin, and an inorganic material, such as glass), is excellent in flowabilityat a low temperature and in melting property in a low temperature range, and is excellent in heat resistance after adhesion, i.e., a graft copolymer satisfying the following items (a) to (e):
the graft copolymer having;
(a) a main chain that is derived from one kind or two or more kinds of monomers selected from (I) acrylic acid and a derivative thereof, (II) methacrylic acid and a derivative thereof, (III) a vinyl ester and a derivative thereof, (IV) styrene and a derivative thereof and (V) a vinyl group-containing silane compound, at least one kind of the a monomer having a crosslinkable functional group,
(b) a side chain that is derived from a reactive polyolefin having a meso pentad fraction (mmmm) of from 30 to 80% by mol and having an end unsaturated group in an amount of from 0.5 to 1.0 group per one molecule, the reactive polyolefin being a homopolymer of one kind of an α-olefin having from 3 to 28 carbon atoms, a copolymer of two or more kinds of α-olefins having from 3 to 28 carbon atoms, or a copolymer of 50% by mass or more of at least one of an α-olefin having from 3 to 28 carbon atoms and 50% by mass or less of ethylene,
(c) a graft ratio of from 1 to 150% by mass,
(d) a weight average molecular weight of from 500 to 400,000 measured by GPC, and
(e) a molecular weight distribution (Mw/Mn) of from 1.5 to 4.
摘要翻译：提供一种接枝共聚物，其用作聚烯烃之间和聚烯烃与其它构件（例如，金属，树脂和无机材料如玻璃）之间的粘合强度优异的粘合剂组合物，（a）〜（e）的接枝共聚物的接枝共聚物，其特征在于，所述接枝共聚物具有在低温下的熔融性和低温下的熔融性，并且粘合后的耐热性优异的接枝共聚物。（a）衍生自选自（I）丙烯酸及其衍生物，（II）甲基丙烯酸及其衍生物，（III）乙烯基酯和衍生物的单体或两种以上单体的主链（IV）苯乙烯及其衍生物和（V）含乙烯基的硅烷化合物，至少一种具有可交联官能团的单体，（b）衍生自反应性聚烯烃的侧链，所述反应性聚烯烃具有其中每一分子具有30至80摩尔％的内消旋五单元组分数（mmmm）并具有0.5至1.0个基团的末端不饱和基团，所述反应性聚烯烃为一种α-烯烃的均聚物， 3至28个碳原子的α-烯烃，2种或更多种具有3至28个碳原子的α-烯烃的共聚物或50质量％或更多的至少一种具有3至28个碳原子的α-烯烃（c）接枝率为1质量％以上且150质量％以下，（d）重量平均为50质量％以下，通过GPC测得的分子量为500-400,000，和（e）分子量分布（Mw / Mn）为1.5-4。

10. 发明授权

EP1681333B1 HEAT-STORAGE MATERIAL COMPOSITION 有权
标题翻译：储热介质
公开(公告)号：EP1681333B1
公开(公告)日：2010-04-21
申请号：EP04793035.9
申请日：2004-10-27
申请人： IDEMITSU KOSAN CO., LTD.
发明人： SERA, Masanori , MINAMI, Yutaka , FUJIMURA, Takenori
IPC分类号： C09K5/06
CPC分类号： C09K5/063

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