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    • 2. 发明公开
    • Sheet type ion measurement electrode
    • Plattenförmige,ionenempfindliche Elektrode。
    • EP0282651A2
    • 1988-09-21
    • EP87119278.7
    • 1987-12-28
    • HORIBA, LTD.
    • Tomita, Katsuhiko
    • G01N27/30
    • G01N27/333
    • Described is a sheet type electrode for the measurement of ions in which an ion-­selective response membrane is formed on the upper surface side of a support layer which is characterized in that said support layer (10) is formed of two piled up sheet materials (11, 12) having a sufficiently high electrical insulating property and said thin film -like ion-selective response membrane (22) is for­med by dropping an ion-selective response membrane paste (20) containing a solvent compatible with said support layer on said support layer.
    • 描述了用于测量在支撑层的上表面侧上形成离子选择性响应膜的离子的片状电极,其特征在于,所述支撑层(10)由两个堆积的片材( 11,12),并且所述薄膜状离子选择响应膜(22)通过将含有与所述支持层相容的溶剂的离子选择性响应膜浆料(20)滴加到所述载体上而形成 层。
    • 6. 发明公开
    • Method of producing pH-responsive membrane
    • Verfahren zum Herstellen einer pH-empfindlichen Membran。
    • EP0493684A1
    • 1992-07-08
    • EP91120517.7
    • 1991-11-29
    • HORIBA, LTD.
    • Tomita, Katsuhiko
    • G01N27/333
    • G01N27/3335
    • A method for producing a pH-responsive membrane consists of pouring a coating solution (3) mainly comprising tantalum alkoxide drop by drop onto a surface of an electrode substrate (1) rotating at an appointed speed to form a thin film (4) of said coating solution on said substrate by this spin coating method, followed by drying and baking to form a pH-responsive membrane formed of a thin film made of tantalum pentaoxide having an appointed film-thickness on said electrode substrate. A second method consists of immersing an electrode substrate (1) in a coating solution (3) mainly comprising tantalum alkoxide, followed by pulling up said electrode substrate at an appointed speed to form a thin film (4) of said coating solution on said substrate, then drying and baking to form a pH-responsive membrane formed of a thin film made of tantalum pentaoxide having an appointed film-thickness on said electrode substrate.
    • 用于制备pH响应膜的方法包括将主要包含钽醇盐的涂料溶液(3)逐滴地倾倒在以规定速度旋转的电极基材(1)的表面上,形成所述 通过该旋涂法在所述基板上涂布溶液,然后进行干燥和烘烤,以形成由在所述电极基板上具有指定膜厚度的由五氧化钽制成的薄膜形成的pH响应膜。 第二种方法包括将电极基体(1)浸入主要包含钽醇盐的涂层溶液(3)中,然后以指定速度拉动所述电极基底,以在所述基底上形成所述涂布溶液的薄膜(4) 然后干燥和烘烤以形成由在所述电极基底上具有指定膜厚度的由五氧化钽制成的薄膜形成的pH响应膜。
    • 9. 发明公开
    • Sheet type glass electrode
    • PlattenförmigeGlaselektrode。
    • EP0269031A2
    • 1988-06-01
    • EP87117176.5
    • 1987-11-20
    • HORIBA, LTD.
    • Kotani, HaruoTomita, KatsuhikoYada, TakaakiNakanishi, Tsuyoshi
    • G01N27/36
    • G01N27/36
    • A glass electrode having a sheet type shape and being open toward an upper sur­face side is described. This sheet type glass electrode provides together with a sheet type reference electrode a sheet type composite electrode wherein the glass electrode and the reference electrode are placed side by side under the condition that they are open toward an upper surface side. This sheet type glass electrode comprises a substrate (10) formed of a material having a sufficiently high electrical insulating property, an electrode (D) comprising an internal electrode portion (B) and a lead portion (C) stuck to an upper surface thereof, a support layer (F) formed of a material having a sufficiently high electrical insulating property which is provided with a hole (E) at a place corresponding to said internal electrode portion (B) being formed on the upper surface of said substrate (A) under the condition that said lead portion (C) and its circum­ference are exposed, said hole (E) in the support layer (F) being tightly filled with a gelatinized internal solution (G) and a flat plate-like ion-response glass membrane (H) which is fixedly mounted on the upper surface of said support layer (F) along a circumference thereof by the use of adhesives (I) having a suffi­ciently high electrical insulating property so that a lower surface therof may be closely stuck to an upper surface of said gelatinized internal solution (G).
    • 描述具有片状形状并朝向上表面侧开口的玻璃电极。 该片状玻璃电极与片状参考电极一起提供片状复合电极,其中玻璃电极和参考电极在朝向上表面侧开口的条件下并排放置。 该片状玻璃电极包括由具有足够高的电绝缘性的材料形成的基板(10),包括粘附到其上表面的内部电极部分(B)和引线部分(C)的电极(D) 由具有足够高电绝缘性的材料形成的支撑层(F)在与所述内部电极部分(B)相对应的位置处设置有在所述基板(A)的上表面上的孔(E) 在所述引线部分(C)及其周边露出的状态下,所述支撑层(F)中的所述孔(E)用凝胶化的内部溶液(G)和平板状离子响应玻璃膜 (H),其通过使用具有足够高的电绝缘性能的粘合剂(I)沿其圆周固定地安装在所述支撑层(F)的上表面上,使得下表面框架可以紧密地粘附到上部 所述凝胶化内部溶液(G)的表面。