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1. 发明公开

EP0254402A1 Improved gas/solid contact method for removing sulfur oxides from gases 失效
标题翻译： Gas-Feststoff-Berührungsverfahrenzur Entfernung von Schwefeloxiden aus Gasen。
公开(公告)号：EP0254402A1
公开(公告)日：1988-01-27
申请号：EP87304661.9
申请日：1987-05-27
申请人： ENGELHARD CORPORATION
发明人： Moore, Andrew S. , Bartholic, David B. , Barger, Dwight F. , Reagan, William J.
IPC分类号： B01D53/34 , B01D53/06
CPC分类号： B01D53/508 , B01D53/12 , B01D2251/402 , B01D2251/602 , B01D2253/104 , B01D2253/1124 , B01D2253/25 , B01D2253/304 , B01D2253/306 , B01D2256/22 , B01D2257/302 , B01D2257/404 , B01D2258/0283 , B01D2259/40009 , B01D2259/40086 , Y02A50/2348
摘要： An improved continuous cyclic process for removing oxides of sulfur from a waste gas (A) with a regenerable particulate adsorbent in which hot absorbent particles pick up SOx in a fast fluid transport riser (B), followed by separation of clean gas (D) from sulfur-containing particles which are then recycled to a desorber (G) in which they are contacted at elevated temperature with a mixture of reducing gas (H) and water vapor (I) for release of sulfur as hydrogen sulfide. The adsorbent particles are then recycled in the process. Means are provided for removing particulates in the waste gas.
摘要翻译：一种用可再生颗粒吸附剂从废气（A）中除去硫的氧化物的改进的连续循环方法，其中热吸收性颗粒在快速流体输送提升管（B）中吸收SO x，然后将清洁气体（D）从然后将其再循环到解吸器（G）中，其中它们在升高的温度下与还原气体（H）和水蒸气（I）的混合物接触以释放硫作为硫化氢。然后在该过程中再循环吸附剂颗粒。提供了用于去除废气中的微粒的装置。

2. 发明公开

EP0247836A1 Removing sulfur oxides from flue gases of FCC units 失效
标题翻译： Entfernung von Schwefeloxiden aus Abgasen von FCC-Anlagen。
公开(公告)号：EP0247836A1
公开(公告)日：1987-12-02
申请号：EP87304662.7
申请日：1987-05-27
申请人： ENGELHARD CORPORATION
发明人： Moore, Andrew S. , Bartholic, David B. , Barger, Dwight F. , Reagan, William J.
IPC分类号： C10G55/06 , C10G25/00
CPC分类号： C10G11/18
摘要： An improved process for reducing SOx in the flue gas from FCC regenerators operated in complete combustion mode is disclosed. The FCC riser is modified to include an SOx desorption zone (D) upstream from the zone in the riser in which regenerated cracking catalyst (A) contacts hydrocarbon feedstock (E). The circulating catalyst inventory (A) includes a regenerable SOx adsorbent. In the SOx desorption zone (D), the hot circulating catalyst inventory (A) is mixed with a reducing gas (B) and water vapor (C) and the gas/solid mixture is maintained in that zone for sufficient time to desorb.
摘要翻译：公开了一种用于减少在完全燃烧模式下操作的FCC再生器的烟道气中的SO x的改进方法。 FCC提升管被修改为包括在再生裂化催化剂（A）接触烃原料（E）的提升管中的区域上游的SOx解吸区（D）。循环催化剂库存（A）包括可再生SOx吸附剂。在SOx解吸区（D）中，将热循环催化剂库存（A）与还原气体（B）和水蒸汽（C）混合，气/固混合物保持在该区域足够的时间解吸。

3. 发明公开

EP0236055A3 Hydrocarbon treatment process 失效
标题翻译：油气处理工艺
公开(公告)号：EP0236055A3
公开(公告)日：1987-10-07
申请号：EP87301612
申请日：1987-02-24
申请人： ENGELHARD CORPORATION
发明人： Bartholic, David B. , Barger, Dwight F.
IPC分类号： C10G11/18
CPC分类号： C10G11/18

4. 发明公开

EP0226421A3 Hydrocarbon conversion process and apparatus 失效
标题翻译：石油转化过程和装置
公开(公告)号：EP0226421A3
公开(公告)日：1987-10-07
申请号：EP86309518
申请日：1986-12-05
申请人： ENGELHARD CORPORATION
发明人： Bartholic, David B. , Barger, Dwight F.
IPC分类号： C10G11/18 , B01J08/18
CPC分类号： B01J8/18 , C10G11/18
摘要： A hydrocarbon conversion system wherein a hydrocarbon feed is converted to lower boiling products in a reactor (K) by contact at elevated temperature with fluidized solid material, spent material containing coke from said reactor is separated from reaction products and stripped of volatile hydrocarbons in a stripping zone (D), stripped solid material is regenerated with oxygen-containing gas in a regeneration zone (B), and hot freshly regenerated fluidized material is returned to the reactor (K), characterised by carrying out both the conversion and the regeneration in a dilute phase and passing all of the solid material from the reactor (K) and the regeneration zone (B) through respective preseparators (E) wherein rapid disengagement of solids and gases occur and from which the solid material is returned to respective beds in respective vessels (C,D) other than said reactor (K) and regenerator (B).
摘要翻译：一种烃转化系统，其中通过在高温下与流化固体材料接触将烃进料在反应器（K）中转化为低沸点产物，将来自所述反应器的含有焦炭的废料与反应产物分离并汽提汽提中的挥发性烃区域（D）中，汽提固体物质在再生区（B）中用含氧气体再生，热新鲜再生的流化物质返回到反应器（K），其特征在于，在稀释相，并使来自反应器（K）和再生区（B）的所有固体物质通过各自的预分离器（E）通过，其中固体和气体迅速脱离，固体材料从该分离器（E）返回到相应容器中的相应床（C，D）除了所述反应器（K）和再生器（B）之外。

5. 发明公开

EP0236055A2 Hydrocarbon treatment process 失效
标题翻译： Verfahren zur Behandlung von Kohlenwasserstoffen。
公开(公告)号：EP0236055A2
公开(公告)日：1987-09-09
申请号：EP87301612.5
申请日：1987-02-24
申请人： ENGELHARD CORPORATION
发明人： Bartholic, David B. , Barger, Dwight F.
IPC分类号： C10G11/18
CPC分类号： C10G11/18
摘要： A process wherein lower boiling products (H) are obtained from a hydrocarbon feed (J and/or HH) by contacting the feed with fluidized solid contact material at elevated temperature in a riser (K), spent contact material is separated and stripped of volatile hydrocarbons in a stripping zone (D), stripped contact material is regenerated with oxygen-containing gas (A) in a regeneration zone (B), and hot freshly regenerated fluidized solid contact material is returned to the riser (K), the process further including two or more of the following:

(i) suspending hot regenerated contact material in a carbonizable lift gas at the lower portion of the riser and injecting hydrocarbon feed higher in the riser;
(ii) charging hydrocarbon feed into the base of the riser, steam cooling a portion of the hot freshly regenerated contact material, and contacting the hydrocarbon feed with hot regenerated contact material upstream of where said hydrocarbon feed is contacted with the steam cooled contact material;
(iii) cooling a portion of hot freshly regenerated contact material before returning it to the riser; and
(iv) adding a portion of freshly heated regenerated contact material to said stripping zone.
摘要翻译：低沸点产物的过程是obtd。通过（a）在高温下将其与流化的固体接触材料接触从烃进料中。在一个冒口，（b）sepg。废弃的接触材料并在汽提区中汽提挥发性烃，（c）通过与O2-contg接触再生剥离的接触材料。在再生区中的气体，以及（d）将热的新鲜再生的接触材料返回到提升管中还包括以下2个或更多个：（i）将热再生接触材料悬浮在提升管的下部的可燃提升气体中并注射碳氢化合物进料在提升管中较高; （ii）将烃进料加入到提升管的底部中，蒸汽冷却一部分热的新鲜再生的接触材料，并使烃进料与热再生接触材料接触，该进料与蒸汽冷却的接触材料接触的点 ; （ii）在将热的新鲜再生接触材料的一部分返回到提升管之前冷却; 和（iv）将一部分新鲜再生的接触材料添加到汽提区。触点材料首选包括具有酸性位点的沸石催化剂。

6. 发明公开

EP0234924A2 Hydrocarbon treatment process 失效
公开(公告)号：EP0234924A2
公开(公告)日：1987-09-02
申请号：EP87301613.3
申请日：1987-02-24
申请人： ENGELHARD CORPORATION
发明人： Bartholic, David B. , Barger, Dwight F.
IPC分类号： C10G11/18
CPC分类号： C10G11/18
摘要： A process wherein lower boiling products (H) are obtained from a hydrocarbon feed (J and/or HH) by contacting the feed with fluidized solid contact material at elevated temperature in a riser (K), spent contact material is separated and stripped of volatile hydrocarbons in a stripping zone (D), stripped contact material is regenerated with oxygen-containing gas (A) in a regeneration zone (B), and hot freshly regenerated fluidized solid contact material is returned to the riser (K), the process further including two or more of the following:

(i) suspending hot regenerated contact material in a carbonizable lift gas at the lower portion of the riser and injecting hydrocarbon feed higher in the riser;
(ii) charging hydrocarbon feed into the base of the riser, steam cooling a portion of the hot freshly regenerated contact material, and contacting the hydrocarbon feed with hot regenerated contact material upstream of where said hydrocarbon feed is contacted with the steam cooled contact material;
(iii) cooling a portion of hot freshly regenerated contact material before returning it to the riser; and
(iv) adding a portion of freshly heated regenerated contact material to said stripping zone.

7. 发明授权

EP0254402B1 Improved gas/solid contact method for removing sulfur oxides from gases 失效
标题翻译：改进的气体/固体接触方法，用于从气体中除去硫氧化物
公开(公告)号：EP0254402B1
公开(公告)日：1992-01-29
申请号：EP87304661.9
申请日：1987-05-27
申请人： ENGELHARD CORPORATION
发明人： Moore, Andrew S. , Bartholic, David B. , Barger, Dwight F. , Reagan, William J.
IPC分类号： B01D53/34 , B01D53/06
CPC分类号： B01D53/508 , B01D53/12 , B01D2251/402 , B01D2251/602 , B01D2253/104 , B01D2253/1124 , B01D2253/25 , B01D2253/304 , B01D2253/306 , B01D2256/22 , B01D2257/302 , B01D2257/404 , B01D2258/0283 , B01D2259/40009 , B01D2259/40086 , Y02A50/2348
摘要： An improved continuous cyclic process for removing oxides of sulfur from a waste gas (A) with a regenerable particulate adsorbent in which hot absorbent particles pick up SOx in a fast fluid transport riser (B), followed by separation of clean gas (D) from sulfur-containing particles which are then recycled to a desorber (G) in which they are contacted at elevated temperature with a mixture of reducing gas (H) and water vapor (I) for release of sulfur as hydrogen sulfide. The adsorbent particles are then recycled in the process. Means are provided for removing particulates in the waste gas.

8. 发明公开

EP0236054A3 Hydrocarbon treatment process 失效
标题翻译：油气处理工艺
公开(公告)号：EP0236054A3
公开(公告)日：1987-10-07
申请号：EP87301611
申请日：1987-02-24
申请人： ENGELHARD CORPORATION
发明人： Bartholic, David B. , Barger, Dwight F.
IPC分类号： C10G11/18
CPC分类号： B01J8/18 , C10G11/18
摘要： A process wherein lower boiling products (H) are obtained from a hydrocarbon feed (J and/or HH) by contacting the feed with fluidized solid contact material at elevated temperature in a riser (K), spent contact material is separated and stripped of volatile hydrocarbons in a stripping zone (D), stripped contact material is regenerated with oxygen-containing gas (A) in a regeneration zone (B), and hot freshly regenerated fluidized solid contact material is returned to the riser (K), the process further including two or more of the following:
(i) suspending hot regenerated contact material in a carbonizable lift gas at the lower portion of the riser and injecting hydrocarbon feed higher in the riser; (ii) charging hydrocarbon feed into the base of the riser, steam cooling a portion of the hot freshly regenerated contact material, and contacting the hydrocarbon feed with hot regenerated contact material upstream of where said hydrocarbon feed is contacted with the steam cooled contact material; (iii) cooling a portion of hot freshly regenerated contact material before returning it to the riser; and (iv) adding a portion of freshly heated regenerated contact material to said stripping zone.
摘要翻译：通过在提升管（K）中将进料与流化固体接触材料在升高的温度下接触，从烃进料（J和/或HH）获得低沸点产物（H）的方法，分离废弃的接触材料并除去挥发性在汽提区（D）中的烃，剥离的接触材料在再生区（B）中用含氧气体（A）再生，热新鲜再生的流化固体接触材料返回到提升管（K），该方法进一步包括以下两个或更多个：（i）将热再生接触材料悬浮在提升管下部的可碳化提升气体中并在提升管中注入烃进料; （ii）将烃进料加入到提升管的底部中，蒸汽冷却热新鲜再生接触材料的一部分，以及使烃进料与热再生接触材料接触，在所述烃再生接触材料的上游，所述烃进料与蒸汽冷却的接触材料接触; （iii）在将一部分热的新鲜再生的接触材料返回到提升管之前冷却; 和（iv）将一部分新鲜再生的接触材料添加到所述汽提区。

9. 发明公开

EP0234924A3 Hydrocarbon treatment process 失效
标题翻译：碳氢化合物处理过程
公开(公告)号：EP0234924A3
公开(公告)日：1987-10-07
申请号：EP87301613
申请日：1987-02-24
申请人： ENGELHARD CORPORATION
发明人： Bartholic, David B. , Barger, Dwight F.
IPC分类号： C10G11/18
CPC分类号： C10G11/18
摘要： A process wherein lower boiling products (H) are obtained from a hydrocarbon feed (J and/or HH) by contacting the feed with fluidized solid contact material at elevated temperature in a riser (K), spent contact material is separated and stripped of volatile hydrocarbons in a stripping zone (D), stripped contact material is regenerated with oxygen-containing gas (A) in a regeneration zone (B), and hot freshly regenerated fluidized solid contact material is returned to the riser (K), the process further including two or more of the following:
(i) suspending hot regenerated contact material in a carbonizable lift gas at the lower portion of the riser and injecting hydrocarbon feed higher in the riser; (ii) charging hydrocarbon feed into the base of the riser, steam cooling a portion of the hot freshly regenerated contact material, and contacting the hydrocarbon feed with hot regenerated contact material upstream of where said hydrocarbon feed is contacted with the steam cooled contact material; (iii) cooling a portion of hot freshly regenerated contact material before returning it to the riser; and (iv) adding a portion of freshly heated regenerated contact material to said stripping zone.
摘要翻译：通过在提升管（K）中在升高的温度下使进料与流化固体接触材料接触，从烃进料（J和/或HH）获得较低沸点产物（H），将失活的接触物质分离并除去挥发物在汽提区（D）中的烃，在再生区（B）中用含氧气体（A）再生剥离的接触材料，并且热的新鲜再生的流态化固体接触材料返回到提升管（K），该工艺进一步包括以下两种或更多种：（i）将热再生接触材料悬浮在提升管下部的可碳化提升气体中，并在提升管中注入更高的烃进料; （ii）将烃进料装入提升管底部，蒸汽冷却一部分热的新鲜再生的接触材料，并使烃进料与热再生接触材料接触，在所述烃进料与蒸汽冷却的接触材料接触的位置上游; （iii）在将其一部分热的新鲜再生的接触材料返回到立管之前冷却; 和（iv）将一部分新鲜加热的再生接触材料加入到所述汽提区中。

10. 发明公开

EP0236054A2 Hydrocarbon treatment process 失效
标题翻译： Verfahren zur Behandlung von Kohlenwasserstoffen。
公开(公告)号：EP0236054A2
公开(公告)日：1987-09-09
申请号：EP87301611.7
申请日：1987-02-24
申请人： ENGELHARD CORPORATION
发明人： Bartholic, David B. , Barger, Dwight F.
IPC分类号： C10G11/18
CPC分类号： B01J8/18 , C10G11/18
摘要： A process wherein lower boiling products (H) are obtained from a hydrocarbon feed (J and/or HH) by contacting the feed with fluidized solid contact material at elevated temperature in a riser (K), spent contact material is separated and stripped of volatile hydrocarbons in a stripping zone (D), stripped contact material is regenerated with oxygen-containing gas (A) in a regeneration zone (B), and hot freshly regenerated fluidized solid contact material is returned to the riser (K), the process further including two or more of the following:

(i) suspending hot regenerated contact material in a carbonizable lift gas at the lower portion of the riser and injecting hydrocarbon feed higher in the riser;
(ii) charging hydrocarbon feed into the base of the riser, steam cooling a portion of the hot freshly regenerated contact material, and contacting the hydrocarbon feed with hot regenerated contact material upstream of where said hydrocarbon feed is contacted with the steam cooled contact material;
(iii) cooling a portion of hot freshly regenerated contact material before returning it to the riser; and
(iv) adding a portion of freshly heated regenerated contact material to said stripping zone.
摘要翻译：通过在提升管（K）中将进料与流化固体接触材料在升高的温度下接触，从烃进料（J和/或HH）获得低沸点产物（H）的方法，分离废弃的接触材料并除去挥发性在汽提区（D）中的烃，剥离的接触材料在再生区（B）中用含氧气体（A）再生，并且热新鲜再生的流化固体接触材料返回到提升管（K），该方法进一步包括以下两个或更多个：（i）将热再生接触材料悬浮在提升管下部的可碳化提升气体中并在提升管中注入烃进料; （ii）将烃进料加入到提升管的底部中，蒸汽冷却热新鲜再生接触材料的一部分，以及使烃进料与热再生接触材料接触，在所述烃再生接触材料的上游，所述烃进料与蒸汽冷却的接触材料接触; （iii）在将一部分热的新鲜再生的接触材料返回到提升管之前冷却; 和（iv）将一部分新鲜再生的接触材料添加到所述汽提区。

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