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    • 8. 发明公开
    • Green sensitized tabular grain photographic emulsions
    • Photographische Emulsionen mit imGrünsensibilisiertetafelförmigeKörner。
    • EP0608955A1
    • 1994-08-03
    • EP94200185.0
    • 1994-01-27
    • EASTMAN KODAK COMPANY
    • Adin, Anthony, c/o Eastman Kodak CompanyDerks, Frederick Charles, c/o Eastman Kodak Comp.Kestner, Melvin Michael, c/o Eastman Kodak CompanyLink, Steven George, c/o Eastman Kodak Company
    • G03C1/29
    • G03C1/29
    • A silver halide photographic element, and a method of making such an element, comprising a tabular grain silver halide emulsion containing at least one green spectral sensitizing dye of formula I, and at least one green spectral sensitizing dye of formula II:

         wherein R1 and R2 may be the same or different and are selected from substituted or unsubstituted C1 or C2 alkyl, substituted or unsubstituted C1 or C2 alkoxy, halogen, substituted or unsubstituted amido, or carbamoyl or substituted or unsubstituted aryl, provided that R1 and R2 are not both aryl, and the benzo back rings may optionally be further substituted;
         X3 is a substituted or unsubstituted C1 to C3 alkyl or alkenyl;
         X1 and X2 are acid or acid salt substituted C1 to C6 alkyl or alkenyl which may be further substituted or unsubstituted;
         M+ is a positive ion as required to balance a charge;

         where R3 and R4 may be the same or different and represent substituted or unsubstituted alkyl or alkenyl of 1 to 4 carbon atoms;
         R5 and R6 may be the same or different and both represent strong electron withdrawing groups;
         R8 and R9 are independently hydrogen, halogen, or a substituted or unsubstituted methyl or ethyl, or a strong electron withdrawing group;
         X4 and X5 are substituted or unsubstituted C1 to C6
      alkyl or alkenyl at least one of which has an acid or acid salt substituent;
         N+ is a positive ion as needed to balance a charge.
    • 卤化银照相元件和制备这种元素的方法,包括含有至少一种式I的绿色光谱增感染料的片状粒状卤化银乳剂和至少一种式II的绿色光谱增感染料:,其中 R 1和R 2可以相同或不同,并且选自取代或未取代的C 1或C 2烷基,取代或未取代的C 1或C 2烷氧基,卤素,取代或未取代的酰氨基或氨基甲酰基或取代或未取代的芳基,条件是R 1和R 2为 不是芳基,苯并环基环可以任选被进一步取代; X3是取代或未取代的C1至C3烷基或链烯基; X1和X2是酸或酸盐取代的C1至C6烷基或烯基,其可以进一步被取代或未取代; M +是平衡电荷所需的正离子; 其中R 3和R 4可以相同或不同,表示取代或未取代的具有1至4个碳原子的烷基或链烯基; R5和R6可以相同或不同,均表示强吸电子基团; R8和R9独立地是氢,卤素或取代或未取代的甲基或乙基或强吸电子基团; X4和X5是取代或未取代的C1至C6烷基或烯基,其中至少一个具有酸或酸盐取代基; N +是平衡电荷所需的正离子。 WH