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1. 发明授权

EP0853634B1 CONTROL OF MOLECULAR WEIGHT AND END-GROUP FUNCTIONALITY IN POLYMERS 失效
标题翻译：控制分子量和聚合物的终止
公开(公告)号：EP0853634B1
公开(公告)日：2001-12-12
申请号：EP96931683.5
申请日：1996-10-04
申请人： COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION , E.I. DU PONT DE NEMOURS AND COMPANY
发明人： RIZZARDO, Enzio , THANG, San, Hoa , MOAD, Graeme , CHONG, Yen, Kwong
IPC分类号： C08F2/38 , C08F2/42
CPC分类号： C08F290/04 , C08F2/38 , C08F14/06
摘要： This invention relates to a process for the production of lower molecular weight polymers by free radical-initiated polymerization of unsaturated species characterised by the use of an unsaturated compound of Formula (I) as a chain transfer agent wherein R?1 and R2¿ are the same or different and are selected from the group consisting of hydrogen, optionally substituted alkyl, optionally substituted saturated or aromatic carbocyclic or heterocyclic ring, and halogen; X is selected from the group consisting of chlorine, bromine, optionally substituted alkylsulfonyl, and optionally substituted arylsulfonyl; Y is selected from the group consisting of halogen, a polymer chain, and CR3R4Z, wherein R?3 and R4¿ are the same or different and are selected from the group consisting of hydrogen, optionally substituted alkyl, optionally substituted saturated, unsaturated or aromatic carbocyclic or heterocyclic ring, and halogen; and Z is selected from the group consisting of chlorine, bromine, optionally substituted alkylsulfonyl and optionally substituted arylsulfonyl; provided that when X is optionally substituted alkylsulfonyl or optionally substituted arylsulfonyl, Y is not halogen. The invention also relates to various polymers produced by this process and products comprising these polymers. The process of the invention may also be used in the preparation of A-B type block copolymers.

2. 发明公开

EP1123332A1 MICROGELS AND PROCESS FOR THEIR PREPARATION 有权
标题翻译：微凝胶和方法及其
公开(公告)号：EP1123332A1
公开(公告)日：2001-08-16
申请号：EP99932369.4
申请日：1999-07-09
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
发明人： BERGE, Charles, T. , FRYD, Michael , JOHNSON, Jeffery, W. , MOAD, Graeme , RIZZARDO, Ezio , SCOPAZZI, Christopher , THANG, San, Hoa
IPC分类号： C08F293/00 , C08F290/04
CPC分类号： C08F265/04 , C08F290/04 , C08F290/061 , C08F293/00 , C08F293/005 , Y10S514/944
摘要： A process for preparing microgel(s) that uses a wide range of activatable prepolymers; in the process, a polymer composition of crosslinked component A and soluble components B and C is formed from mono-olefinic and multi-olefinic monomers in the presence of catalyst and initiator; the process comprises: I) introducing mono-olefinic monomer, catalyst, and initiator into a reactor in the absence of multi-olefinic monomer and producing an activatable prepolymer, component B; II) contacting the product of I) with multi-olefinic monomer to produce components A and C, optionally in the presence of additional initiator; also optionally in the presence of additional mono-olefinic monomer and initiator; the ratio of components A/(B+C) can be controlled by varying the mole ratio of Component B/ multi-olefinic monomer from 0.05/1 up to 5/1, by decreasing the mole ratio to increase the ratio of A/(B+C), and increasing the mole ratio to decrease the ratio of A/(B+C).

3. 发明授权

EP0791017B1 POLYMERIZATION IN AQUEOUS MEDIA 失效
标题翻译：聚合在水介质中
公开(公告)号：EP0791017B1
公开(公告)日：2000-06-21
申请号：EP95939795.1
申请日：1995-11-08
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
发明人： MOAD, Graeme , MOAD, Catherine, Louise , KRSTINA, Julia , RIZZARDO, Ezio , THANG, San, Hoa , FRYD, Michael
IPC分类号： C08F2/38 , C08F2/22
CPC分类号： C08F2/38 , C08F293/005
摘要： A method for the solution or emulsion polymerization of ethylenically unsaturated monomers, styrene, and other free radical polymerizable monomers in aqueous media in which a cobalt chain transfer agent is used which has both hydrolytic stability and solubility in water and in the organic phase with preferential solubility in the organic phase.

4. 发明授权

EP0910587B1 POLYMERIZATION WITH LIVING CHARACTERISTICS 失效
标题翻译：与“活”板聚合
公开(公告)号：EP0910587B1
公开(公告)日：2001-12-12
申请号：EP97932627.9
申请日：1997-07-03
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
发明人： LE, Tam, Phuong , MOAD, Graeme , RIZZARDO, Ezio , THANG, San, Hoa
IPC分类号： C08F2/38 , C07C327/36
CPC分类号： C08K5/38 , C07C327/36 , C07C329/00 , C07F9/4065 , C08F2/38 , C08F12/08 , C08F293/00 , C08F293/005 , C08L25/06

5. 发明公开

EP0910587A1 POLYMERIZATION WITH LIVING CHARACTERISTICS 失效
标题翻译：与“活”板聚合
公开(公告)号：EP0910587A1
公开(公告)日：1999-04-28
申请号：EP97932627.0
申请日：1997-07-03
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
发明人： LE, Tam, Phuong , MOAD, Graeme , RIZZARDO, Ezio , THANG, San, Hoa
IPC分类号： C07C327 , C07C329 , C07F9 , C08F2
CPC分类号： C08K5/38 , C07C327/36 , C07C329/00 , C07F9/4065 , C08F2/38 , C08F12/08 , C08F293/00 , C08F293/005 , C08L25/06
摘要： This invention concerns a free radical polymerization process, selected chain transfer agents employed in the process and polymers made thereby, in which the process comprises preparing polymer of general Formula (A) and Formula (B) comprising contacting: (i) a monomer selected from the group consisting of vinyl monomers (of structure CH2 = CUV), maleic anhydride, N-alkylmaleimide, N-arylmaleimide, dialkyl fumarate and cyclopolymerizable monomers; (ii) a thiocarbonylthio compound selected from Formula (C) and Formula (D) having a chain transfer constant greater than about 0.1; and (iii) free radicals produced from a free radical source; the polymer of Formula (A) being made by contacting (i), (ii) C and (iii) and that of Formula (B) by contacting (i), (ii) D, and (iii); and (iv) controlling the polydispersity of the polymer being formed by varying the ratio of the number of molecules of (ii) to the number of molecules of (iii); wherein Q, R, U, V, Z, Z', m, p and q are as defined in the text.

6. 发明公开

EP0853634A1 CONTROL OF MOLECULAR WEIGHT AND END-GROUP FUNCTIONALITY IN POLYMERS 失效
标题翻译：聚合物中分子量和端基功能的控制
公开(公告)号：EP0853634A1
公开(公告)日：1998-07-22
申请号：EP96931683.0
申请日：1996-10-04
申请人： COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION , E.I. DU PONT DE NEMOURS AND COMPANY
发明人： RIZZARDO, Enzio , THANG, San, Hoa , MOAD, Graeme , CHONG, Yen, Kwong
IPC分类号： C08L101 , C08F2 , C08F14 , C08F214 , C08F290 , C08F293 , C09D201 , C09J201
CPC分类号： C08F290/04 , C08F2/38 , C08F14/06
摘要： This invention relates to a process for the production of lower molecular weight polymers by free radical-initiated polymerization of unsaturated species characterised by the use of an unsaturated compound of Formula (I) as a chain transfer agent wherein R?1 and R2¿ are the same or different and are selected from the group consisting of hydrogen, optionally substituted alkyl, optionally substituted saturated or aromatic carbocyclic or heterocyclic ring, and halogen; X is selected from the group consisting of chlorine, bromine, optionally substituted alkylsulfonyl, and optionally substituted arylsulfonyl; Y is selected from the group consisting of halogen, a polymer chain, and CR3R4Z, wherein R?3 and R4¿ are the same or different and are selected from the group consisting of hydrogen, optionally substituted alkyl, optionally substituted saturated, unsaturated or aromatic carbocyclic or heterocyclic ring, and halogen; and Z is selected from the group consisting of chlorine, bromine, optionally substituted alkylsulfonyl and optionally substituted arylsulfonyl; provided that when X is optionally substituted alkylsulfonyl or optionally substituted arylsulfonyl, Y is not halogen. The invention also relates to various polymers produced by this process and products comprising these polymers. The process of the invention may also be used in the preparation of A-B type block copolymers.
摘要翻译：本发明涉及一种通过不饱和物质的自由基引发聚合生产低分子量聚合物的方法，其特征在于使用式（I）的不饱和化合物作为链转移剂，其中R 1和R 2是相同或不同，并且选自氢，任选取代的烷基，任选取代的饱和或芳族碳环或杂环以及卤素; X选自氯，溴，任选取代的烷基磺酰基和任选取代的芳基磺酰基; Y选自卤素，聚合物链和CR 3 R 4 Z，其中R 3和R 4相同或不同，选自氢，任选取代的烷基，任选取代的饱和，不饱和或芳族碳环或杂环和卤素; 且Z选自氯，溴，任选取代的烷基磺酰基和任选取代的芳基磺酰基; 条件是当X是任选取代的烷基磺酰基或任选取代的芳基磺酰基时，Y不是卤素。本发明还涉及由该方法生产的各种聚合物和包含这些聚合物的产品。本发明的方法也可以用于制备A-B型嵌段共聚物。

7. 发明授权

EP0951485B1 METHOD OF CONTROLLING POLYMER MOLECULAR WEIGHT AND STRUCTURE 失效
标题翻译：方法控制分子量和聚合物结构的
公开(公告)号：EP0951485B1
公开(公告)日：2003-04-02
申请号：EP98903464.0
申请日：1998-01-07
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
发明人： ANDERSON, Albert, G. , GRIDNEV, Alexei , MOAD, Graeme , RIZZARDO, Ezio , THANG, San, Hoa
IPC分类号： C08F4/00 , C08F2/38 , C07D233/38 , C07D235/02 , C01C1/20 , C01C3/20
CPC分类号： C07D235/02 , C07D233/38 , C08F2/38 , C08F4/00 , C08F220/14 , C08F293/005 , C08F2220/1825 , C08F2438/02 , C08F212/08
摘要： This invention concerns the preparation of polymers of low polydispersity and/or controlled molecular weight and architecture employing living free radical polymerization initiated by an alkoxyamine initiator or nitroxide plus, optionally, a free radical initiator; the polymer produced thereby; selected nitroxide and alkoxyamine initiators; and a process for making the initiators; the polymeric products being useful in protective coatings.

8. 发明公开

EP0951485A2 METHOD OF CONTROLLING POLYMER MOLECULAR WEIGHT AND STRUCTURE 失效
标题翻译：方法控制分子量和聚合物结构的
公开(公告)号：EP0951485A2
公开(公告)日：1999-10-27
申请号：EP98903464.0
申请日：1998-01-07
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
发明人： ANDERSON, Albert, G. , GRIDNEV, Alexei , MOAD, Graeme , RIZZARDO, Ezio , THANG, San, Hoa
IPC分类号： C07D233 , C07D235 , C08F2 , C08F4 , C08F293 , C08F220
CPC分类号： C07D235/02 , C07D233/38 , C08F2/38 , C08F4/00 , C08F220/14 , C08F293/005 , C08F2220/1825 , C08F2438/02 , C08F212/08
摘要： This invention concerns the preparation of polymers of low polydispersity and/or controlled molecular weight and architecture employing living free radical polymerization initiated by an alkoxyamine initiator or nitroxide plus, optionally, a free radical initiator; the polymer produced thereby; selected nitroxide and alkoxyamine initiators; and a process for making the initiators; the polymeric products being useful in protective coatings.

9. 发明公开

EP0711327A1 AQUEOUS DISPERSIONS CONTAINING CYCLOPOLYMER DISPERSANTS 失效
标题翻译：水性分散体，循环变聚合物分散剂CONTAIN
公开(公告)号：EP0711327A1
公开(公告)日：1996-05-15
申请号：EP94925712.0
申请日：1994-07-29
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
发明人： MA, Sheau-Hwa , THANG, San, Hoa , RIZZARDO, Ezio , MOAD, Graeme
IPC分类号： C07D239 , B01J27 , B01J31 , B41M1 , C07C1 , C07C13 , C07C17 , C07C22 , C07C49 , C07C55 , C07C57 , C07C67 , C07C69 , C07C253 , C07C255 , C07C315 , C07C317 , C07D319 , C07F9 , C08F20 , C08F32 , C08F36 , C08F136 , C08F220 , C08F236 , C08F244 , C08L45 , C08L47 , C09D11 , C09D121 , C09D147
CPC分类号： C08F36/20 , C07C69/604 , C07C69/618 , C07C69/65 , C07D239/62 , C07D319/06 , C07F9/4015 , C09D11/326
摘要： PCT No. PCT/AU94/00433 Sec. 371 Date Jan. 26, 1996 Sec. 102(e) Date Jan. 26, 1996 PCT Filed Jul. 29, 1994 PCT Pub. No. WO95/04026 PCT Pub. Date Feb. 9, 1995Compounds of general formula (I) (I) characterised in that R1 and R2 are independently selected from the group consisting of COOR, CN, aryl, substituted aryl, COOH, halogen, C(O)NHR4, C(O)NR5R6; X and Y are independently selected from the group consisting of H, COOH, COOR, CN, R3CO-, C(O)NHR4, C(O)NR5R6, P(O)(OR7)2 and SO2R8; with the proviso that X and Y are not both H; or X and Y together with the carbon atom to which they are attached form a carbocyclic or heterocyclic ring system which can contain oxygen, sulfur or nitrogen atoms; and R, R3, R4, R5, R6, R7 and R8 are various groups; and polymers and copolymers derived from such compounds.

10. 发明授权

EP1054906B1 POLYMERIZATION PROCESS WITH LIVING CHARACTERISTICS AND POLYMERS MADE THEREFROM 有权
标题翻译： POLYMERISATIONSVERFAHREN MIT LEBENDEN EIGENSCHAFTEN UND DARAUS HERGESTELLTE POLYMERE
公开(公告)号：EP1054906B1
公开(公告)日：2006-11-22
申请号：EP98963877.0
申请日：1998-12-11
申请人： E.I. DU PONT DE NEMOURS AND COMPANY , COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION
发明人： CHIEFAIR, John , MAYADUNNE, Roshan, Tyrrel , MOAD, Graeme , RIZZARDO, Ezio , THANG, San, Hoa
IPC分类号： C08F2/38 , C07C327/20 , C07C327/52 , C07C329/04 , C07C329/12 , C07C333/18
CPC分类号： C07D233/60 , C07C325/02 , C07C327/36 , C07C329/16 , C07C333/20 , C07C2601/10 , C07D207/27 , C07D207/325 , C07D207/327 , C07D209/48 , C08F2/38
摘要： A free radical polymerization process suitable for synthesizing polymers is disclosed. The process utilizes novel sulfur based chain transfer agents and is widely compatible over a range of monomers and reaction conditions. Novel polymers having low polydispersity and predictable specific polymer architecture amd molecular weight are produced by the process. The polymers produced by the process are suitable for use as binders in automotive OEM and refinish coatings.
摘要翻译：公开了一种适用于合成聚合物的自由基聚合方法。该方法利用新型的硫基链转移剂，并且在一系列单体和反应条件下广泛相容。通过该方法产生具有低多分散性和预测特异性聚合物结构和分子量的新型聚合物。该方法生产的聚合物适用于汽车OEM和修补涂料中的粘合剂。

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