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    • 2. 发明公开
    • PLASTIC LENS
    • EP3683602A1
    • 2020-07-22
    • EP18855904.1
    • 2018-09-06
    • Daicel Corporation
    • SHIBAMOTO, AkihiroYOSHIMURA, Takashi
    • G02B1/14G02B1/113G02B1/115G02B5/08G02B5/30G02C7/10G02C7/12
    • The present invention aims at providing a plastic lens having excellent heat resistance and durability in which generation of cracks is suppressed even in high-temperature environments or when a mechanical stress being applied, and has excellent surface hardness and scratch resistance. The present invention provides a plastic lens containing a plastic lens substrate, a layer formed on at least one surface of the plastic lens substrate, and a vapor deposition coated film formed on at least one surface of the hard coating layer, the hard coating layer being a cured product of a curable composition containing a polyorganosilsesquioxane, the polyorganosilsesquioxane containing a constituent unit represented by Formula (1), a constituent unit represented by Formula (I), hard coating a constituent unit represented by (II), and a constituent unit represented by Formula (4); wherein a molar ratio of the constituent unit represented by Formula (I) and the constituent unit (II) represented by Formula (II) is 5 or greater and 500 or less,
      a ratio of the constituent unit represented by Formula (1) and the constituent unit represented by Formula (4) relative to the total amount (100 mol%) of siloxane constituent units is from 55 to 100 mol%; a number average molecular weight is from 1000 to 50000; and a molecular weight dispersity (a weight average molecular weight/a number average molecular weight) is from 1.0 to 4.0.
    • 3. 发明公开
    • PLASTIC LENS
    • EP3683603A1
    • 2020-07-22
    • EP18856529.5
    • 2018-09-06
    • Daicel Corporation
    • SHIBAMOTO, AkihiroYOSHIMURA, Takashi
    • G02B1/14C08G77/14C09D4/00C09D183/04G02C7/10G02C7/12
    • An object of the present invention is to provide a plastic lens that has a hard coat layer exhibiting high surface hardness and scratch resistance and that suppresses occurrence of interference fringes. The present invention provides a plastic lens containing a plastic lens substrate; and a hard coat layer formed on at least one surface of the plastic lens substrate, wherein the plastic lens substrate contains at least one resin selected from the group consisting of a polyamide-based resin, a polycarbonate-based resin, an acrylic resin, an allyl-based resin, a urethane-based resin, and a thiourethane-based resin, and the hard coat layer is a cured product of a curable composition containing a polyorganosilsesquioxane described below, a content of the polyorganosilsesquioxane being 80 wt.% or greater relative to the total solid content (100 wt.%) of the curable composition, the polyorganosilsesquioxane containing a constituent unit represented by Formula (1), the polyorganosilsesquioxane having a molar ratio of a constituent units of Formula (I) to constituent units of Formula (II) being from 5 to 500, the polyorganosilsesquioxane having a ratio of the constituent unit of Formula (1) and a constituent unit of Formula (4) relative to the total amount of siloxane constituent units being from 55 to 100 mol%, the polyorganosilsesquioxane having a number average molecular weight being from 1000 to 50000, and the polyorganosilsesquioxane having a molecular weight dispersity being from 1.0 to 4.0.
      [Chem. 1]

              [R 1 SiO 3/2 ]     (1)

      [Chem. 2]

              [R a SiO 3/2 ]     (I)

      [Chem. 3]

              [R b SiO 2/2 (OR c )]     (II)

      [Chem. 4]

              [R 1 SiO 2/2 (OR c )]     (4)