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1. 发明公开

EP0990634A4 ACYLATING AGENTS, ACYLATION METHOD WITH THE USE OF THE SAME AND ADAMANTANE DERIVATIVES 有权
标题翻译：酰化剂和酰化，这意味着并用金刚烷
公开(公告)号：EP0990634A4
公开(公告)日：2005-01-26
申请号：EP99902870
申请日：1999-02-10
申请人： DAICEL CHEM
发明人： ISHII YASUTAKA , NAKANO TATSUYA , HIRAI NARUHISA
IPC分类号： B01J27/128 , B01J31/02 , B01J31/04 , B01J31/20 , C07B41/06 , C07B61/00 , C07C1/207 , C07C1/24 , C07C13/28 , C07C13/615 , C07C27/04 , C07C29/136 , C07C35/22 , C07C45/33 , C07C45/45 , C07C45/46 , C07C47/34 , C07C49/323 , C07C49/345 , C07C49/453 , C07D303/04 , C07D303/14 , C07C13/32 , C07C51/373 , C07C61/135 , C07C62/14 , C07D209/48 , C07D301/14
CPC分类号： C07D303/14 , C07B41/06 , C07C1/24 , C07C45/33 , C07C45/455 , C07C49/323 , C07C49/345 , C07C49/453 , C07C2603/74 , C07D303/04 , C07C13/615
摘要： Acylating agents comprising: (A) a 1,2-dicarbonyl compound or its hydroxy-reduction derivative; (B) an enzyme; and (C) at least one compound selected from among (c1) metal compounds and (c2) imide compounds such as N-hydroxyphthalimide. As the 1,2-dicarbonyl compound or its hydroxy-reduction derivative (A), use may be made of biacetyl, 2,3-butanediol, etc. As the metal compounds (c1), use may be made of a cobalt compound such as cobalt acetate. An acyl group can be efficiently introduced into a methine carbon atom by treating a compound carrying a methine carbon atom such as an adamantane derivative by the above acylating agent.

2. 发明公开

EP1120438A4 METHOD FOR SURFACE MODIFICATION OF MOLDED ARTICLE OF PLASTIC AND METHOD FOR MODIFYING POLYMER 有权
标题翻译：方法用于改性聚合物表面改性形塑料对象和方法
公开(公告)号：EP1120438A4
公开(公告)日：2004-06-09
申请号：EP00915398
申请日：2000-04-07
申请人： DAICEL CHEM
发明人： ISHII YASUTAKA , FUNAKI YOSHINORI , NAKANO TATSUYA
IPC分类号： C08J7/12 , C08J3/00
CPC分类号： C08J7/12
摘要： A method for the surface modification of a molded article of a plastic comprising treating a molded article of a plastic with an oxygen-containing gas such as oxygen, carbon monoxide, a nitrogen oxide or a sulfur oxide in the presence of an imide compound such as N-hydroxy, phthalimide which is represented by formula (1): wherein R and R may be the same or different and each represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group, a hydroxyl group, an alkoxy group, a carboxyl group, an alkoxycarbonyl group or an acyl group, and R and R may be bonded to each other to form together a double bonding or an aromatic or non-aromatic ring, and X represents an oxygen atom or a hydroxyl group; and a method for modifying a polymer comprising treating the polymer with an oxygen-containing gas such as oxygen, carbon monoxide, a nitrogen oxide or a sulfur oxide in the presence of an imide compound which is represented by formula (1).

3. 发明公开

EP2301918A4 PROCESS FOR PRODUCING AMIDE OR LACTAM 审中-公开
标题翻译： VERFAHREN ZUR HERSTELLUNG EINES AMIDS ODER LACTAMS
公开(公告)号：EP2301918A4
公开(公告)日：2012-05-30
申请号：EP09762269
申请日：2009-06-10
申请人： DAICEL CHEM
发明人： IWAHAMA TAKAHIRO , NAKANO TATSUYA , ISHII YASUTAKA
IPC分类号： C07D201/04 , C07B61/00 , C07D223/10
CPC分类号： C07D201/04 , C07D223/10 , Y02P20/52

4. 发明公开

EP1350786A4 PROCESS FOR PRODUCTION OF DICARBOXYLIC ACIDS 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG VONDICARBONSÄUREN
公开(公告)号：EP1350786A4
公开(公告)日：2005-12-14
申请号：EP01270515
申请日：2001-12-07
申请人： DAICEL CHEM
发明人： ISHII YASUTAKA , KAJIKAWA YASUTERU
IPC分类号： C07C51/31 , C07B61/00 , C07C55/14 , C07C55/21
CPC分类号： C07C51/313 , Y02P20/55 , C07C55/02 , C07C55/14 , C07C55/21
摘要： A process for producing dicarboxylic acids by oxidative cleavage of cycloalkanes with oxygen, characterized in that the oxidative cleavage is conducted in the presence of a catalyst constituted of both an imido compound having a cyclic imide skeleton represented by the general formula (I): (I) [wherein X is oxygen or OR (wherein R is hydrogen or a hydroxyl-protecting group)] and a metal compound at a temperature of 80 °C or above in a reaction system having a cycloalkane concentration of 21 wt% or above. The imido compound is N-hydroxyphthalimide or the like, and is used in an amount of about 0.000001 to 0.01 mol per mol of the cycloalkane. In producing dicalboxylic acids by catalytic oxygenation of cycloalkanes, this process attains high space time yield even with a reduced amount of a catalyst.
摘要翻译：一种通过用氧气氧化裂解环烷烃生产二羧酸的方法，其特征在于氧化裂解是在由通式（I）表示的具有环状酰亚胺骨架的亚氨基化合物构成的催化剂存在下进行的：（I ）在环烷烃浓度为21wt％或更高的反应体系中，其中X是氧或OR（其中R是氢或羟基保护基）]和金属化合物在80℃或更高的温度下反应。酰亚胺化合物是N-羟基邻苯二甲酰亚胺等，其用量为每摩尔环烷烃约0.000001-0.01摩尔。在通过环烷烃的催化氧化生产二羧酸时，该方法即使在催化剂量减少的情况下也获得高时空产率。

5. 发明公开

EP1057806A4 POLYMERIZABLE ALICYCLIC ESTERS AND PROCESS FOR PRODUCING THE SAME 审中-公开
标题翻译：高分子聚合酶联免疫吸附
公开(公告)号：EP1057806A4
公开(公告)日：2005-05-18
申请号：EP99972618
申请日：1999-11-15
申请人： DAICEL CHEM
发明人： ISHII YASUTAKA , INOUE KEIZO
IPC分类号： B01J27/08 , B01J31/02 , B01J31/22 , C07B61/00 , C07C67/08 , C07C69/00 , C07C69/013 , C07C69/54 , C07C69/56 , C07C69/73 , C08F20/10 , B01J27/125
CPC分类号： C07C69/54 , C07C2602/28 , C07C2603/24 , C07C2603/68 , Y02P20/55
摘要： Polymerizable alicyclic esters represented by formula (1) or (2), wherein rings A, B, C, D, and E each represents a nonaromatic carbon ring; R represents a polymerizable unsaturated group; and R?a1, Rb1, and Rc1¿ are the same or different and each represents hydrogen, a hydroxyl group optionally protected by a protective group, or a group represented by RCO¿2? (R has the same meaning as the above). Examples of the rings A, B, C, D, and E include a cyclopentane ring, a cyclohexane ring, and crosslinked rings. Examples of R include vinyl, isopropenyl, and allyl.
摘要翻译：本发明的可聚合脂环族酯由下式（1）或（2）表示：其中环A，环B，环C，环D和环E各自为非芳香族碳环，其中R为可聚合的不饱和基团，R a1，R b1和R c1各自彼此相同或不同，为氢原子，可被保护基保护的羟基，或 RCO 2基团，其中R具有与上述相同的含义。环A，环B，环C，环D和环E各自为例如环戊烷环，环己烷环或桥环。 R包括例如乙烯基，异丙烯基或芳基。

6. 发明公开

EP0824962A4 OXIDATION CATALYST SYSTEM AND PROCESS FOR OXIDATION WITH THE SAME 失效
标题翻译：氧化铝制氧化铝系统
公开(公告)号：EP0824962A4
公开(公告)日：1999-01-07
申请号：EP97902584
申请日：1997-02-06
申请人： DAICEL CHEM
发明人： ISHII YASUTAKA , NAKANO TATSUYA
IPC分类号： B01J31/02 , B01J31/12 , B01J31/22 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/36 , C07C49/453 , C07C49/675 , C07C51/265 , C07C51/31
CPC分类号： C07C51/313 , B01J31/006 , B01J31/0247 , B01J31/2234 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/22 , B01J2531/26 , B01J2531/31 , B01J2531/46 , B01J2531/48 , B01J2531/56 , B01J2531/64 , B01J2531/72 , B01J2531/842 , B01J2531/845 , C07B2200/09 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/36 , C07C49/453 , C07C49/675 , C07C51/265 , C07C2601/10 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2602/08 , C07C2602/20 , C07C2602/28 , C07C2602/42 , C07C2603/18 , C07C2603/68 , C07C2603/74 , C07C2603/78 , C07C2603/86 , C07C49/385 , C07C49/413 , C07C49/403 , C07C49/597 , C07C49/603 , C07C49/607 , C07C47/542 , C07C47/565 , C07C49/76 , C07C49/78 , C07C65/21 , C07C63/16 , C07C63/26 , C07C63/06 , C07C65/03 , C07C55/14 , C07C55/18 , C07C55/20 , C07C35/06 , C07C35/20 , C07C35/37 , C07C35/28 , C07C35/36 , C07C35/44 , C07C35/32 , C07C35/38 , C07C35/08 , C07C33/035 , C07C35/18 , C07C35/30
摘要： Substrates (such as cycloalkalnes, polycyclic hydrocarbons or aromatic compounds having methyl or methylene adjacent to their respective aromatic rings) are converted into oxides (such as ketones, alcohols or carboxylic acids) through oxygenation in the presence of an oxidation catalyst system comprising an imide compound of general formula (1) (such as N-hydroxyphthalimide) and a co-catalyst containing an element selected from the group consisting of group 2A elements of the periodic table, transition metals (group 3A to 7A, 8, 1B and 2B elements of the periodic table) and group 3B elements of the periodic table (except phosphovanadomolybdic acid) (wherein R?1 and R2¿ are each hydrogen or a substituent such as halogen, or alternatively R?1 and R2¿ may be united to form a double bond or an aromatic or non-aromatic 5- to 12-membered ring; X is O or OH; and n is 1 to 3).
摘要翻译：本发明涉及包含酰亚胺化合物和助催化剂的氧化催化体系，所述助催化剂包含含元素周期表第7A族元素的化合物和含有元素周期表第8族元素的化合物。本发明还涉及一种氧化方法，其包括在所述氧化催化体系的存在下使底物与氧接触的步骤。

7. 发明公开

EP2248792A4 PROCESS FOR PRODUCTION OF OXYGEN-CONTAINING ORGANIC COMPOUND 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG EINER SAUERSTOFFHALTIGEN ORGANISCHEN VERBINDUNG
公开(公告)号：EP2248792A4
公开(公告)日：2012-08-15
申请号：EP09717329
申请日：2009-02-27
申请人： DAICEL CHEM
发明人： TAKANO MINORU , HIRAI NARUHISA , ISHII YASUTAKA
IPC分类号： C07C27/12 , B01J27/02 , B01J27/053 , C07B61/00 , C07C29/50 , C07C35/37 , C07C45/33 , C07C45/36 , C07C47/542 , C07C49/39 , C07C49/78 , C07C51/00 , C07C51/235 , C07C51/265 , C07C53/126 , C07C63/06
CPC分类号： C07C45/33 , B01J27/053 , B01J37/0201 , C07C29/50 , C07C45/36 , C07C51/00 , C07C51/265 , C07C2603/74 , Y02P20/55 , C07C35/37 , C07C47/542 , C07C49/417 , C07C63/04

8. 发明公开

EP2116529A4 PROCESS FOR PRODUCTION OF AMIDE OR LACTAM 审中-公开
标题翻译：用于生产酰胺或内酰胺
公开(公告)号：EP2116529A4
公开(公告)日：2010-09-08
申请号：EP07859896
申请日：2007-12-20
申请人： DAICEL CHEM
发明人： ISHII YASUTAKA , IWAHAMA TAKAHIRO , NAKANO TATSUYA
IPC分类号： C07D201/04 , C07C231/10 , C07D211/76 , C07D223/10 , C07D225/02 , C07D227/087
CPC分类号： C07C231/10 , C07D201/04 , C07D211/76 , C07D223/10 , C07D225/02 , C07D227/087

9. 发明公开

EP1433527A4 CATALYSTS COMPRISED OF N-SUBSTITUTED CYCLIC IMIDES AND PROCESSES FOR PREPARING ORGANIC COMPOUNDS WITH THE CATALYSTS 有权
标题翻译：催化剂的N-取代环状酰亚胺AND METHOD FOR有机化合物与催化剂生产
公开(公告)号：EP1433527A4
公开(公告)日：2007-03-07
申请号：EP02767988
申请日：2002-09-20
申请人： DAICEL CHEM
发明人： ISHII YASUTAKA , HIRAI NARUHISA , TERADA MASAHIKO
IPC分类号： B01J31/02 , B01J31/22 , B01J31/28 , B01J31/32 , C07C45/36
CPC分类号： C07C45/36 , B01J31/0247 , B01J31/2243 , B01J2231/42 , B01J2231/70 , B01J2231/72 , B01J2531/72 , B01J2531/845 , Y02P20/55
摘要： A catalyst comprised of an imide compound having an N-substituted cyclic imide skeleton represented by the general formula (I): (I) (wherein R is a hydroxyl-protecting group). The hydroxyl-protecting group (R) is preferably a hydrolyzable one and examples thereof include groups derived from carboxylic acid, sulfonic acid, carbonic acid, carbamic acid, sulfuric acid, nitric acid, phosphoric acid, boric acid, and so on by the removal of a hydroxyl group. The catalyst may be comprised of a combination of the above imide compound and a metal compound. Reactions of (A) radical-forming compounds with (B) radical -scavenging compounds in the presence of the above catalyst give products of addition or substitution reaction between the compounds (A) and (B) or derivatives thereof. According to the invention, organic compounds can be prepared through addition or substitution reaction or the like under mild conditions with high selectivity in high yield.

10. 发明公开

EP0980706A4 OXIDATION CATALYST SYSTEM AND METHOD OF OXIDATION WITH THE SAME 有权
标题翻译：催化剂为与催化剂氧化氧化和方法
公开(公告)号：EP0980706A4
公开(公告)日：2005-08-24
申请号：EP99902869
申请日：1999-02-10
申请人： DAICEL CHEM
发明人： ISHII YASUTAKA , NAKANO TATSUYA
IPC分类号： B01J23/46 , B01J31/02 , B01J31/24 , B01J31/28 , C07B41/06 , C07B61/00 , C07C45/38 , C07C45/39 , C07C47/02 , C07C47/115 , C07C47/21 , C07C47/347
CPC分类号： B01J31/2404 , B01J23/462 , B01J31/0202 , B01J31/0208 , B01J2231/763 , B01J2531/821 , C07C45/38 , C07C45/39 , C07C47/347
摘要： An oxidation catalyst system comprising (A) a ruthenium compound and (B) a dihydroxybenzene or an oxidation product thereof. Examples of the ruthenium compound (A) include ruthenium complexes, e.g., dichlorotris(triphenylphosphine)ruthenium(II), and Ru/C. Examples of the dihydroxybenzene or oxidation product (B) include hydroquinone. When an alcohol is oxidized with molecular oxygen in the presence of the oxidation catalyst system, the corresponding carbonyl compound is obtained in a high yield. Primary alcohols are more selectively oxidized than secondary alcohols.

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