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    • 5. 发明公开
    • METHOD FOR ALKYLATING AN AMINO COMPOUND
    • EP3327009A1
    • 2018-05-30
    • EP16200228.1
    • 2016-11-23
    • Borealis Agrolinz Melamine GmbH
    • GABRIEL, HerbertDICKE, René
    • C07D251/70C07C275/06
    • C07D251/70C07C273/1863C07C275/06
    • The invention relates to a method for alkylating an amino compound, characterized in that at least one triazine derivative of general formula (I)

      or at least one urea or urea derivative of the general formula (II)

      wherein
      • R 4 and R 5 mean independently from each other Q 1 or a moiety of the formula R 6 -N-R 7 or R 8 -N-R 9 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat
      - Q 1 means a linear or branched C 1 -C 30 -alkyl or a cyclic substituent in form of a C 5 -C 20 -cycloalkyl, a C 5 -C 20 -aryl, a C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl or an amide of a cyclic unsaturated carboxylic acid, whereat the C 1 -C 30 -alkyl or the cyclic substituent can be interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O-,

      • R 1 , R 2 , R 3 , R 6 , R 7 , R 8 and R 9 mean independently from each other H, linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cyclo alkyl, C 5 -C 20 -aryl, C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which in each case can be interrupted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, - OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, and
      • X means O or S,
      is reacted with at least one alcohol of the general formula (III)

               R 10 -OH

      wherein R 10 means a linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cycloalkyl, or C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which can be in each case interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, wherein the reaction is carried out in the presence of at least one Ruthenate of the general formula (IV) M n (RuO 4 ) and/or at least one Perruthenate of the general formula (V) M(RuO 4 )n wherein the cation M is selected from a group comprising an alkali, earth alkali or substituted or non-substituted ammonium cation.
    • 6. 发明公开
    • NOVEL TRIAZINE PRECONDENSATE AND METHOD FOR OBTAINING THE SAME
    • 新的三嗪前体及其获得方法
    • EP3263561A1
    • 2018-01-03
    • EP16176878.3
    • 2016-06-29
    • Borealis Agrolinz Melamine GmbH
    • GABRIEL, HerbertDICKE, RenéPUCHINGER, Helmut
    • C07D251/70
    • C07D251/70
    • The present invention relates to a triazine precondensate according to the general formula (I)

      wherein R 1 means Q 1 or a moiety of the formula R 3 -N-R 4 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 9 means Q 1 or a moiety of the formula R 7 -N-R 8 connected with the nitrogen atom to the triazine ring of the structure of formula (I),
      wherein R 2 , R 3 , R 4 and R 6 mean independently from each other H, Q1 or R 8 mean independently from each other H, Q 1 ,

      R 7 and

      or

      R 10 and R 11 mean independently from each other R 7 or R 8 ; R 5 means linear or branched C 2 -C 20 -alkyl that can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms, R x , Ry mean independently from each other H, OH, Q 1 , -[C 1 -C 18 ]-OH or

      wherein Q 1 means linear or branched C 1 -C 20 -alkyl, linear or branched C 2 -C 20 -alkenyl, linear or branched C 2 -C 20 -alkinyl, C 3 -C 10 -cycloalkyl, C 5 -C 7 -cycloalkenyl, which in each case can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms and/or by one or more groups of the type -C(O)O-, -OC(O)-, -C(O)-, -NHC(O)O-, -OC(O)NH- and/or -OC(O)O-; and wherein n = 0-10, preferably 1-8, most preferably 1 - 5, and m = 0-8, preferably 1-7, most preferably 1 - 5 or mixtures thereof.
    • 本发明涉及根据通式(I)的三嗪预缩合物,其中R 1是指Q1或式R3-N-R4与氮原子连接至式(I)结构的三嗪环的部分,其中 R9是指Q1或式R7-NR8的与氮原子连接的式(I)结构的三嗪环的部分,其中R2,R3,R4和R6彼此独立地表示H,Q1或R8 彼此独立地表示H,Q1,R7和/或R10和R11彼此独立地表示R7或R8; R5是指可被一个或多个氧原子,硫原子,取代或未取代的氮原子间隔的直链或支链C2-C20-烷基,Rx,Ry彼此独立地表示H,OH,Q1, - [C1- C18] -OH或其中Q1表示直链或支链C1-C20-烷基,直链或支链C2-C20-链烯基,直链或支链C2-C20-炔基,C3-C10-环烷基,C5-C7-环烯基, 可以被一个或多个氧原子,硫原子,取代或未取代的氮原子和/或一个或多个-C(O)O - , - OC(O) - ,-C(= O) - , - NHC(O)O-,-OC(O)NH-和/或-OC(O)O-。 并且其中n = 0-10,优选1-8,最优选1-5和m = 0-8,优选1-7,最优选1-5或其混合物。
    • 9. 发明公开
    • METHOD FOR ALKYLATING AN AMINO COMPOUND
    • EP3544963A1
    • 2019-10-02
    • EP17816488.5
    • 2017-11-23
    • Borealis Agrolinz Melamine GmbH
    • GABRIEL, HerbertDICKE, René
    • C07D251/70C07C275/06
    • The invention relates to a method for alkylating an amino compound, characterized in that at least one triazine derivative of general formula (I) or at least one urea or urea derivative of the general formula (II) wherein €¢ R 4 and R 5 mean independently from each other Q 1 or a moiety of the formula R 6 -N-R 7 or R 8 -N-R 9 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat - Q 1 means a linear or branched C 1 -C 30 -alkyl or a cyclic substituent in form of a C 5 -C 20 -cycloalkyl, a C 5 -C 20 -aryl, a C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl or an amide of a cyclic unsaturated carboxylic acid, whereat the C 1 -C 30 -alkyl or the cyclic substituent can be interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O-, €¢ R 1 , R 2 , R 3 , R 6 , R 7 , R 8 and R 9 mean independently from each other H, linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cyclo alkyl, C 5 -C 20 -aryl, C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which in each case can be interrupted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, - OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, and €¢ X means O or S, is reacted with at least one alcohol of the general formula (III) €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ R 10 -OH wherein R 10 means a linear or branched C 1 -C 20 -alkyl, C 5 -C 20 -cycloalkyl, or C 1 -C 20 -alkylsubstituted C 5 -C 20 -aryl, which can be in each case interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, wherein the reaction is carried out in the presence of at least one Ruthenate of the general formula (IV) M n (RuO 4 ) and/or at least one Perruthenate of the general formula (V) M(RuO 4 )n wherein the cation M is selected from a group comprising an alkali, earth alkali or substituted or non-substituted ammonium cation.
    • 10. 发明公开
    • NOVEL TRIAZINE-PRECONDENSATE-ALDEHYDE CONDENSATION PRODUCTS AND METHOD FOR OBTAINING THE SAME
    • EP3478667A1
    • 2019-05-08
    • EP17740303.7
    • 2017-06-28
    • Borealis Agrolinz Melamine GmbH
    • GABRIEL, HerbertDICKE, RenéPUCHBERGER, Helmut
    • C07D251/00
    • The present invention relates to a triazine-precondensate-aldehyde condensation products is provided that is obtainable by reacting a) at least one triazine compound of the general formulae (I) b) at least one aldehyde, in particular formaldehyde, and c) at least one triazine precondensate of the general formula (II) as additive, wherein R 1 means Q 1 or a moiety of the formula R 3 -N-R 4 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein Rg means Q 1 or a moiety of the formula R 7 -N-R 8 connected with the nitrogen atom to the triazine ring of the structure of formula (I), wherein R 2 , R 3 , R 4 and R 6 mean independently from each other H, Q 1 or R 7 and R 8 mean independently from each other H, Q 1 , or R 10 and R 11 mean independently from each other R 7 or R 8 ; R 5 means linear or branched C 2 -C 20 -alkyl that can be interrupted by one or more oxygen atoms, sulphur atoms, substituted and non-substituted nitrogen atoms, R x , R y mean independently from each other H, OH, Q 1 , -[C 1 -C 18 ]-OH or wherein Q 1 means linear or branched C 1 -C 20 -alkyl, linear or branched C 2 -C 20 -alkenyl, linear or branched C 2 -C 20 -alkinyl, C 3 -C 10 -cycloalkyl, C 5 -C 7 -cycloalkenyl, which in each case can be interrupted by one or more oxygen atoms, sulphur atoms, substituted or non-substituted nitrogen atoms and/or by one or more groups of the type -C(O)O-, -OC(O)-, -C(O)-, -NHC(O)O-, -OC(O)NH- and/or -OC(O)O-; and wherein n = 0-10, preferably 1-8, most preferably 1 - 5, and m = 0-8, preferably 1-7, most preferably 1 - 5 or mixtures thereof.