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    • 9. 发明公开
    • TEILKRISTALLINES POLYETHYLENTEREPHTHALAT
    • EP1727849A1
    • 2006-12-06
    • EP05700331.1
    • 2005-01-24
    • Bühler AG
    • CHRISTEL, AndreasCULBERT, Brent AllanJÜRGENS, Theodor
    • C08G63/80C08G63/183C08G63/78
    • C08G63/80C08G63/183C08G63/785
    • The invention relates to a partially crystalline polyethylene terephthalate having a degree of polymerization which is greater than 80, particularly greater than 100, produced from a diol component and a dicarboxylic acid component, wherein according to the invention the DSC melting point, when measured with a heating rate of 10°C/Min during the first passage and second passage, is less than the melting temperature (Tm) of a comparable standard polyethylene terephthalate which is dependent upon the comonomer content. The inventive method for the production of a polyethylene terephthalate comprises a step for the production of a polycondensate prepolymer melt; a step for the formation of granules and the solidification of the polycondensate prepolymer melt; a step for increasing the degree of crystallization of the prepolymer granulates and a step for increasing the molecular weight of the granulates by means of solid phase polycondensation, wherein according to the invention a treatment temperature of 220° C in step d) is not exceeded.
    • 本发明涉及由二醇组分和二羧酸组分制备的具有大于80,特别大于100的聚合度的部分结晶聚对苯二甲酸乙二醇酯,其中根据本发明,DSC熔点用 在第一次通过和第二次通过期间10℃/ min的加热速率小于取决于共聚单体含量的可比较的标准聚对苯二甲酸乙二醇酯的熔融温度(Tm)。 用于生产聚对苯二甲酸乙二醇酯的本发明的方法包括制备缩聚预聚物熔体的步骤; 形成颗粒的步骤和缩聚预聚物熔体的固化; 增加预聚物颗粒的结晶度的步骤和通过固相缩聚增加颗粒的分子量的步骤,其中根据本发明,步骤d)中的处理温度不超过220℃ 。