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    • 6. 发明公开
    • HYDROGENATED BLOCK COPOLYMERS AND CROSSLINKING COMPOSITIONS CONTAINING THE SAME
    • 水性木糖醇脱乙酰壳多糖VERNETZENDE ZUSAMMENSETZUNGEN
    • EP2050773A1
    • 2009-04-22
    • EP07792089.0
    • 2007-08-07
    • Asahi Kasei Chemicals Corporation
    • KUSANOSE, YasuhiroFUJIWARA, MasahiroSHIMIZU, Daisuke
    • C08F297/04C08F8/04
    • C08F8/04C08F297/04C08L51/006C08L53/025C08L67/02C08L69/00C08L2666/02C08L2666/24C08L2666/04
    • A hydrogenated block copolymer obtained by selective hydrogenation of a block copolymer comprising at least two polymer blocks (A) which each comprise vinyl aromatic monomer units as the main component and may be the same or different from each other, at least two polymer blocks (B) which each comprise monomer units derived from a conjugated diene of 5 or more carbon atoms as the main component and may be the same or different from each other, and one or more polymer blocks (C) which each comprise monomer units derived from a conjugated diene of 4 or more carbon atoms as the main component and may be the same or different from each other and/or one or more random copolymer blocks (D) which each comprise monomer units (d-1) derived from a conjugated diene of 4 or more carbon atoms and vinyl aromatic monomer units (d-2) as the main components, wherein the degree of hydrogenation of olefinically unsaturated double bonds of the blocks (B) is 50% or below; the degrees of hydrogenation of olefinically unsaturated double bonds of the blocks (C) and (D) are 80% or above; the content of vinyl aromatic monomer units in the block copolymer is 10 to 85% by weight; the contents of A, B, C and D in the block copolymer are 10 to 70% by weight, 1 to 15% by weight, 0 to 85% by weight and 0 to 85% by weight respectively with the proviso that the sum of C and D is 25 to 85% by weight and the sum total of A, B, C and D is 100% by weight; and the weight-average molecular weight (M) of A satisfies the relationship: M≥20000/[1+{content (%) of (d-2)}/20].
    • 通过选择性氢化包含至少两个聚合物嵌段(A)的嵌段共聚物获得的氢化嵌段共聚物,它们各自包含乙烯基芳族单体单元作为主要组分并且可以彼此相同或不同,至少两个聚合物嵌段(B ),其各自包含衍生自5个或更多个碳原子的共轭二烯作为主要成分的单体单元,并且可以彼此相同或不同,以及一个或多个聚合物嵌段(C),其各自包含衍生自共轭 二烯以4个以上的碳原子作为主要成分,可以相同或不同,和/或一个或多个无规共聚物嵌段(D),其各自包含衍生自共轭二烯的单体单元(d-1)4 或更多的碳原子和乙烯基芳族单体单元(d-2)作为主要成分,其中嵌段(B)的烯属不饱和双键的氢化度为50%以下; 嵌段(C)和(D)的烯属不饱和双键的氢化度为80%以上; 嵌段共聚物中乙烯基芳族单体单元的含量为10〜85重量% 嵌段共聚物中A,B,C和D的含量分别为10〜70重量%,1〜15重量%,0〜85重量%,0〜85重量%,条件是 C和D为25〜85重量%,A,B,C和D的总和为100重量% A的重均分子量(M)满足M‰¥20000 / [1+ {含量(%)(d-2)} / 20]。
    • 7. 发明公开
    • PHOTOSENSITIVE RESIN COMPOSITION
    • 光敏树脂组合物
    • EP1881370A1
    • 2008-01-23
    • EP06745827.3
    • 2006-04-28
    • Asahi Kasei Chemicals Corporation
    • FUJIWARA, MasahiroDOI, KenjiARAKI, YoshifumiYAMAZAWA, Kazuyoshi
    • G03F7/033G03F7/00
    • G03F7/033Y10S430/106
    • The present invention relates to a photosensitive resin composition comprising at least a thermoplastic elastomer (a), a photopolymerizable unsaturated monomer (b), and a photopolymerization initiator (c), characterized in that the thermoplastic elastomer (a) comprises at least vinyl aromatic hydrocarbon units, butadiene units, and alkylene units and contains alkylene units not less than 5 wt% and not more than 80 wt% with respect to the total amount of butadiene units and alkylene units. The present invention provides a photosensitive resin composition that simultaneously achieves excellent fine line reproducibility, ester solvent resistance, and prevention of cracks occurring on plate surface.
    • 本发明涉及至少含有热塑性弹性体(a),光聚合性不饱和单体(b)和光聚合引发剂(c)的感光性树脂组合物,其特征在于,热塑性弹性体(a)至少含有乙烯基芳香族烃 单元,丁二烯单元和亚烷基单元,并且相对于丁二烯单元和亚烷基单元的总量包含不小于5重量%且不大于80重量%的亚烷基单元。 本发明提供一种同时实现优异的细线再现性,耐酯溶剂性和防止板表面产生裂纹的感光性树脂组合物。