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    • 1. 发明公开
    • NON-ALKALI GLASS, AND PROCESS FOR PRODUCTION OF NON-ALKALI GLASS
    • NICHTALKALISCHES GLAS U​​ND VERFAHREN ZUR HERSTELLUNG DES NICHTALKALISCHEN GLASES
    • EP2660213A1
    • 2013-11-06
    • EP11852770.4
    • 2011-12-20
    • Asahi Glass Company, Limited
    • TSUJIMURA TomoyukiNISHIZAWA ManabuKOIKE Akio
    • C03C3/087C03C1/00C03C3/091C03C3/093G02B1/00G02F1/1333
    • C03C3/091C03C3/087C03C3/093
    • The present invention relates to an alkali-free glass having a strain point of 735°C or higher, an average thermal expansion coefficient at from 50 to 350°C of from 30×10 -7 to 40×10 -7 /°C, a temperature T 2 at which a glass viscosity is 10 2 dPa·s of 1,710°C or lower, a temperature T 4 at which a glass viscosity is 10 4 dPa·s of 1,340°C or lower, and a devitrification temperature of 1,330°C or lower, the alkali-free glass including, in terms of mol% on the basis of oxides: SiO 2 66 to 69, Al 2 O 3 12 to 15, B 2 O 3 0 to 1.5, MgO 6 to 9.5, CaO 7 to 9, SrO 0.5 to 3, BaO 0 to 1, and ZrO 2 0 to 2, in which MgO+CaO+SrO+BaO is from 16 to 18.2, MgO/(MgO+CaO+SrO+BaO) is 0.35 or more, MgO/(MgO+CaO) is 0.40 or more and less than 0.52, and MgO/(MgO+SrO) is 0.45 or more.
    • 本发明涉及应变点为735℃以上,50〜350℃的平均热膨胀系数为30×10 -7〜40×10 -7 /℃的无碱玻璃, 玻璃粘度为10 2 dPa·s为1710℃以下的温度T 2,玻璃粘度为10 4 dPa·s的温度T 4为1340℃以下,失透温度为1330℃ ℃以下的无碱玻璃,以氧化物:SiO 2 66〜69,Al 2 O 3 12〜15,B 2 O 3 0〜1.5,MgO 6〜9.5, CaO 7〜9,SrO 0.5〜3,BaO 0〜1,ZrO 2 0〜2,MgO + CaO + SrO + BaO为16〜18.2,MgO /(MgO + CaO + SrO + BaO)为0.35 以上,MgO /(MgO + CaO)为0.40以上且小于0.52,MgO /(MgO + SrO)为0.45以上。
    • 2. 发明公开
    • ALKALI FREE GLASS AND METHOD FOR PRODUCING ALKALI FREE GLASS
    • ALKALIFREIES GLAS U​​ND VERFAHREN ZUR HERSTELLUNG VON ALKALIFREIEM GLAS
    • EP2650262A1
    • 2013-10-16
    • EP11847758.7
    • 2011-12-02
    • Asahi Glass Company, Limited
    • TSUJIMURA TomoyukiNISHIZAWA ManabuKOIKE Akio
    • C03C3/087C03C1/00C03C3/091C03C3/093
    • C03C3/091C03C3/087
    • The present invention relates to an alkali-free glass having a strain point of 725°C or higher, an average thermal expansion coefficient at from 50 to 300°C of from 30×10 -7 to 40×10 -7 /°C, a temperature T 2 at which a glass viscosity is 10 2 dPa·s of 1,710°C or lower, and a temperature T 4 at which a glass viscosity is 10 4 dPa·s of 1,320°C or lower, the alkali-free glass including, in terms of mol% on the basis of oxides, SiO 2 : 66 to 70, Al 2 O 3 : 12 to 15, B 2 O 3 : 0 to 1.5, MgO: more than 9.5 and 13 or less, CaO: 4 to 9, SrO: 0.5 to 4.5, BaO: 0 to 1, and ZrO 2 : 0 to 2, in which MgO+CaO+SrO+BaO is from 17 to 21, MgO/(MgO+CaO+SrO+BaO) is 0.4 or more, MgO/(MgO+CaO) is 0.4 or more, MgO/(MgO+SrO) is 0.6 or more, and the alkali-free glass does not substantially contain an alkali metal oxide.
    • 本发明涉及应变点为725℃以上,50〜300℃的平均热膨胀系数为30×10 -7〜40×10 -7 /℃的无碱玻璃, 玻璃粘度为10 2 dPa·s为1710℃以下的温度T 2,玻璃粘度为10 4 dPa·s的温度T 4为1320℃以下,无碱玻璃 包括以氧化物为基准的摩尔%,SiO 2:66〜70,Al 2 O 3:12〜15,B 2 O 3:0〜1.5,MgO:9.5以上13以下,CaO: 4〜9,SrO:0.5〜4.5,BaO:0〜1,ZrO 2:0〜2,MgO + CaO + SrO + BaO为17〜21,MgO /(MgO + CaO + SrO + BaO) 为0.4以上,MgO /(MgO + CaO)为0.4以上,MgO /(MgO + SrO)为0.6以上,无碱玻璃基本不含有碱金属氧化物。
    • 4. 发明公开
    • ALKALI-FREE GLASS AND METHOD FOR PRODUCING SAME
    • ALKALIFREIES GLAS U​​ND VERFAHREN ZU SEINER HERSTELLUNG
    • EP2450319A1
    • 2012-05-09
    • EP10794089.2
    • 2010-06-25
    • Asahi Glass Company, Limited
    • NAGAI KensukeKUROKI YuichiNISHIZAWA ManabuTSUJIMURA Tomoyuki
    • C03C3/091C03B1/00C03C3/087C03C3/093C03C6/00G02F1/1333G09F9/30
    • C03C3/087C03C1/00C03C3/091C03C3/093G02F2001/133302
    • The present invention provides an alkali-free glass that has a high strain point, low viscosity and low devitrification, and is easily subjected to float molding and fusion molding. The present invention relates to an alkali-free glass having a strain point of 725°C or higher; an average thermal expansion coefficient at 50 to 300°C of 30 × 10 -7 to 40 × 10 -7 /°C; a temperature T 2 at which a glass viscosity becomes 10 2 dPa·s of 1,710°C or lower; a temperature T 4 at which a glass viscosity becomes 10 4 dPa·s of 1,330°C or lower; a glass surface devitrification temperature (T c ) of 1,330°C or lower; a glass internal devitrification temperature (T d ) of 1,330°C or lower, and including, in terms of mol% on the basis of oxides, SiO 2 : 66 to 70, Al 2 O 3 : 12 to 15, B 2 O 3 : 0 to 1.5, MgO: 6 to 9.5, CaO: 4.5 to 8, SrO: 2 to 7, BaO: 0 to less than 1, and ZrO 2 : 0 to 2, provided that MgO + CaO + SrO + BaO is 14 to 18.2, MgO/(MgO + CaO + SrO + BaO) is 0.35 or greater, MgO/(MgO + CaO) is 0.52 or greater, and MgO/(MgO + SrO) is 0.45 or greater, in which the alkali-free glass does not substantially contain alkali metal oxides.
    • 本发明提供一种具有高应变点,低粘度和低失透性的无碱玻璃,并且容易进行浮法成型和熔融成型。 本发明涉及应变点为725℃以上的无碱玻璃; 50〜300℃的平均热膨胀系数为30×10 -7〜40×10 -7 /℃; 玻璃粘度为10 2 dPa·s的温度T 2为1710℃以下; 玻璃粘度为10 4 dPa·s为1330℃以下的温度T 4; 玻璃表面失透温度(T c)为1330℃以下; 玻璃内部失透温度(T d)为1330℃以下,以SiO 2为66〜70,Al 2 O 3:12〜15,B 2 O 3为基准,以氧化物为基准的摩尔% :0〜1.5,MgO:6〜9.5,CaO:4.5〜8,SrO:2〜7,BaO:0〜小于1,ZrO 2:0〜2,条件是MgO + CaO + SrO + BaO为14 至18.2,MgO /(MgO + CaO + SrO + BaO)为0.35以上,MgO /(MgO + CaO)为0.52以上,MgO /(MgO + SrO)为0.45以上, 玻璃基本上不含有碱金属氧化物。
    • 6. 发明公开
    • ALKALI-FREE GLASS SUBSTRATE AND METHOD FOR REDUCING THICKNESS OF ALKALI-FREE GLASS SUBSTRATE
    • ALKALIFREIE GLASSUBSTRATE UND VERFAHREN ZUR VERRINGERUNG DER DICKE EINES ALKALIFREIEN GLASSUBSTRATS
    • EP2860160A1
    • 2015-04-15
    • EP13797158.6
    • 2013-05-30
    • Asahi Glass Company, Limited
    • TOKUNAGA HirofumiTSUJIMURA TomoyukiNISHIZAWA ManabuKOIKE Akio
    • C03C3/091C03C3/087C03C3/093C03C15/00
    • C03C15/00C03C3/087C03C3/091
    • The present invention relates to an alkali-free glass substrate with a thickness of 0.4 mm or less, which has been reduced in thickness by 5 µm or more by a hydrofluoric acid (HF) etching treatment, in which the alkali-free glass substrate contains an alkali-free glass described below, and the alkali-free glass substrate after reduced in thickness has a specific modulus of 32 MNm/kg or more and a photoelastic constant of 31 nm/MPa/cm or less, the alkali-free glass having a strain point of 710°C or higher, an average thermal expansion coefficient at 50 to 350°C of from 30×10 -7 to 43×10 -7 /°C, a temperature T 2 at which a glass viscosity reaches 10 2 dPa·s of 1710°C or lower, a temperature T 4 at which the glass viscosity reaches 10 4 dPa·s of 1320°C or lower, and containing, indicated by mol% on the basis of oxides, SiO 2 66 to 70, Al 2 O 3 12 to 15, B 2 O 3 0 to 1.5, MgO exceeding 9.5 to 13, CaO 4 to 9, SrO 0.5 to 4.5, BaO 0 to 1, and ZrO 2 0 to 2, in which MgO+CaO+SrO+BaO is from 17 to 21, MgO/(MgO+CaO+SrO+BaO) is 0.40 or more, MgO/(MgO+CaO) is 0.40 or more, and MgO/(MgO+SrO) is 0.60 or more.
    • 本发明涉及厚度为0.4mm以下的无碱玻璃基板,其通过氢氟酸(HF)蚀刻处理将厚度减小5μm以上,其中无碱玻璃基板含有 下述的无碱玻璃,厚度减小后的无碱玻璃基板的比模量为32MNm / kg以上,光弹性常数为31nm / MPa / cm以下,无碱玻璃具有 应变点为710℃以上,50〜350℃的平均热膨胀系数为30×10 -7〜43×10 -7 /℃,玻璃粘度为10 2的温度T 2 dPa·s为1710℃以下,玻璃粘度达到10 4 dPa·s为1320℃以下的温度T 4,以氧化物的摩尔%表示,SiO 2 66〜70 ,Al 2 O 3 12〜15,B 2 O 3 0〜1.5,MgO超过9.5〜13,CaO 4〜9,SrO 0.5〜4.5,BaO 0〜1,ZrO 2 0〜2,MgO + CaO +的SrO + BaO的 MgO /(MgO + CaO + SrO + BaO)为0.40以上,MgO /(MgO + CaO)为0.40以上,MgO /(MgO + SrO)为0.60以上。
    • 7. 发明公开
    • NON-ALKALI GLASS AND METHOD FOR PRODUCING SAME
    • VERFAHREN ZUR HERSTELLUNG DAVON的NICHTALKALISCHES GLAS
    • EP2842918A1
    • 2015-03-04
    • EP13780855.6
    • 2013-04-24
    • Asahi Glass Company, Limited
    • TOKUNAGA HirofumiTSUJIMURA TomoyukiNISHIZAWA ManabuKOIKE Akio
    • C03C3/091C03C1/02C03C3/093
    • C03C3/091C03C3/087C03C3/093
    • The present invention relates to a non-alkali glass having a strain point of from 710°C to lower than 725°C, an average thermal expansion coefficient at from 50 to 300°C of from 30×10 -7 to 43×10 -7 /°C, a temperature T 2 at which glass viscosity reaches 10 2 dPa·s of 1710°C or lower, a temperature T 4 at which the glass viscosity reaches 10 4 dPa·s of 1320°C or lower, and containing, indicated by mol% on the basis of oxides, SiO 2 66 to 70, Al 2 O 3 12 to 14, B 2 O 3 exceeding 0 to 1.5, MgO exceeding 9.5 to 13 (or 5 to 9.5), CaO 4 to 9 (or 4 to 11), SrO 0.5 to 4.5, BaO 0 to 0.5 and ZrO 0 to 2, in which MgO+CaO+SrO+BaO is from 17 to 21 (or exceeding 18.2 to 21), MgO/(MgO+CaO+SrO+BaO) is 0.4 or more (or 0.25 or more), MgO/(MgO+CaO) is 0.4 or more (or 0.3 or more), and MgO/(MgO+SrO) is 0.6 or more (and Al 2 O 3 ×(MgO/(MgO+CaO+SrO+BaO)) is 5.5 or more).
    • 本发明涉及应变点为710℃以上且低于725℃,50〜300℃的平均热膨胀系数为30×10 -7〜43×10 -4的非碱玻璃, 7 /℃,玻璃粘度达到10 2 dPa·s为1710℃以下的温度T 2,玻璃粘度达到10 4 dPa·s的温度T 4为1320℃以下,含有 以氧化物摩尔%表示,SiO 2 66〜70,Al 2 O 3 12〜14,B 2 O 3超过0〜1.5,MgO超过9.5〜13(或5〜9.5),CaO 4〜9 (或4〜11),SrO 0.5〜4.5,BaO 0〜0.5和ZrO 0〜2,MgO + CaO + SrO + BaO为17〜21(或超过18.2〜21),MgO /(MgO + CaO + SrO + BaO)为0.4以上(或0.25以上),MgO /(MgO + CaO)为0.4以上(0.3以上),MgO /(MgO + SrO)为0.6以上(Al 2 O 3×(MgO /(MgO + CaO + SrO + BaO))为5.5以上)。
    • 8. 发明公开
    • ALKALI-FREE GLASS AND METHOD FOR PRODUCING SAME
    • VERFAHREN ZU SEINER HERSTELLUNG的NICHTALKALISCHES GLAS
    • EP2857367A1
    • 2015-04-08
    • EP13799861.3
    • 2013-06-04
    • Asahi Glass Company, Limited
    • TOKUNAGA HirofumiKOIKE AkioNISHIZAWA ManabuTSUJIMURA Tomoyuki
    • C03C3/112C03C3/118
    • C03C3/093C03C1/02C03C3/087C03C3/091C03C3/112C03C3/118
    • The present invention relates to an alkali-free glass having a strain point of 710°C or higher, an average thermal expansion coefficient at from 50 to 350°C of from 30×10 -7 to 43×10 -7 /°C, a temperature T 2 at which glass viscosity reaches 10 2 dPa·s of 1,710°C or lower, and a temperature T 4 at which the glass viscosity reaches 10 4 dPa·s of 1,320°C or lower, containing, indicated by % by mass on the basis of oxides: SiO 2 58.5 to 67.5, Al 2 O 3 18 to 24, B 2 O 3 0 to 1.7, MgO 6.0 to 8.5, CaO 3.0 to 8.5, SrO 0.5 to 7.5, BaO 0 to 2.5, and ZrO 2 0 to 4.0, containing 0 to 0.35% by mass of Cl, 0.01 to 0.15% by mass of F, and 0.01 to 0.3% by mass of SnO 2 , and having a β-OH value of the glass of from 0.15 to 0.60 mm -1 , in which (MgO/40.3)+(CaO/56.1)+(SrO/103.6)+(BaO/153.3) is from 0.27 to 0.35, (MgO/40.3)/((MgO/40.3)+(CaO/56.1)+(SrO/103.6)+(BaO/153.3)) is 0.40 or more, (MgO/40.3)/((MgO/40.3)+(CaO/56.1)) is 0.40 or more, and (MgO/40.3)/((MgO/40.3)+(SrO/103.6)) is 0.60 or more.
    • 本发明涉及应变点为710℃以上,50〜350℃的平均热膨胀系数为30×10 -7〜43×10 -7 /℃的无碱玻璃, 玻璃粘度达到10 2 dPa·s的温度T 2为1710℃以下,玻璃粘度达到10 4 dPa·s以下的温度T 4为1320℃以下,含有% 基于氧化物:SiO 2 58.5〜67.5,Al 2 O 3 18〜24,B 2 O 3 0〜1.7,MgO 6.0〜8.5,CaO 3.0〜8.5,SrO 0.5〜7.5,BaO 0〜2.5,以及 ZrO 2 0〜4.0,含有0〜0.35质量%的Cl,0.01〜0.15质量%的F,0.01〜0.3质量%的SnO 2,玻璃的-2-OH值为0.15〜 (MgO / 40.3)+(CaO / 56.1)+(SrO / 103.6)+(BaO / 153.3)为0.27〜0.35(MgO / 40.3)/((MgO / 40.3)+ CaO / 56.1)+(SrO / 103.6)+(BaO / 153.3))为0.40以上,(MgO / 40.3)/((MgO / 40.3)+(CaO / 56.1))为0.40以上,(MgO / 40.3)/((MgO / 40.3)+(SrO / 103.6))为0.60以上 。
    • 9. 发明公开
    • NON-ALKALI GLASS AND METHOD FOR PRODUCING SAME
    • 非碱性玻璃及其制造方法
    • EP2842919A1
    • 2015-03-04
    • EP13780817.6
    • 2013-04-24
    • Asahi Glass Company, Limited
    • TOKUNAGA HirofumiURATA ShingoKOIKE AkioNISHIZAWA ManabuENOMOTO TakashiTSUJIMURA Tomoyuki
    • C03C3/112C03B1/00C03B5/225
    • C03C3/112C03B1/00C03C3/087C03C3/091C03C3/118Y02P40/57
    • The present invention relates to a non-alkali glass having a strain point of 710°C or higher, an average thermal expansion coefficient at from 50 to 300°C of from 30×10 -7 to 43x 10 -7 /°C, a temperature T 2 at which glass viscosity reaches 10 2 dPa·s of 1,710°C or lower, a temperature T 4 at which the glass viscosity reaches 10 4 dPa·s of 1,320°C or lower, containing, indicated by percentage by mass on the basis of oxides, SiO 2 58.5 to 67.5, Al 2 O 3 18 to 24, B 2 O 3 0 to 1.7, MgO 6.0 to 8.5, CaO 3.0 to 8.5, SrO 0.5 to 7.5, BaO 0 to 2.5 and ZrO 2 0 to 4.0, containing Cl in an amount of from 0.15 to 0.35% by mass, F in an amount of from 0.01 to 0.15% by mass and SO 3 in an amount of from 1 to 25 ppm and having a β-OH value of the glass of from 0.15 to 0.45 mm -1 , in which (MgO/40.3)+(CaO/56.1)+(SrO/103.6)+(BaO/153.3) is from 0.27 to 0.35, (MgO/40.3)/((MgO/40.3)+(CaO/56.1)+(SrO/103.6)+(BaO/153.3)) is 0.40 or more, (MgO/40.3)/((MgO/40.3) +(CaO56.1)) is 0.40 or more, and (MgO/40.3)/((MgO/40.3) +(SrO/103.6)) is 0.60 or more.
    • 本发明涉及应变点为710℃以上,50℃〜300℃的平均热膨胀系数为30×10 -7〜43×10 -7 /℃的无碱玻璃, 玻璃粘度达到102dPa·s时的温度T2为1710℃以下,玻璃粘度达到104dPa·s时的温度T4为1320℃以下,以氧化物基准的质量%表示 ,SiO 2 58.5〜67.5,Al 2 O 3 18〜24,B 2 O 3 0〜1.7,MgO 6.0〜8.5,CaO 3.0〜8.5,SrO 0.5〜7.5,BaO 0〜2.5,ZrO 2 0〜4.0, 0.35质量%,F为0.01〜0.15质量%,SO 3为1〜25ppm,玻璃的β-OH值为0.15〜0.45mm -1,其中( (MgO / 40.3)+((MgO / 40.3)+(CaO / 56.1)+(SrO / 40.3)+(CaO / 56.1)+(SrO / 103.6)+(BaO / 153.3)为0.27-0.35。 (MgO / 40.3)/((MgO / 40.3)+(CaO56.1))为0.40以上,(MgO / 40.3)/((MgO / 40.3) ) +(SrO / 103.6))为0.60以上。