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    • 3. 发明公开
    • PRODUCTION METHOD FOR 2,3,3,3-TETRA-FLUOROPROPENE
    • 2,3,3,3-四 - 氟丙烯的生产方法
    • EP2826766A1
    • 2015-01-21
    • EP13761810.4
    • 2013-03-14
    • Asahi Glass Company, Limited
    • FURUTA, ShojiTAKEUCHI, Yu
    • C07C17/269C07C21/18
    • C07C17/269C07C21/18
    • To provide an economically advantageous process for producing industrially useful HFO-1234yf efficiently and in a sufficiently controlled state by one reaction involving thermal decomposition, by using readily available raw material. A process for producing 2,3,3,3-tetrafluoropropene from a raw material composition containing chlorodifluoromethane and chloromethane, by a synthetic reaction involving thermal decomposition, which comprises (a) a step of supplying the chlorodifluoromethane and the chloromethane to a reactor, as preliminarily mixed or separately, in such amounts that the chloromethane would be in a ratio of from 0.01 to 3 mol to 1 mol of the chlorodifluoromethane, (b) a step of supplying a heat medium to the reactor, and (c) a step of bringing the heat medium in contact with the chlorodifluoromethane and the chloromethane in the reactor to form the 2,3,3,3-tetrafluoropropene.
    • 通过使用容易获得的原料,通过一个涉及热分解的反应,提供一种经济有效的工艺有效的HFO-1234yf工艺生产和控制充分的状态。 由含有一氯二氟甲烷和氯甲烷的原料组合物通过涉及热分解的合成反应制造2,3,3,3-四氟丙烯的方法,其包括(a)将氯二氟甲烷和氯甲烷提供给反应器的步骤, 预先混合或分开使用,氯代甲烷的量相对于氯二氟甲烷1摩尔为0.01〜3摩尔,(b)向反应器供给热介质的工序,(c)工序 使热介质与反应器中的氯二氟甲烷和氯甲烷接触以形成2,3,3,3-四氟丙烯。