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1. 发明授权

EP2456791B1 DISPERSION AQUEUSE DE POLYMERE AUTORETICULABLE, A BASE DE PARTICULES DE POLYMERE STRUCTUREES EN COEUR DUR ET ECORCE MOLLE ET COMPOSITIONS DE REVETEMENTS OU DE TRAITEMENT 有权
标题翻译：以硬和软CASE及涂料或处理组合物含水Autocrosslinkable聚合物分散体的聚合物颗粒
公开(公告)号：EP2456791B1
公开(公告)日：2013-08-21
申请号：EP10732881.7
申请日：2010-07-15
申请人： Arkema France
发明人： BETREMIEUX, Isabelle , BOONE, Alain , LOZE, Jean-Yves
IPC分类号： C08F2/24 , C08F265/04 , C09D151/00
CPC分类号： C08F2/24 , C08F220/14 , C08F265/00 , C08F265/04 , C08F291/00 , C08L51/003 , C08L2666/02 , C09D133/14 , C09D151/003 , C09J151/003 , Y10T428/2933 , C08F220/06 , C08F2220/1825 , C08F222/1006

2. 发明公开

EP2456791A1 DISPERSION AQUEUSE DE POLYMERE AUTORETICULABLE, A BASE DE PARTICULES DE POLYMERE STRUCTUREES EN COEUR DUR ET ECORCE MOLLE ET COMPOSITIONS DE REVETEMENTS OU DE TRAITEMENT 有权
标题翻译：以硬和软CASE及涂料或处理组合物含水Autocrosslinkable聚合物分散体的聚合物颗粒
公开(公告)号：EP2456791A1
公开(公告)日：2012-05-30
申请号：EP10732881.7
申请日：2010-07-15
申请人： Arkema France
发明人： BETREMIEUX, Isabelle , BOONE, Alain , LOZE, Jean-Yves
IPC分类号： C08F2/24 , C08F265/04 , C09D151/00
CPC分类号： C08F2/24 , C08F220/14 , C08F265/00 , C08F265/04 , C08F291/00 , C08L51/003 , C08L2666/02 , C09D133/14 , C09D151/003 , C09J151/003 , Y10T428/2933 , C08F220/06 , C08F2220/1825 , C08F222/1006
摘要： The present invention relates to an aqueous polymer dispersion, which includes hard-core, soft-shell structured particles, with the polymer phase of the core P1 having a glass-transition temperature Tg1 of 60 to 120ºC, the polymer phase of the shell P2 having a glass-transition temperature Tg2 of -20 to 40°C, the minimum film-formation temperature TMF being 0 to 50°C, with the phase P1 being 15 to 60% of the total weight of P1+P2, the phase P1 including at least one monomer M1 having at least two copolymerisable ethylene unsaturations and at least one ethylene unsaturated monomer M2 having at least one carboxylic anhydride and/or acid function, the phase P2 being 40 to 85% of the total weight of P1+P2, with said phase P2 including: at least one monomer M3 selected among the monomers having, in addition to the polymerisable ethylene unsaturation, at least one group selected among acetoacetoxy, diacetone, methylol or alkoxysilane. The invention also relates to protective and/or decorative coating compositions such as paints, varnishes, surface coatings, inks or adhesives and fibre-treatment compositions.

3. 发明公开

EP3374439A1 REVETEMENTS AYANT UNE RESISTANCE AMELIOREE AUX TACHES ET SALISSURES 有权转让
公开(公告)号：EP3374439A1
公开(公告)日：2018-09-19
申请号：EP16809933.1
申请日：2016-10-25
申请人： Arkema France
发明人： BOONE, Alain , MAZAJCZIK, Jérôme , DELMAS, Grégory , CHAMBAT, Claire
IPC分类号： C09D5/02 , C08F265/06 , C09D151/00
摘要： The present invention relates to an aqueous coating composition based on a specific aqueous polymer dispersion as binder, having increased resistance to domestic stains and dirt without specialist functional monomers. Said aqueous polymer dispersion having an MFFT between 0 and 50 °C, comprises polymer particles obtained by emulsion polymerisation in at least two steps with at least two polymer phases P1 and P2, where P1 represents 75 to 90% by weight of P1+P2 having a Fox Tg1 from 0 to 40 °C and P2 having a Fox Tg2 from 0 to 40°C, said polymer P2 representing 10 to 25% by weight of the sum of the two polymers P1 and P2 and having a calculated Hansch parameter

4. 发明授权

EP3068814B1 DISPERSION AQUEUSE DE POLYMERE A BASE DE PARTICULES MULTISTRUCTUREES POUR REVETEMENTS AQUEUX A RESISTANCE AU BLOCKING ET A L'EMPREINTE ET AVEC UNE DURETE AMELIOREES 有权
公开(公告)号：EP3068814B1
公开(公告)日：2018-08-08
申请号：EP14814919.8
申请日：2014-11-12
申请人： Arkema France
发明人： BETREMIEUX, Isabelle , BOONE, Alain , LOZE, Jean-Yves
IPC分类号： C08F285/00 , C09D151/00
CPC分类号： C09D151/003 , C08F285/00 , C08L51/003 , C08F220/06

6. 发明授权

EP2456791B2 DISPERSION AQUEUSE DE POLYMÈRE AUTORÉTICULABLE, À BASE DE PARTICULES DE POLYMÈRE STRUCTURÉES EN COEUR DUR ET ÉCORCE MOLLE ET COMPOSITIONS DE REVÊTEMENTS OU DE TRAITEMENT 有权
公开(公告)号：EP2456791B2
公开(公告)日：2019-08-21
申请号：EP10732881.7
申请日：2010-07-15
申请人： Arkema France
发明人： BETREMIEUX, Isabelle , BOONE, Alain , LOZE, Jean-Yves
IPC分类号： C08F2/24 , C08F265/04 , C09D151/00

7. 发明授权

EP3068815B1 DISPERSION AQUEUSE DE POLYMERE A BASE DE PARTICULES MULTISTRUCTUREES POUR REVETEMENTS AQUEUX MURAUX RESISTANT A LA SALISSURE ET A L'ABRASION HUMIDE 有权
公开(公告)号：EP3068815B1
公开(公告)日：2018-08-08
申请号：EP14814920.6
申请日：2014-11-12
申请人： Arkema France
发明人： BETREMIEUX, Isabelle , BOONE, Alain , LOZE, Jean-Yves
IPC分类号： C08F285/00 , C09D151/00
CPC分类号： C09D5/1662 , C08F285/00 , C09D5/022 , C09D133/08 , C09D133/12 , C09D151/003

8. 发明公开

EP3237093A1 UTILISATION DE REVETEMENTS A BASE DE DISPERSIONS AQUEUSES DE POLYMERE A STRUCTURE COEUR/ECORCE POUR LE CAPTAGE DE COMPOSES ORGANIQUES VOLATILS COMME LES ALDEHYDES 有权
标题翻译：利用改造基础DE DISPERSIONS AQUEUSES DE POLYMERE结构COEUR / ECORCE POUR LE CAPTAGE DE COMPOSES ORGANIQUES VOLATILS COMME LES ALDEHYDES
公开(公告)号：EP3237093A1
公开(公告)日：2017-11-01
申请号：EP15817469.8
申请日：2015-12-03
申请人： Arkema France
发明人： BOONE, Alain , ROIDOT, Chantal , BEURDELEY, Patricia , FOURNIER, Frédéric
IPC分类号： B01D53/02 , C08F2/24
CPC分类号： B01D53/02 , B01D2253/202 , B01D2257/708 , C08F2/24 , C08F265/06 , Y02A50/235
摘要： The invention concerns the use of an aqueous polymer dispersion having core/shell structure particles with an FFT ranging from 0 to 50°C, the polymer phase P1 being a hard core with a Tg1 of 60 to 120°C and the polymer phase P2 being a soft shell with a Tg2 of -20 to 40°C, in which P1 comprises a monomer M1 with two polymerisable ethylenic unsaturations and an ethylenically unsaturated monomer M2 carrying a carboxylic acid/anhydride functional group, and P2, representing 40 to 85% by weight of P1 + P2, comprises, in the structure of same, units from at least one monomer M3 carrying a polymerisable ethylenic unsaturation and also a ureido functional group or a functional group having a mobile alpha-hydrogen of a ketonic carbonyl, said use being for the irreversible capturing and trapping of a volatile organic compound carrying an aldehyde, ketone or amine functional group. More particularly, said use concerns the polymer from said dispersion in the form of a film or coating.
摘要翻译：本发明涉及具有0至50℃的FFT的具有核/壳结构颗粒的聚合物水分散体的用途，聚合物相P1是Tg1为60至120℃的硬核，并且聚合物相P2为 Tg为-20至40℃的软壳，其中P1包含具有两个可聚合的烯属不饱和度的单体M1和具有羧酸/酸酐官能团的烯属不饱和单体M2，P2包含40-85％的重量的P1 + P2在其结构中包含来自至少一种携带可聚合烯属不饱和基团的单体M3以及脲基官能团或具有酮羰基的可移动α-氢的官能团的单元，所述用途为用于不可逆地捕获和捕获携带醛，酮或胺官能团的挥发性有机化合物。更具体地说，所述用途涉及来自所述分散体的聚合物形式的膜或涂层。

9. 发明公开

EP3068815A1 DISPERSION AQUEUSE DE POLYMERE A BASE DE PARTICULES MULTISTRUCTUREES POUR REVETEMENTS AQUEUX MURAUX RESISTANT A LA SALISSURE ET A L'ABRASION HUMIDE 有权
标题翻译：聚合物从多水分散体的结构颗粒用于水性外墙涂料防尘和防NASSABREIBUNG
公开(公告)号：EP3068815A1
公开(公告)日：2016-09-21
申请号：EP14814920.6
申请日：2014-11-12
申请人： Arkema France
发明人： BETREMIEUX, Isabelle , BOONE, Alain , LOZE, Jean-Yves
IPC分类号： C08F285/00 , C09D151/00
CPC分类号： C09D5/1662 , C08F285/00 , C09D5/022 , C09D133/08 , C09D133/12 , C09D151/003
摘要： The invention concerns an aqueous dispersion of polymer made from structured polymer particles, said particles comprising a polymer core phase, made from a polymer P1 with a Tg1 ranging from 60 to 120°C, a second polymer phase enveloping said core, made from a polymer P2 with a Tg2 ranging from -60 to 40°C and a third polymer outer phase (or shell) made from a polymer P3, with a Tg3 ranging from Tg2 -5°C to Tg2 +5°C and having an Mn not exceeding 150000, the weight ratios of said polymers P1, P2 and P3 being, relative to the total weight of the polymer (P1 + P2 + P3): P1 from 5 to 60%, P2 from 40 to 85%, P3 from 5 to 25%, the sum of said weight ratios being 100%. The invention also concerns a method for preparing and using the dispersion of the invention as a binder in protective or decorative aqueous coating compositions. The dispersions of the invention allow the perfect formation of the film during coalescence into a homogeneous film as a result of the controlled structure of the particles formed, and the perfect reproducibility and predictability of the MFFT of same. This excellent control therefore allows excellent performances, in particular in terms of resistance to dirt, when the non-crosslinkable dispersions of the invention are formulated in external wall coating with a medium or low PVC and very good resistance to wet abrasion, in particular, in the case of paints with a high PVC.

10. 发明授权

EP3374439B1 REVETEMENTS AYANT UNE RESISTANCE AMELIOREE AUX TACHES ET SALISSURES 有权转让
公开(公告)号：EP3374439B1
公开(公告)日：2019-12-11
申请号：EP16809933.1
申请日：2016-10-25
申请人： Arkema France
发明人： BOONE, Alain , MAZAJCZYK, Jérôme , DELMAS, Grégory , CHAMBAT, Claire
IPC分类号： C09D5/02 , C08F265/06 , C09D151/00 , C08F220/18 , C08F212/08 , C08F220/40 , C08F220/06 , C08F2/24

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