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    • 1. 发明公开
    • Process for removing surface contaminants from III-V semiconductors
    • Verfahren zur Entfernung vonOberflächeverunreinigungenauf III-V Halbleitern。
    • EP0599516A2
    • 1994-06-01
    • EP93309002.9
    • 1993-11-11
    • AT&T Corp.
    • Choquette, Kent DennisFreund, Robert S.Hong, MinghweiMannaerts, Joseph Petrus
    • H01L21/306H01L21/20
    • H01L21/02046C30B29/42C30B33/00Y10S148/017
    • In accordance with the invention, a contaminated III-V semiconductor surface is cleaned by the sequential steps of exposure to hydrogen plasma, chemical etching in chlorine and annealing in vacuum. In a preferred embodiment, a semiconductor of the gallium arsenide family is subjected to hydrogen plasma in an ECR system for 20-120 minutes, then, without breaking vacuum, subjected to a C1 2 chemical etch at 250°C-450°C for 1-5 minutes. Again, without breaking vacuum, the semiconductor is annealed at 200°C-600°C for 5-15 minutes. To obtain good surface reconstruction, annealing preferably takes place at a temperature 300°C or above. The semiconductor surface thus processed is atomically smooth and sufficiently clean to permit regrowth of a high quality epitaxial layer.
    • 根据本发明,通过暴露于氢等离子体,氯中的化学蚀刻和真空退火的顺序步骤来清洁受污染的III-V半导体表面。 在优选的实施方案中,将砷化镓族的半导体在ECR系统中经受氢等离子体20-120分钟,然后在不破坏真空的情况下,在250℃-450℃进行Cl2化学蚀刻,得到1- 5分钟。 再次,在不破坏真空的情况下,半导体在200℃-600℃退火5-15分钟。 为了获得良好的表面重构,退火优选在300℃或更高的温度下进行。 如此处理的半导体表面是原子光滑的并且足够清洁以允许高质量外延层的再生长。
    • 2. 发明公开
    • Process for removing surface contaminants from III-V semiconductors
    • 从III-V半导体去除表面污染物的方法。
    • EP0599516A3
    • 1994-06-22
    • EP93309002.9
    • 1993-11-11
    • AT&T Corp.
    • Choquette, Kent DennisFreund, Robert S.Hong, MinghweiMannaerts, Joseph Petrus
    • H01L21/306H01L21/20
    • H01L21/02046C30B29/42C30B33/00Y10S148/017
    • In accordance with the invention, a contaminated III-V semiconductor surface is cleaned by the sequential steps of exposure to hydrogen plasma, chemical etching in chlorine and annealing in vacuum. In a preferred embodiment, a semiconductor of the gallium arsenide family is subjected to hydrogen plasma in an ECR system for 20-120 minutes, then, without breaking vacuum, subjected to a C1 2 chemical etch at 250°C-450°C for 1-5 minutes. Again, without breaking vacuum, the semiconductor is annealed at 200°C-600°C for 5-15 minutes. To obtain good surface reconstruction, annealing preferably takes place at a temperature 300°C or above. The semiconductor surface thus processed is atomically smooth and sufficiently clean to permit regrowth of a high quality epitaxial layer.
    • 根据本发明,通过暴露于氢等离子体,氯中的化学蚀刻和真空退火的顺序步骤来清洁受污染的III-V半导体表面。 在优选的实施方案中,将砷化镓族的半导体在ECR系统中经受氢等离子体20-120分钟,然后在不破坏真空的情况下,在250℃-450℃进行Cl2化学蚀刻,得到1- 5分钟。 再次,在不破坏真空的情况下,半导体在200℃-600℃退火5-15分钟。 为了获得良好的表面重构,退火优选在300℃或更高的温度下进行。 如此处理的半导体表面是原子光滑的并且足够清洁以允许高质量外延层的再生长。