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    • 6. 发明公开
    • METHOD OF PRODUCING POLYVINYL ALCOHOL RESIN, AND POLYVINYL ALCOHOL RESIN OBTAINED THEREBY
    • VERFAHREN ZUR HERSTELLUNG EINES POLYVINYLALKOHOLHARZES UND SO HERGESTELLTES POLYVINYLALKOHOLHARZ
    • EP3059266A1
    • 2016-08-24
    • EP14854506.4
    • 2014-09-10
    • Japan Vam & Poval Co., Ltd.
    • OHARUDA, AkinobuKAWANISHI, Masatoshi
    • C08F216/06B41M5/00B41M5/337B41M5/50B41M5/52C08F8/12C08F218/08C08L29/04C09D129/04
    • Provided are a method for producing a polyvinyl alcohol resin which is highly transparent in the form of an aqueous solution, has a good appearance when formed into a film or an aqueous gel, and improves ink acceptability and color appearance and exhibits water resistance when used for a thermal recording material or an ink-jet recording material; and a polyvinyl alcohol resin obtained by the method. In particular, provided is a method for producing a polyvinyl alcohol resin, comprising the steps of copolymerizing an aliphatic vinyl ester (A) with diacetone acrylamide (B), at least a part of which diacetone acrylamide (B) is added at a later stage, in the presence of a polymerization catalyst in an alcohol solvent, so that the ratio (a)/(b) of the polymerization yield at the end of the polymerization (a) to the polymerization yield at the end of the later addition (b) of diacetone acrylamide (B) is in the range of 1.01 to 1.10, and saponifying the resulting copolymer.
    • 提供一种以水溶液形式高度透明的聚乙烯醇树脂的制造方法,当形成膜或水性凝胶时具有良好的外观,并且改善油墨可接受性和颜色外观,并且当用于 热敏记录材料或喷墨记录材料; 和通过该方法得到的聚乙烯醇树脂。 特别是提供一种聚乙烯醇树脂的制造方法,其特征在于,包括使脂肪族乙烯基酯(A)与双丙酮丙烯酰胺(B)共聚的步骤,其中至少一部分在以后阶段加入双丙酮丙烯酰胺(B) 在醇溶剂中存在聚合催化剂的情况下,聚合结束时的聚合产率(a)/(b)(a)与后期添加结束时的聚合收率(b )双丙酮丙烯酰胺(B)的范围为1.01〜1.10,皂化所得共聚物。