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    • 4. 发明公开
    • VERFAHREN ZUR KATALYTISCHEN UMVINYLIERUNG VON CARBONSÄUREN
    • VERFAHREN ZUR KATALYTISCHEN UMVINYLIERUNG VONCARBONSÄUREN
    • EP3209633A1
    • 2017-08-30
    • EP16745764.7
    • 2016-08-03
    • Wacker Chemie AG
    • SCHULTHEISS, PeterHOELLEIN, VolkerPATSCH, Brigitte
    • C07C67/10C07C67/54C07C69/24
    • C07C67/10C07C51/09C07C67/54Y02P20/582C07C69/24C07C53/08C07C69/01
    • The invention provides a process for transvinylation of a reactant carboxylic acid with a reactant vinyl ester to give a product vinyl ester and the corresponding acid of the reactant vinyl ester in the presence of one or more catalysts, in a reactor at a temperature of 100°C to 170°C and a pressure of 2 bar abs. to 15 bar abs., wherein the reactant vinyl ester, the reactant carboxylic acid and the catalyst are supplied to a reactor, and the transvinylation reaction is conducted, and, on completion of the transvinylation reaction, the product vinyl ester is separated from the reaction mixture by distillation, characterized in that the reaction mixture is decompressed in a decompression vessel, the gaseous phase obtained is then condensed and recycled into the reactor without further purification, and the liquid phase obtained is freed of reactant vinyl ester and corresponding acid with a first distillation, and the product vinyl ester is separated from the reaction mixture in a further distillation step.
    • 本发明提供了一种反应物羧酸与反应物乙烯基酯进行转乙酰基反应得到产物乙烯基酯和反应物乙烯基酯的相应酸在一种或多种催化剂存在下在反应器中在100° C至170℃,绝对压力为2巴。 其中反应物乙烯基酯,反应物羧酸和催化剂被提供到反应器中,并且进行转乙炔基化反应,并且在转乙基化反应完成时,产物乙烯基酯与反应物分离 其特征在于反应混合物在减压容器中减压,然后将所得气相冷凝并不经进一步纯化而再循环到反应器中,并将所得液相与反应物乙烯基酯和相应的酸以第一 蒸馏,并在另一蒸馏步骤中将产物乙烯酯从反应混合物中分离出来。