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    • 10. 发明公开
    • Short chain polyether polyols prepared from ultra-low water-content starters via DMC catalysis
    • 通过DMC催化的装置,用于从超低水含量起动生产短链聚醚多元醇的方法
    • EP2267056A1
    • 2010-12-29
    • EP10006324.7
    • 2010-06-18
    • Bayer MaterialScience LLC
    • Pazos, Jose F.Browne, Edward P.Loveday, Anthony
    • C08G65/00
    • C08G65/2663C08G65/2696
    • The present invention provides a process for the polyoxyalkylation of a starter involving establishing oxyalkylation conditions in an oxyalkylation reactor in the presence of a double metal cyanide (DMC) catalyst, continuously introducing into the reactor at least one alkylene oxide and an acidified, ultra-low water content starter, in which the starter contains greater than 100 ppm and less than or equal to 500 ppm water, based on the weight of the starter, and recovering an oxyalkylated low molecular weight starter polyether product. The inventive process allows the production of short chain polyether polyols which have hydroxyl numbers of from greater than 250 up to 500, from hygroscopic initiators, such as glycerin, without DMC catalyst deactivation.
    • 本发明提供一种用于起动器包括用催化剂得到建立烷氧基化条件下的烷氧基化在双金属氰化物(DMC)的存在下反应器中,连续引入到反应器中的至少一个,烯化氧和在酸化,超低的聚烷氧基化的方法 含水量起动机,其中,所述起始物含有大于100ppm和小于或等于500ppm的水,基于所述起动器的重量,和烷氧基化的低分子量起始聚醚产物的回收。 本发明的方法允许生产短链聚醚多元醇,其具有由大于250的羟基数高达500,从吸湿性引发剂,:如甘油,没有DMC催化剂失活。