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    • 1. 发明公开
    • COMPOSITE CONTAINING CATALYTIC METAL NANOPARTICLES, AND USE FOR SAME
    • VERBUNDSTOFF MIT KATALYTISCHEN METALLNANOPARTIKELN SOWIE VERWENDUNGDAFÜR
    • EP2985078A2
    • 2016-02-17
    • EP14774636.6
    • 2014-03-28
    • Japan Science and Technology AgencyFuruya Metal Co., Ltd.
    • ARISAWA, MitsuhiroSHUTO, SatoshiHOSHIYA, NaoyukiARAI, Satoshi
    • B01J31/28C07C17/269C07C25/18C07C45/61C07C49/784C07D295/02C07B61/00
    • C07D295/033B01J23/44B01J23/462B01J23/464B01J23/468B01J23/52B01J23/745B01J23/75B01J23/755B01J31/06B01J31/165B01J31/28B01J35/0013B01J35/002B01J35/006B01J2231/4205B01J2231/4211B01J2231/4255B01J2231/4261B01J2231/4266B01J2231/4283B82Y30/00C07B37/04C07D295/023
    • Provided is a material that, when compared with SAPd, exhibits the similar activity in cross-coupling (CC) reactions, can decrease the amount of catalytic metal that is mixed into the reaction product, and increases the number of times use can be repeated. Provided are a catalyst and a catalyst precursor that use a catalytic metal other than Pd and that exhibit the CC reaction activity similar to when Pd is used. Provided are a catalyst and a catalyst precursor that exhibit the similar CC reaction activity when using Pd or a catalytic metal other than Pd, without using a carrier such as metal and without using piranha solution. A composite wherein catalytic metal nanoparticles are dispersed in a continuous phase comprising a polymer having C2-6 alkylene group units and phenylene group units (an alkylene group unit being bonded to at least the first and fourth position of the phenylene group unit). The particle diameter of the catalytic metal nanoparticles is at most 20nm. A composite structure including a substrate, and the aforementioned composite provided to the surface of the substrate. A method for manufacturing the composite structure by dehydrocondensating, in the presence of a catalytic metal compound, a benzene compound having at least two alkyl groups (two of the alkyl groups being at the first and fourth position) in order to form the composite on the substrate surface.
    • 提供了当与SAPd比较时,在交叉偶联(CC)反应中表现出相似的活性的材料,可以减少混入反应产物中的催化金属的量,并且可以重复使用次数。 提供了催化剂和催化剂前体,其使用除Pd以外的催化金属,并且显示出与使用Pd类似的CC反应活性。 提供了当使用Pd或除Pd之外的催化金属时,不使用载体如金属并且不使用食人鱼溶液时,催化剂和催化剂前体显示出类似的CC反应活性。 一种其中催化金属纳米颗粒分散在包含具有C 2-6亚烷基单元和亚苯基单元的聚合物(亚烷基单元至少连接至亚苯基单元的第一和第四位置)的连续相中的复合物。 催化金属纳米粒子的粒径为20nm以下。 一种复合结构体,包括基材和提供给基材表面的前述复合​​材料。 在催化金属化合物的存在下,通过脱气缩合制备复合结构体的方法,其中具有至少两个烷基的苯化合物(两个烷基在第一和第四位置)以形成复合材料 基材表面。
    • 5. 发明公开
    • THERMOMETER
    • 温度计
    • EP3273212A1
    • 2018-01-24
    • EP17189349.8
    • 2014-08-07
    • Furuya Metal Co., Ltd.
    • ITO, AtsushiSATO, YasuhiroMIYAZAWA, TomoakiMARUKO, Tomohiro
    • G01K7/02G01K1/10G01K1/08
    • G01K7/02G01K1/08G01K1/10
    • Provided is a thermometer that can protect a thermocouple from the external environment while preventing layers of protection tubes from reacting with each other.
      A thermometer has: a thermocouple having a pair of wires, a temperature measuring junction between the wires, and an insulator covering the wires; a first protection tube surrounding the wires, the temperature measuring junction, and the insulator of the thermocouple, while at least partially spaced apart from the wires, the temperature measuring junction, and the insulator of the thermocouple; a second protection tube surrounding the first protection tube, while at least partially spaced apart from the first protection tube; and a third protection tube located outside the first protection tube and inside the second protection tube and surrounding the first protection tube, while at least partially spaced apart from the first protection tube and the second protection tube.
    • 提供了一种温度计,它可以保护热电偶免受外部环境的影响,同时防止保护管层互相反应。 温度计具有:具有一对导线的热电偶,导线之间的温度测量结,以及覆盖导线的绝缘体; 包围所述导线,所述温度测量接头和所述热电偶的绝缘体的第一保护管,同时与所述导线,所述温度测量接头和所述热电偶的绝缘体至少部分地间隔开; 第二保护管,其围绕所述第一保护管,同时与所述第一保护管至少部分地间隔开; 以及第三保护管,所述第三保护管位于所述第一保护管外部并且位于所述第二保护管内部并且围绕所述第一保护管,同时与所述第一保护管和所述第二保护管至少部分间隔开。