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1. 发明公开

EP0744411A3 Halomethylation of polymer 失效
标题翻译：聚合物的卤甲基化
公开(公告)号：EP0744411A3
公开(公告)日：1998-05-20
申请号：EP96107620
申请日：1996-05-13
申请人： BAYER RUBBER INC
发明人： OSMAN AKHTAR
IPC分类号： C08F8/24
CPC分类号： C08F8/24 , C08F210/10
摘要： A process is provided for the halomethylation of the aromatic groups in an isoolefin-vinylidene aromatic monomer polymer by the in situ generation of the halomethylating species formed by the reaction of a methoxy alkoxy methane with a thionyl halide, the halomethylation of the polymer being catalyzed by a Lewis acid.

2. 发明授权

EP0588097B1 Nitrile rubber hydrogenation 失效
标题翻译：丁腈橡胶的氢化
公开(公告)号：EP0588097B1
公开(公告)日：1997-01-15
申请号：EP93113337.5
申请日：1993-08-20
申请人： BAYER RUBBER INC.
发明人： Rempel, Garry Llewellyn , Guo, Xiang-Yao
IPC分类号： C08C19/02
CPC分类号： C08C19/02

3. 发明授权

EP0509357B1 Polyisobutylene based block copolymers 失效
标题翻译：基于聚异丁烯的嵌段共聚物
公开(公告)号：EP0509357B1
公开(公告)日：1996-06-05
申请号：EP92105892.1
申请日：1992-04-06
申请人： BAYER RUBBER INC.
发明人： Osman, Akhtar
IPC分类号： C08G81/02
CPC分类号： C08F297/00 , C08F297/02 , C08G81/021

4. 发明公开

EP0676443A3 Silica filled rubbery vulcanizates 失效
标题翻译：填充的橡胶硫化用二氧化硅。
公开(公告)号：EP0676443A3
公开(公告)日：1996-05-01
申请号：EP95104391.8
申请日：1995-03-24
申请人： BAYER RUBBER INC.
发明人： Urban, Paul Carl , von Hellens, Walter
IPC分类号： C08K3/36 , C08L21/00 , B60C1/00 , C08L51/00
CPC分类号： C08K3/36 , C08K5/548 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L55/02 , C08L2666/02 , C08L2666/24
摘要： A process is provided for making improved rubbery vulcanizates wherein rubbery polymer is mixed with silica or silica and carbon black, polyfunctional polysulphide silane compound and sulphur-based vulcanizaiton agents and the mixture is vulcanized, the rubber polymer is a polymer having two or three domains or a mixture of a polymer having two or three domains and one of polybutadiene, styrene-butadiene polymer or natural rubber or a mixture of polybutadiene and natural rubber.

5. 发明授权

EP0444616B1 Sulfenyl chloride adducts of hydrogenated nitrile rubber 失效
标题翻译：的硫基氯加成物与氢化丁腈橡胶。
公开(公告)号：EP0444616B1
公开(公告)日：1995-08-09
申请号：EP91102828.0
申请日：1991-02-26
申请人： BAYER RUBBER INC.
发明人： Arsenault, Gilles Joseph
IPC分类号： C08F8/34 , C08C19/20
CPC分类号： C08C19/20

6. 发明公开

EP0654459A1 Purification of hydrocarbon streams 失效
标题翻译： Verfahren zur Reinigung vonKohlenwasserstoffströmen。
公开(公告)号：EP0654459A1
公开(公告)日：1995-05-24
申请号：EP94117842.8
申请日：1994-11-11
申请人： BAYER RUBBER INC.
发明人： Ostrowicki, Andreas
IPC分类号： C07C7/148
CPC分类号： C07C7/1485
摘要： A process is provided for the removal of tertiary butyl chloride from a hydrocarbon stream, wherein the hydrocarbon stream is contacted at a temperature of from about 130° to about 170°C with a particulate calcium oxide containing from 1 to 10 mole % of a Group 3 or 4 compound and the hydrocarbon stream is recovered containing a reduced level of tertiary butyl chloride.
摘要翻译：提供了从烃流中除去叔丁基氯的方法，其中烃流在约130至约170℃的温度下与含有1至10摩尔％的组3或4化合物，回收含有降低量的叔丁基氯的烃流。

7. 发明公开

EP0652234A2 Reduced fouling in process for production of EP 失效
标题翻译： Verminderte Verschmutzung in einem Verfahren zur Herstellung von EP。
公开(公告)号：EP0652234A2
公开(公告)日：1995-05-10
申请号：EP94117016.9
申请日：1994-10-27
申请人： BAYER RUBBER INC.
发明人： Knauf, Thomas F. , Osman, Akhtar , Padliya, Dilipkumar
IPC分类号： C08F4/68 , C08F210/16 , C08F210/18
CPC分类号： C08F10/00 , C08F4/68
摘要： A process for producing EP and EPDM polymers with a reduction in fouling is provided, which process comprises polyemrizing ethylene, an alpha-olefin and a nonconjugated diolefin (if utilized) in a polymerization medium comprising a hydrocarbon diluent at a temperature of from about -50°C to about 150°C in the presence of a catalyst system comprising (a) a vanadium compound, (b) diethyl aluminum chloride, ethyl aluminum sesquichloride or ethyl aluminum dichloride and (c) an organo aluminum compound of the formula R₃Al wherein R is an alkyl group having from 8 to 12 carbon atoms and, optionally, triethyl aluminum, the molar ratio of chloride in diethyl aluminum chloride to the total aluminum content in (b) and (c) being from about 0.7:1 to about 0.95:1, the molar ratio of the chloride in ethyl aluminum sesquichloride to the total aluminum content in (b) and (c) being from about 0.7:1 to about 1.4:1 and the molar ratio of the chloride in ethyl aluminum dichloride to the total aluminum content in (b) and (c) being from about 0.7:1 to about 1.8:1 and the ratio of the mols of vanadium compound to the total mols of diethyl aluminum chloride and ethyl aluminum sesquichloride being from about 1:10 to about 1:50 to the desired conversion.
摘要翻译：提供了一种生产具有减少结垢的EP和EPDM聚合物的方法，该方法包括在包含烃稀释剂的聚合介质中在约-50℃的温度下聚乙烯，α-烯烃和非共轭二烯烃（如果使用）在（a）钒化合物，（b）二乙基氯化铝，乙基倍半氯化铝或二氯化乙基铝的催化剂体系的存在下，在约0.03至约150℃的温度下，和（c）式R3Al的有机铝化合物，其中R 是具有8至12个碳原子的烷基和任选的三乙基铝，（b）和（c）中氯化铝中氯化物与总铝含量的摩尔比为约0.7:1至约0.95:1，如图1所示，（b）和（c）中的乙基倍半氯化铝中的氯化物与总铝含量的摩尔比为约0.7:1至约1.4:1，二氯乙基铝中的氯化物与总氯化物的摩尔比明矾（b）和（c）中的含量为约0.7:1至约1.8:1，钒化合物的摩尔数与二乙基氯化铝和三乙基铝的总摩尔数的比例为约1:10至约 1:50到所需的转换。

8. 发明公开

EP0588096A1 Hydrogenation of nitrile rubber 失效
标题翻译： Hydrierung von Nitrilkautschuk。
公开(公告)号：EP0588096A1
公开(公告)日：1994-03-23
申请号：EP93113336.7
申请日：1993-08-20
申请人： BAYER RUBBER INC.
发明人： Rempel, Garry Llewellyn , Guo, Xiang-Yao
IPC分类号： C08C19/02
CPC分类号： C08C19/02
摘要： An improved process is provided for the catalytic hydrogenation of nitrile rubber using a ruthenium catalyst wherein the improvement is that the nitrile rubber is provided as an aqueous emulsion and a solvent and a selected inorganic additive are present during the hydrogenation, whereby the molecular weight increase in the hydrogenation process is minimized and controlled.
摘要翻译：提供了使用钌催化剂对丁腈橡胶的催化氢化的改进方法，其中改进是在氢化期间以丁腈橡胶作为水乳液提供溶剂和选择的无机添加剂，由此分子量增加氢化过程被最小化和控制。

9. 发明公开

EP0579058A1 Butyl rubber with a bimodal molecular weight distribution 失效
标题翻译： Butylkautschuk mit bimodaler Molekulargewichtsverteilung。
公开(公告)号：EP0579058A1
公开(公告)日：1994-01-19
申请号：EP93110610.8
申请日：1993-07-02
申请人： BAYER RUBBER INC.
发明人： Puskas, Judit Eva , Kaszas, Gabor
IPC分类号： C08F210/12 , C08F2/38
CPC分类号： C08F210/10
摘要： A polymerization process is provided for producing a butyl rubber with a bimodal molecular weight distribution which comprises introducing isobutylene, a conjugated diolefin monomer having from 4 to 8 carbon atoms, from about 1 x 10⁻⁵ to about 1 x 10⁻³ moles of an initiator component per mole of isobutylene, said initiator component being selected from the group consisting of an initiator component having the formula:

in which R₁, R₂ and R₃ are selected from the group consisting of alkyl, aryl and aralkyl groups and can be the same or different and i is a positive whole number from 2 to 6, and an initiator component having an adamantyl nucleus bearing from 2 to 4 hydroxyl groups an inert organic solvent and from about 1 x 10⁻⁴ to about 1 x 10⁻³ moles of water per litre of inert organic solvent into a suitable reaction vessel at a temperature of from about -120°C to about -50°C, adding a solution of from about 5 x 10⁻⁵ to about 1 x 10⁻² moles of a Lewis acid per mole of isobutylene in an organic solvent and polymerizing the monomers to form said butyl rubber.
摘要翻译：提供聚合方法用于生产具有双峰分子量分布的丁基橡胶，其包括引入异丁烯，具有4至8个碳原子的共轭二烯烃单体，约1×10 5至约1×10 5， - > 3摩尔的引发剂组分/摩尔异丁烯，所述引发剂组分选自具有下式的引发剂组分：其中R 1，R 2和R 3选自烷基芳基和芳烷基，并且可以相同或不同，i为2至6的正整数，并且具有2至4个羟基的金刚烷基核的引发剂组分为惰性有机溶剂和约1×10 6 - > 4>至约1×10 -3摩尔水/升惰性有机溶剂，在约-120℃至约-50℃的温度下加入合适的反应容器中，加入溶液为约5×10 -5至约1×10 -2摩尔的a 路易斯酸/有机溶剂中的每摩尔异丁烯，并使单体聚合以形成所述丁基橡胶。

10. 发明公开

EP0573881A1 Process for the manufacture of functionalized resins 失效
标题翻译： Verfahren zur Herstellung von Funktionalisierten Harzen。
公开(公告)号：EP0573881A1
公开(公告)日：1993-12-15
申请号：EP93108784.5
申请日：1993-06-01
申请人： BAYER RUBBER INC.
发明人： Arsenault, Gilles Joseph
IPC分类号： C08F212/08
CPC分类号： C08F212/08
摘要： A process is provided for the production of functional group containing resins wherein an alkyl-di-thiol is added to the polymerizing mixture of styrene and divinyl benzene part way through the polymerization. On completion of the polymerization, the product is a thiol functionalized styrene-divinyl benzene resin.
摘要翻译：提供了一种制备含官能团树脂的方法，其中通过聚合将部分途中加入苯乙烯和二乙烯基苯的聚合混合物中的烷基二硫醇。聚合完成后，产物是硫醇官能化的苯乙烯 - 二乙烯基苯树脂。

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