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81. 发明授权

EP1604972B1 Hydrogenation of high contaminated methylenedianiline 有权转让
标题翻译：高度污染的亚甲基二苯胺加氢
公开(公告)号：EP1604972B1
公开(公告)日：2011-08-10
申请号：EP05010749.9
申请日：2005-05-18
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Ding, Hao , Vedage, Gamini Ananda , Martine, William R. , Dholakia, Vipul P.
IPC分类号： C07C209/72 , C07C211/50 , B01J23/00 , B01J23/46 , B01J23/58
CPC分类号： C07C209/72 , B01J23/002 , B01J23/464 , B01J23/58 , B01J35/0006 , B01J2523/00 , B01J2523/11 , B01J2523/31 , B01J2523/821 , B01J2523/822 , C07C211/36

82. 发明公开

EP2231584A2 VERFAHREN ZUR HERSTELLUNG VON CYCLOALIPHATISCHEN AMINEN 有权
标题翻译：用于生产AMINES脂环族
公开(公告)号：EP2231584A2
公开(公告)日：2010-09-29
申请号：EP09701997.0
申请日：2009-01-14
申请人： BASF SE
发明人： PFEFFINGER, Joachim , DOELL, Willi
IPC分类号： C07C209/72 , C07C211/36 , C08K5/00 , C23F11/14 , C08K5/18
CPC分类号： C08K5/14 , C07C209/72 , C07C211/44 , C07C2601/14 , C08K5/17 , Y02P20/582 , C07C211/35 , C07C211/36
摘要： The invention relates to a method for producing cycloaliphatic amines by hydrogenation of the corresponding aromatic compounds with a gas containing hydrogen at a temperature of 30 to 280°C and a pressure of 50 - 350 bar, in the presence of ruthenium-containing catalysts, characterised in that the hydrogenation is carried out in the presence of 1 to 500 wt. %, based on the catalyst (calculated as elementary ruthenium (Ru)) and suspended inorganic adjuncts and the use of the inventive cycloaliphatic amines as synthetic building blocks.

83. 发明公开

EP1828097A1 VERFAHREN ZUR HERSTELLUNG VON 1,2-DIAMINO-3-METHYLCYCLOHEXAN UND/ODER 1,2-DIAMINO-4-METHYLCYCLOHEXAN 有权
标题翻译： VERFAHREN ZUR HERSTELLUNG VON 1,2-二氨基-3-甲基环己烷/二甲基-1,2-二氨基-4-甲基环己烷
公开(公告)号：EP1828097A1
公开(公告)日：2007-09-05
申请号：EP05819382.2
申请日：2005-12-14
申请人： BASF AKTIENGESELLSCHAFT
发明人： OSSWALD, Friederike , BRAUCH, Karl Heinz , BÖTTCHER, Arnd , HENKELMANN, Jochem , VAN LAAR, Frederik , GERLACH, Till
IPC分类号： C07C209/72
CPC分类号： C07C209/72 , C07C2601/14 , C07C211/36
摘要： The invention relates to a method for producing 1,2-diamino-3-methylcyclohexane and/or 1,2-diamino-4-methylcyclohexane by reacting 2,3- and/or 3,4-diaminotoluol with hydrogen under high pressure and high temperature in the presence of a heterogene catalyst containing rhodium. A mixture containing 2,3- and/or 3,4-diaminotoluol, a dialkylether and/or alicyclic ether as a solvent and ammonia is present in an autoclave in the presence of the catalyst and is subsequently hydrated by supplying hydrogen.
摘要翻译：通过使2,3-和/或3,4-二氨基甲苯与氢在升高的压力和升高的温度下反应制备1,2-二氨基-3-甲基环己烷和/或1,2-二氨基-4-甲基环己烷的方法，的异相铑催化剂，其中包含2,3-和/或3,4-二氨基甲苯，二烷基醚和/或脂环族醚作为溶剂的混合物和氨最初在催化剂的存在下在高压釜中装入，随后在供应氢时氢化。

84. 发明公开

EP1767520A1 Hydrogenation of aromatic amines to alicyclic amines using a ruthenium catalyst supported on lithium aluminate 有权
标题翻译：使用钌催化剂上的铝酸锂载体的芳香胺，以脂环族胺的氢化
公开(公告)号：EP1767520A1
公开(公告)日：2007-03-28
申请号：EP06019510.4
申请日：2006-09-18
申请人： Air Products and Chemicals, Inc.
发明人： Vedage, Gamini Ananda , Ding, Hao , Engel, Matthew J. , Lutz, George , Emig, Lenore Ann
IPC分类号： C07C209/72 , B01J23/46 , C07C211/36
CPC分类号： C07C209/72 , C07C2601/14 , C07C211/35 , C07C211/36
摘要： The present invention relates to processes for the catalytic hydrogenation of aromatic amines to their acyclic counterparts using a ruthenium catalyst on a lithium aluminate support. The hydrogenation process comprises contacting an aromatic amine with hydrogen in the presence of a ruthenium catalyst under temperature and pressure conditions suitable to effect ring hydrogenation. The process is especially useful for hydrogenating aniline to cyclohexylamine.

85. 发明公开

EP1566372A4 METHOD OF HYDROGENATION REACTION 有权
标题翻译： VERFAHRENFÜREINE HYDRIERUNGSREAKTION
公开(公告)号：EP1566372A4
公开(公告)日：2007-03-21
申请号：EP03811941
申请日：2003-11-27
申请人： NEW JAPAN CHEM CO LTD
发明人： FUJITANI KANGO , HAYASHI YUTAKA
IPC分类号： C07C29/149 , C07C29/17 , C07C209/72 , C07C211/36
CPC分类号： C07C29/149 , C07C29/177 , C07C209/72 , C07C33/02 , C07C31/20 , C07C31/125 , C07C211/36
摘要： Disclosed is a heterogeneous catalytic hydrogenation process comprising hydrogenating a substance to be hydrogenated under trickle flow condition using a reaction tower charged with a solid catalyst, in which hydrogen gas and a liquid phase containing the substance to be hydrogenated are made to flow co-currently downward from above, wherein dynamic liquid phase holdup amount per unit catalyst exterior surface area of the catalyst charged in the reaction tower is 0.005 x 10 to 0.14 x 10 m /m and the catalyst has a catalyst strength of 1.0 Kg or more, as determined by the following formula catalyst strength = A-2 sigma wherein A represents a mean value of minimum strengths of 100 catalyst samples measured according to the method described in "Test method for crushing strength" of JIS Z-8841-1993" and sigma represents a mean standard deviation.
摘要翻译：公开了一种多相催化氢化方法，其包括使用装有固体催化剂的反应塔在滴流状态下氢化待氢化的物质，其中使氢气和含有待氢化物质的液相共同向下流动其中，装载在反应塔中的催化剂的每单位催化剂外表面积的动态液相滞留量为0.005×10 -3至0.14×10 -3 m 3 / m 2，催化剂的催化剂强度为1.0Kg以上，如下式所示：其中A表示根据所述方法测量的100个催化剂样品的最小强度的平均值在JIS Z-8841-1993的“抗碎强度试验方法”中，sigma表示平均标准偏差。

86. 发明公开

EP1604972A1 Hydrogenation of high contaminated methylenedianiline 有权转让
标题翻译：高度污染的亚甲基二苯胺加氢
公开(公告)号：EP1604972A1
公开(公告)日：2005-12-14
申请号：EP05010749.9
申请日：2005-05-18
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Ding, Hao , Vedage, Gamini Ananda , Martine, William R. , Dholakia, Vipul P.
IPC分类号： C07C209/72 , C07C211/50 , B01J23/00 , B01J23/46 , B01J23/58
CPC分类号： C07C209/72 , B01J23/002 , B01J23/464 , B01J23/58 , B01J35/0006 , B01J2523/00 , B01J2523/11 , B01J2523/31 , B01J2523/821 , B01J2523/822 , C07C211/36
摘要： This invention relates to a process for the catalytic hydrogenation of impurity laden methylenedianiline feedstocks commonly referred to a MDA-50 and MDA-60. The process for hydrogenating methylenedianiline containing at least 40 % oligomer function by weight comprises:

contacting the feedstock with hydrogen in the presence of a rhodium/ruthenium containing catalyst system carried on a lithium aluminate support under conditions for effecting ring hydrogenation.

87. 发明公开

EP1329446A3 Hydrogenation of single ring aromatic diamines 有权
标题翻译：单环芳族二胺的氢化
公开(公告)号：EP1329446A3
公开(公告)日：2003-11-12
申请号：EP03000877.5
申请日：2003-01-15
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： Burdeniuc, Juan Jesus , Vedage, Gamini Ananda , Cook, Bradley Heath
IPC分类号： C07C209/72 , C07C211/36
CPC分类号： C07C209/72 , C07C211/18
摘要： This invention relates to an improved process for the preparation of cyclohexylamines wherein an aromatic amine is contacted with hydrogen in the presence of a hydrogenation catalyst. The improvement resides in utilizing a hydrogenation catalyst comprised of rhodium metal, utilizing a dialkyl ether solvent, and effecting delay addition of the aromatic diamine to the reaction medium.

88. 发明公开

EP1252926A3 Ruthenium-Katalysator für die Hydrierung von Diaminodiphenylmethan zu Diaminocyclohexylmethan 审中-公开
标题翻译：钌 - 二氧化二苯基甲烷二氨基环己基甲烷
公开(公告)号：EP1252926A3
公开(公告)日：2003-04-16
申请号：EP02007354.0
申请日：2002-04-08
申请人： BAYER AG
发明人： Schulze Tilling, Andreas, Dr. , Prinz, Thomas, Dr. , Kintrup, Jürgen Dr.
IPC分类号： B01J23/46 , B01J21/04 , C07C209/72
CPC分类号： C07C209/72 , B01J21/04 , B01J23/462 , B01J37/031 , C07C2601/14 , C07C211/36
摘要： Die Erfindung betrifft Ruthenium-Katalysatoren für die Hydrierung von Diaminodiphenylmethan (MDA) zu Diaminodicyclohexylmethan (PACM), insbesondere mit einem Anteil an trans,trans-4,4'-Diaminodicyclohexylmethan von 17 bis 24 %, in einem kontinuierlich betriebenen Suspensionsreaktor, wobei Ruthenium auf einen Träger aus hochreinem Aluminiumoxid aufgebracht ist, das vorzugsweise einen Gehalt an Natrium von weniger als 0,05 Gew.-%, eine Korngröße von 5 bis 150 µm und eine spezifische Oberfläche nach BET von 30 bis 300 m 2 /g aufweist.
摘要翻译：在连续悬浮反应器中用于将二氨基二苯基甲烷（MDA）氢化成二氨基二环己基甲烷（PACM）的钌催化剂由高纯度氧化铝载体上的钌组成。

89. 发明公开

EP1251119A2 Kontinuierliches Verfahren zur Herstellung von Diaminodicyclohexylmethan 审中-公开
标题翻译： Kontinueierliches Verfahren zur Herstellung von Diaminodicyclohexylmethan
公开(公告)号：EP1251119A2
公开(公告)日：2002-10-23
申请号：EP02007355.7
申请日：2002-04-08
申请人： BAYER AG
发明人： Bunnenberg, Rolf, Dr. , Gröschl, Andreas, Dr. , Holzbrecher, Michael , Schulze Tilling , Andreas Dr.
IPC分类号： C07C209/72 , C07C211/36
CPC分类号： C07C209/72 , C07C2601/14 , C07C211/36
摘要： Die Erfindung betrifft ein Verfahren zur Herstellung von Diaminodicyclohexylmethan (PACM) mit einem Anteil an trans,trans-4,4'-Diaminodicyclohexylmethan von 17 bis 24 % durch Hydrierung von Diaminodiphenylmethan (MDA) in Gegenwart eines pulverförmigen, insbesondere Ruthenium-haltigen Katalysators, wobei die Hydrierung in einem kontinuierlich betriebenen Suspensionsreaktor durchgeführt wird und der Umsatz an MDA mindestens 95 %, bezogen auf die eingesetzte Menge an MDA beträgt. Vorzugeweise wird in einer Kaskade mehrerer hintereinandergeschalteter Suspensionsreaktoren, beispielsweise einer Rührkesselkaskade oder einer Blasensäulenkaskade gearbeitet.
摘要翻译：在催化剂粉末存在下，通过二氨基二苯基甲烷（MDA）的氢化制备具有17-24％反式，反式-4,4'-二氨基二环己基甲烷部分的二氨基二环己基甲烷（PACM），在具有NOTLESS 95％ MDA转换。

90. 发明公开

EP1037870A1 VERFAHREN ZUR HERSTELLUNG VON VARIABLEN GEMISCHEN AUS CYCLOHEXYLAMIN UND DICYCLOHEXYLAMIN 审中-公开
标题翻译：用于生产变量从混合体环己胺和二环己胺
公开(公告)号：EP1037870A1
公开(公告)日：2000-09-27
申请号：EP98964445.5
申请日：1998-11-26
申请人： BAYER AG
发明人： DARSOW, Gerhard , LANGER, Reinhard
IPC分类号： C07C209/72 , C07C211/35
CPC分类号： C07C209/72 , C07C211/35
摘要： According to the inventive method for producing mixtures of optionally substituted cyclohexylamine and optionally substituted dicyclohexlamine in variable amounts by hydrogenating optionally substituted aniline using a catalyst, at a high temperature and at a high H2 pressure, Ru/Pd catalysts on supports are used. Said catalysts are characterised in that they do not contain any halogen or sulphur compounds.

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