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    • 81. 发明公开
    • PROCESS FOR COATING AND/OR TOUCHING UP COATINGS ON METAL SURFACES
    • VERFAHREN ZUM BESCHICHTEN UND / ODER NACHBESSERN VON BESCHICHTUNGEN AUFMETALLOBERFLÄCHEN
    • EP1024905A4
    • 2000-12-13
    • EP98943251
    • 1998-08-21
    • HENKEL CORP
    • MCCORMICK DAVID RLINDERT ANDREAS
    • C23C22/34C23C22/36C23C22/38C23C22/44C23C22/83B05D1/18B05D3/02C23C22/07C23C22/24C23C22/33C23C22/48
    • C23C22/36C23C22/34C23C22/361C23C22/38C23C22/44C23C22/83
    • Defects in an initial protective coating, particularly a conversion coating, on a metal substrate can be touched up so as to at least equal the original coating in corrosion protection by use of a dry-in-place aqueous acidic liquid comprising: fluorometallate anions; a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and an oxidizing agent, preferably a mixture of hexavalent and trivalent chromium. Other preferred optional active ingredients include free fluoride ions, which stabilize the fluorometallate ions against the formation of precipitates, and a fluorinated surfactant. The same composition also forms an effective protective coating over previously uncoated metal, particularly aluminum. The compositions do not contain any substantial amount of silica, which has often been previously used in compositions for similar purposes.
    • 在金属基材上的初始保护涂层,尤其是转化涂层中的缺陷可以通过使用包括以下的干式含水酸性液体来调整:至少等于原始涂层在防腐蚀保护中:含氟金属氧酸盐阴离子; 选自含磷无机氧阴离子和膦酸阴离子的组分; 和氧化剂,优选六价和三价铬的混合物。 其他优选的任选活性成分包括游离氟离子和氟化表面活性剂,所述游离氟离子稳定氟金属离子以防止沉淀形成。 相同的组合物也在先前未涂布的金属,特别是铝上形成有效的保护涂层。 该组合物不含有任何大量的二氧化硅,为了类似的目的,该组合物以前经常用于组合物中。
    • 82. 发明公开
    • COMPOSITION AND PROCESS FOR TREATING METAL
    • ZUSAMMENSETZUNG UND VERFAHREN ZUR BEHANDLUNG VON METALL
    • EP0912776A4
    • 1999-09-22
    • EP97931322
    • 1997-06-27
    • HENKEL CORP
    • DOLAN SHAWN E
    • C23C22/28C23C22/34C23C22/37C23C22/73C23C22/24
    • C23C22/34C23C22/37
    • Heating an aqueous mixture of a fluoroacid such as H2TiF6 and an oxide, hydroxide, and/or carbonate such as silica produces a clear mixture with long term stability against settling of any solid phase, even when the oxide, hydroxide, or carbonate phase before heating was a dispersed solid with sufficiently large particles to scatter light and make the mixture before heating cloudy. The clear mixture produced by heating can be mixed with soluble hexavalent and/or trivalent chromium, and preferably also nitrate and chloride ions to produce a composition that provides a conversion coating with good protection against corrosion while requiring substantially less chromium than previous coatings of equal corrosion protective quality.
    • 加热含氟酸例如H 2 TiF 6和氧化物,氢氧化物和/或碳酸盐例如二氧化硅的含水混合物产生清澈的混合物,即使在加热之前氧化物,氢氧化物或碳酸盐相在加热之前具有防止任何固相沉降的长期稳定性 是具有足够大颗粒的分散固体以散射光并使混合物在加热之前变浑浊。 通过加热产生的透明混合物可以与可溶的六价和/或三价铬以及优选还有硝酸盐和氯离子混合以产生组合物,该组合物提供具有良好的抗腐蚀保护的转化涂层,同时需要比先前的等腐蚀涂层少得多的铬 保护质量。
    • 85. 发明公开
    • Surface treatment method of a copper foil for printed circuits
    • 印刷电路铜箔的表面处理方法
    • EP0541997A3
    • 1994-11-02
    • EP92117930.5
    • 1992-10-20
    • NIKKO GOULD FOIL CO., LTD.
    • Hino, Eiji, c/o Nikko Gould Foil Co., Ltd.Yamanishi, Keisuke, c/o Nikko Gould Foil Co., Ltd.Sakaguchi, Kazuhiko, c/o Nikko Gould Foil Co.,Ltd.
    • C25D11/38C23C22/24H05K1/09
    • H05K3/244C23C22/24C25D11/38H05K3/064H05K3/384H05K2201/0355H05K2203/0723Y10S205/92
    • There is disclosed a treating process whereby the thermal oxidation resistance on the shiny side of a copper foil is enhanced so that the shiny side will not discolor on heating to higher temperatures than usual, without impairing the foil's solder wettability, adhesion to resist, and other properties. A Zn-Ni alloy layer which comprises 50-97 wt% Zn and 3-50 wt% Ni or a Zn-Co alloy layer which comprises 50-97 wt% Zn and 3-50 wt% Co is formed on the shiny side of a copper foil at a deposition quantity of 100-500 µ g/dm² and then the alloy surface is treated for Cr-base corrosion-preventive coating. The Cr-base corrosion-preventive treatment comprises (1) a treatment for forming a coating film of chromium oxide alone, (2) a treatment for forming a mixed coating film of chromium oxide and zinc and/or zinc oxide or (1) + (2). The roughened side of the copper foil may be treated to form thereon a layer of single metal or alloy of two or more metals chosen from among Cu, Cr, Ni, Fe, Co, and Zn. The shiny side does not cause discoloration upon exposure to high-temperature conditions of 240 °C for 30 minutes or 270°C for 10 minutes.
    • 公开了一种处理方法,其中铜箔的光泽面上的耐热氧化性提高,使得光泽面在加热时不会比通常更高的温度变色,而不损害箔的焊料润湿性,与抗蚀剂的粘合性等 属性。 包含50-97重量%Zn和3-50重量%Ni的Zn-Ni合金层或包含50-97重量%Zn和3-50重量%Co的Zn-Co合金层形成在 以100-500g / dm 2的沉积量的铜箔,然后将合金表面处理用于Cr基防腐涂层。 Cr基防腐处理包括(1)单独形成氧化铬的涂膜的处理,(2)形成氧化铬和锌和/或氧化锌的混合涂膜的处理或(1)+ (2)。 可以对铜箔的粗糙面进行处理,在其上形成选自Cu,Cr,Ni,Fe,Co和Zn中的两种或更多种金属的单一金属或合金层。 闪光的一面在240℃的高温条件下暴露30分钟或270℃10分钟时不会变色。