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    • 90. 发明公开
    • Non-hairing moisture curable compositions
    • KeineFädenziehende,feuchtigkeitshärtendeZusammensetzungen。
    • EP0344912A2
    • 1989-12-06
    • EP89304319.0
    • 1989-04-28
    • MINNESOTA MINING AND MANUFACTURING COMPANY
    • Kangas, Lani S. c/o Minnesota Mining andStobbie IV, Charles W. c/o Minnesota Mining and
    • C08G18/42C08G18/76C09J175/06
    • C08G18/4202C08G18/12C08G2150/20C08G2190/00C08G2250/00C08G18/307
    • A mixture of hydroxy functional polymers which can be used to form isocyanate prepolymers which are non-hairing at application temperature are disclosed. Examples of suitable mixtures of hydroxy functional polymers that can be used to form the prepolymers are:

      (1) linear polyester blends, comprising a first and second polyester wherein each polyester is the reaction product of a polyol and a polyacid, wherein
      a + b or = 6
      a + b > 4 or ≦ 6, c + d > or = 10
      a + b > 6 or ≦ 8, c + d > or = 12
      herein a is the number of methylene moieties in the polyol used to form the first polyester,
      b is the number of methylene moieties in the polyacid used to form the first polyester,
      c is the number of methylene moieties in the polyol used to form the second polyester of the blend,
      d is the number of methylene moieties in the polyacid used to form the second polyester of the blend; and
      (2) a blend of at least one non-linear polyester and one linear polyester, wherein the non-linear polyester is selected from the group consisting of polyneopentyl adipate, polypropylene adipate and polycyclohexanedimethyl adipate, and the linear polyester is selected from the group consisting of polyethylene adipate, polybutylene succinate, and polyhexamethylene sebacate, provided that when the linear polyester is polyhexamethylene sebacate, the non-linear polyester is polyneopentyl adipate or polypropylene adipate; and
      (3) a blend of poly ε-caprolactone and at least one linear polyester selected from the group consisting of polyethylene adipate, polyethylene succinate and polybutylene succinate.
    • 公开了可用于形成在应用温度下不发毛的异氰酸酯预聚物的羟基官能聚合物的混合物。 可用于形成预聚物的合适的羟基官能聚合物混合物的实例是:(1)包含第一和第二聚酯的线性聚酯共混物,其中每个聚酯是多元醇和多元酸的反应产物,其中a + 或= 4,c + d>或= 6a + b> 4或或= 10a + b6或或= 用于形成第一聚酯的多元醇中的亚甲基数目b是用于形成第一聚酯的多酸中亚甲基的数目,c是用于形成第二聚酯的多元醇中亚甲基部分的数目 共混物,d是用于形成共混物的第二聚酯的多元酸中的亚甲基部分的数目; 和(2)至少一种非线性聚酯和一种直链聚酯的共混物,其中所述非线性聚酯选自己二酸戊二醇酯,己二酸聚丙烯酯和己二酸聚环己烷二甲酯,线性聚酯选自 由聚己二酸乙二醇酯,聚丁二酸丁二醇酯和聚癸二酸六亚甲基酯组成,条件是当线性聚酯为癸二酸六亚甲基酯时,非线性聚酯为己二酸戊二醇酯或聚己二酸戊酯; 和(3)聚ε-己内酯和至少一种选自聚己二酸乙二醇酯,聚琥珀酸乙烯酯和聚丁二酸丁二醇酯的线性聚酯的共混物。 Ť