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81. 发明公开

EP1539688A2 NOUVEAUX COMPOSES COMPRENANT UN GROUPEMENT THIOCARBONYLSULFANYLE UTILES POUR LA SYNTHESE DE COMPOSES ALPHA-PERFLUOROALKYLAMINES PAR VOIE RADICALAIRE 有权
标题翻译： NOUVEAUX COMPOSES COMPRENANT UN GROUP GROUP THIOCARBONYLSULFANYLE URTILES POUR LA SYNTHESE DE COMPOSES ALPHA-PERFLUOROALKYLAMINES PAR VOIE RADICALAIRE
公开(公告)号：EP1539688A2
公开(公告)日：2005-06-15
申请号：EP03795042.5
申请日：2003-09-11
申请人： Rhodia Chimie
发明人： ZARD, Samir , GAGOSZ, Fabien , TOURNIER, Lucie
IPC分类号： C07C327/36 , C07D317/36 , C07F7/08 , C07D209/48 , C07F9/40 , C07D207/26 , C07C233/18 , C07C209/14 , C07C231/12 , C07C233/13
CPC分类号： C07C231/12 , C07C233/13 , C07C233/18 , C07C233/36 , C07C327/36 , C07C329/16 , C07C329/18 , C07C2601/02 , C07D207/27 , C07D209/14 , C07D209/48 , C07D317/36 , C07D339/06 , C07F9/4006 , C07C233/31
摘要： The invention relates to compounds having general formula (I), the preparation method thereof and the use of same in radical organic synthesis. The invention also relates to compounds having formula (II), the preparation method thereof and a method of preparing compounds having formula (VIII).
摘要翻译：本发明涉及具有通式（I）的化合物，其制备方法及其在自由基有机合成中的用途。本发明还涉及具有式（II）的化合物，其制备方法和制备具有式（VIII）的化合物的方法。

82. 发明授权

EP1331985B1 PROCEDE DE PREPARATION D'UNE EMULSION DONT LA PHASE ORGANIQUE EST DE FORTE VISCOSITE 有权
标题翻译：为了制造乳液法制，有机相高粘度HAS
公开(公告)号：EP1331985B1
公开(公告)日：2005-06-08
申请号：EP01980622.3
申请日：2001-10-22
申请人： RHODIA CHIMIE
发明人： LANNIBOIS-DREAN, Hélène , MORVAN, Mikel , LABEAU, Marie-Pierre , VIDIL, Christine
IPC分类号： B01F3/08
CPC分类号： A61K8/062 , A61K8/066 , A61K8/90 , A61K2800/24 , A61K2800/54 , A61Q19/00 , B01F17/0028 , B01F17/005 , B01F17/0085 , B01F17/0092

83. 发明公开

EP1532199A2 ADDITIF POROGENE POUR MOUSSE D ELASTOMERE SILICONE 审中-公开
标题翻译：成孔添加剂在硅弹性体发泡
公开(公告)号：EP1532199A2
公开(公告)日：2005-05-25
申请号：EP03756051.3
申请日：2003-06-04
申请人： Rhodia Chimie
发明人： GEORGE, Catherine , LEUCI, Christine , MARTIN, Nadia , POUCHELON, Alain , THIRIA, Rémi
IPC分类号： C08J9/00 , C08J9/12
CPC分类号： C08J9/125 , C08J9/0061 , C08J2383/04
摘要： The invention relates to a porogenic additive for use in production of silicone elastomer foams, which forms a single phase and which comprises: (1) water, (2) a mineral charge, (3) a texturing agent which is a water-soluble thermoplastic polymer with a high molecular mass equal to or greater than 50,000 g/mol, particularly 100,000 g/mol and (4) preferably a liquid polymer which is water-soluble, having a viscosity less than or equal to 5000 mPa.s at 25 °C. The invention further relates to a silicone composition with peroxide or as a polyaddition cross-linker, generating an elastomeric foam and comprising a porogenic additive as above.

84. 发明公开

EP1525179A2 PROCEDE DE PREPARATION D UN ESTER D UN ACIDE CARBOXYLIQUE AROMATIQUE PORTEUR D AU MOINS UN GROUPE PERFLUOROALKYLE 审中-公开
标题翻译：用于生产芳族羧酸酯中的至少一个全氟烷基BEARS
公开(公告)号：EP1525179A2
公开(公告)日：2005-04-27
申请号：EP03755627.1
申请日：2003-07-23
申请人： Rhodia Chimie
发明人： CHENEDE, Alain , SAINT-JALMES, Laurent , TIREL, Philippe-Jean , ROUSTAN, Alain
IPC分类号： C07C67/22 , C07C69/76
CPC分类号： C07C67/22 , C07C69/76
摘要： The invention relates to a method of preparing an ester of an aromatic carboxylic acid bearing at least one perfluoroalkyl group on the aromatic ring and, more specifically, alkyl esters with low carbon condensation. The inventive method is characterised in that it consists in (i) reacting an aromatic compound bearing at least one perfluoroalkyl group and at least one nitrile group on the aromatic ring, an alkanol and a strong protonic acid at a temperature of at least 45 °C and (ii) recovering the ester thus produced.

85. 发明公开

EP1517888A2 PROCEDE DE SYNTHESE DE DERIVES A RADICAL HYDROGENOFLUOROMETHYLENESULFONYLE 有权
标题翻译： PROCEDE DE SYNTHES DE衍生自由基氢芴甲基烯丙基砜
公开(公告)号：EP1517888A2
公开(公告)日：2005-03-30
申请号：EP03761633.1
申请日：2003-06-24
申请人： RHODIA CHIMIE
发明人： SAINT-JALMES, Laurent
IPC分类号： C07C319/14 , C07C323/03 , C07C303/16 , C07C309/80
CPC分类号： C07C319/14 , C07C303/16 , C07C323/03 , C07C309/80
摘要： The invention concerns a method for synthesis of hydrogenofluoromethylenesulphonyl radical derivatives, comprising: a) a step which consists in condensing a thiolate (that is a monoalkyl sulphide salt) with a compound having a sp3 hybridized carbon bearing a hydrogen, a fluorine, a heavy halogen selected among chlorine, bromine and iodine and an electron-attracting group selected among fluorine and those whereof the σp is not less than 0.2, advantageously than 0.4; b) a step which consists in oxidizing the compound obtained in step a). The invention is applicable to the synthesis of various compounds having a suphinyl or sulphonyl group.
摘要翻译：本发明涉及一种用于合成氢氟代亚甲基磺酰基自由基衍生物的方法，其包括：a）将硫醇盐（即单烷基硫化物盐）与具有sp3杂化碳的化合物缩合的步骤，该化合物带有氢，氟，重卤素选自氯，溴和碘以及选自氟和其中σp不小于0.2，有利地小于0.4的那些吸电子基团; b）包括氧化步骤a）中获得的化合物的步骤。本发明适用于合成具有亚磺酰基或磺酰基的各种化合物。

86. 发明公开

EP1516002A2 COPOLYMERES SEQUENCES 无效
标题翻译：嵌段共聚物
公开(公告)号：EP1516002A2
公开(公告)日：2005-03-23
申请号：EP03749905.0
申请日：2003-04-25
申请人： RHODIA CHIMIE
发明人： BENDEJACQ, Denis , JOANICOT, Mathieu , LIZARRAGA, Gilda , PONSINET, Virginie
IPC分类号： C08F293/00 , C08L53/00 , C09J153/00
CPC分类号： C08L53/00 , C08F293/00 , C09J153/00
摘要： The invention relates to a block copolymer and, more specifically, a thermoplastic elastomer block copolymer. The block copolymer is a diblock copolymer (block A)-(block B), a triblock copolymer (block A)-(block B)-(block A) or (block A)-(block B)-(block C), block A being a rigid block, block B being a flexible block and block C being a rigid block. Moreover, block A or block B comprises recurring units which are derived from segregation monomers.

87. 发明公开

EP1515977A1 PROCEDE DE PREPARATION D ORGANO DIALKYLALCOXYSILANE 有权
标题翻译：程序DE制备D ORGANO DIALKYLALCOXYSILANE
公开(公告)号：EP1515977A1
公开(公告)日：2005-03-23
申请号：EP03760774.4
申请日：2003-06-23
申请人： Rhodia Chimie SA
发明人： RAMDANI, Kamel , VOGIN, Bernard , GUENNOUNI, Nathalie,La Clairière
IPC分类号： C07F7/14 , C07F7/18
CPC分类号： C07F7/14 , C07F7/1892
摘要： The invention relates to the preparation of organodialkylalkoxysilane using a continuous method consisting in bringing an alkanol into continuous contact with an omega-haloalkyl dialkylhalosilane in a countercurrent reactor, such as a plate column or a packed column. The reaction is performed in the aforementioned countercurrent reactor in the presence or absence of a non-reactive solvent with scavenging of the hydrochloric acid formed. The omega-haloalkyl dialkylalkoxysilane thus formed is particularly suitable for use as a starting material for the preparation of organosilicon compounds containing sulphur having general formula (I) by means of sulphidisation reaction on an alkaline metal polysulphide.
摘要翻译：本发明涉及使用连续方法制备有机二烷基烷氧基硅烷，所述方法包括在逆流反应器（例如板式塔或填充塔）中使链烷醇与ω-卤代烷基二烷基卤代硅烷连续接触。反应在上述逆流反应器中在存在或不存在非反应性溶剂的情况下进行，同时清除所形成的盐酸。由此形成的ω-卤代烷基二烷基烷氧基硅烷特别适合用作通过在碱金属多硫化物上的硫化反应制备具有通式（I）的硫的有机硅化合物的原料。

88. 发明公开

EP1509562A1 SILICONE A FONCTION DICARBOXY 有权
标题翻译：有机硅二元共聚物
公开(公告)号：EP1509562A1
公开(公告)日：2005-03-02
申请号：EP03749903.5
申请日：2003-04-17
申请人： Rhodia Chimie
发明人： OLIER, Philippe
IPC分类号： C08G77/38 , C08G77/14
CPC分类号： C08G77/38 , C08G77/14
摘要： The invention relates to polyorganosiloxanes with dicarboxy function having formula (I): X (R4 R5 Si O)p (R6 A Si O)q Y, wherein X denotes a triorganosiloxyl end group or OH, Y denotes a triorganosilyl end group or H, R1 to R6 denote an alkyl or phenyl radical, A denotes the dicarboxy radical having formula (I'), -(CH2)3-CH(COOH)-CH2COOH (I'), or one of the salts thereof, p is between 0 and 1000 and q is between 1 and 100, the ratio of the number of H and OH end groups/total number of X and Y end groups being between 0/100 and 75/100. The invention can be used for the waterproofing of surfaces, particularly inorganic surfaces, and for the anti-corrosion treatment of metal surfaces.
摘要翻译：本发明涉及具有式（I）的具有二羧基官能团的聚有机硅氧烷：其中X表示三有机甲硅烷氧基端基或OH，Y表示三有机甲硅烷基端基或H， R1至R6代表烷基或苯基，A代表具有式（I'）， - （CH2）3-CH（COOH）-CH2COOH（I'）的二羧基或其一种盐，p在0 并且q在1和100之间时，H和OH端基的数量/ X和Y端基的总数的比例在0/100和75/100之间。本发明可用于表面特别是无机表面的防水以及金属表面的防腐蚀处理。

89. 发明公开

EP1504039A1 POLYMERE OBTENU PAR POLYMERISATION RADICALAIRE CONTROLEE COMPRENANT AU MOINS UNE FONCTION BORONATE, ASSOCIATION AVEC UN COMPOSE LIGAND ET UTILISATIONS 审中-公开
标题翻译：通过受控自由基GOT聚合物与至少一种BORONATFUNKTION，它们的组合与配体化合物及其用途
公开(公告)号：EP1504039A1
公开(公告)日：2005-02-09
申请号：EP03749904.3
申请日：2003-05-14
申请人： RHODIA CHIMIE
发明人： DESTARAC, Mathias , BAVOUZET, Bruno , BZDUCHA, Wojciech , FLEURY, Etienne
IPC分类号： C08F4/00
CPC分类号： C08F293/005 , C08F4/00
摘要： The invention relates to a polymer that can be obtained by means of controlled radical polymerisation of at least one monomer comprising a boronate function or precursor and of at least monomer without a boronate function or precursor. In addition, the invention relates to the association of the aforementioned polymer with at least one monomer, oligomer, polymer or an organic or mineral surface having at least one group which can be complexed with a boronate function or precursor of the inventive polymer. The invention also relates to the production of said association and the use thereof.

90. 发明公开

EP1494795A2 PREPARATION D UNE EMULSION PAR DILUTION D UN CONCENTRE EMULSIONNABLE COMPRENANT UN COPOLYMERE AMPHIPHILE 审中-公开
标题翻译： METHOD FOR PRODUCING乳液用薄的可乳化浓缩物与共聚物的两亲性
公开(公告)号：EP1494795A2
公开(公告)日：2005-01-12
申请号：EP03747139.8
申请日：2003-04-11
申请人： RHODIA CHIMIE
发明人： DEROO, Sophie , MORVAN, Mikel , DESTARAC, Mathias
IPC分类号： B01F17/00
CPC分类号： B01F17/0028 , B01F17/005 , B01F17/0085 , B01F17/0092
摘要： The invention concerns a method for preparing a direct emulsion, which consists in diluting in an aqueous phase a clear emulsifiable concentrate comprising an oil phase, optionally water, and amphiphilic compounds consisting of at least one surfactant, at least one copolymer having at least one hydrophilic segment and at least one hydrophobic segment, optionally at least one co-surfactant and optionally at least one neutralizing agent; the total content in amphiphilic compounds representing 1 to 40 wt. % of the emulsifiable concentrate; the copolymer content representing at least 0,1 to 25 wt. % of said amphiphilic compounds; more than 75 wt. % of the emulsion droplets have an average size not more than 1 νm; the average size of the droplets of an emulsion obtained by diluting a emulsifiable concentrate free of said copolymer; the total concentration in amphiphilic compounds being the same in both cases.

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