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71. 发明公开

EP0959061A4 3,3'-DIFLUOROBIPHENYL DERIVATIVES, LIQUID CRYSTAL COMPOSITIONS, AND LIQUID CRYSTAL DISPLAY ELEMENTS 失效
标题翻译： 3,3'- DIFLUOROBIPHENYLDERIVATE，液体制剂及液晶显示元件
公开(公告)号：EP0959061A4
公开(公告)日：2000-08-23
申请号：EP97913430
申请日：1997-11-21
申请人： CHISSO CORP
发明人： KONDO TOMOYUKI , MATSUI SHUICHI , MIYAZAWA KAZUTOSHI , TAKEUCHI HIROYUKI , TAKESHITA FUSAYUKI , NAKAGAWA ETSUO
IPC分类号： C07C25/18 , C07C43/192 , C07C43/225 , C09K19/04 , C09K19/12 , C09K19/14 , C09K19/30 , C09K19/42 , C09K19/08 , G02F1/13
CPC分类号： C09K19/12 , C07C25/18 , C07C43/192 , C07C43/225 , C09K19/0403 , C09K19/14 , C09K19/3003 , C09K19/3066 , C09K19/42 , C09K2019/0407
摘要： Liquid crystal compounds which exhibit not only negative anisotropy of permittivity but also extremely high voltage retention and low threshold voltages, are extremely reduced in the temperature dependence of these properties, difficultly exhibit a smectic phase, and are excellent in compatibility with other liquid crystal materials; liquid crystal compositions containing them; and liquid crystal display elements made by using the compositions. The compounds are specific 3,3'-difluorobiphenyl derivatives represented by general formula (1).

72. 发明公开

EP0949232A1 DIFLUOROPHENYL DERIVATIVES, LIQUID-CRYSTAL COMPOUNDS, AND LIQUID-CRYSTAL COMPOSITION 失效
标题翻译： DIFLUOROPHENYLDERIVATE液晶化合物和液体制剂
公开(公告)号：EP0949232A1
公开(公告)日：1999-10-13
申请号：EP97947960.7
申请日：1997-12-16
申请人： CHISSO CORPORATION
发明人： KATO, Takashi , MATSUI, Shuichi , MIYAZAWA, Kazutoshi , TAKESHITA, Fusayuki , NAKAGAWA, Etsuo
IPC分类号： C07C25/18 , C07C25/24 , C07C43/192 , C07C43/225 , C07D239/26 , C07F9/54 , C09K19/12 , C09K19/14 , C09K19/20 , C09K19/30 , C09K19/34 , C09K19/42 , G02F1/13
CPC分类号： C07C17/16 , C07B59/001 , C07C17/12 , C07C17/263 , C07C17/2632 , C07C17/269 , C07C17/354 , C07C25/18 , C07C25/24 , C07C43/192 , C07C43/225 , C07C45/513 , C07C45/60 , C07C2601/14 , C07F7/0896 , C09K19/0403 , C09K19/14 , C09K19/20 , C09K19/3003 , C09K19/3066 , C09K19/3402 , C09K19/3444 , C09K19/3458 , C09K19/3491 , C09K19/42 , C09K2019/0407 , C09K2019/3027 , C09K2019/3422 , Y10T428/10 , C07C22/00 , C07C47/105
摘要： Disclosed are liquid crystalline compounds which (i) are characterized in that the compounds have a wide temperature range in which the compounds exhibit a liquid crystal phase, are low in viscosity, and have a negative and high Δε, (ii) are readily mixed with other various liquid crystal materials even at low temperatures, and (iii) are useful as component of liquid crystal compositions suitable both for TFT type display mode and IPS mode; and liquid crystal composition comprising the liquid crystalline compound; the compounds are expressed by the general formula (1)
wherein R 1 represents an alkyl group having 1 to 15 carbon atoms; ring A 1 , ring A 2 , and ring A 3 independently represent trans-1,4-cyclohexylene group, trans-1,4-silacyclohexylene group, pyrimidine-2,5-diyl group, pyridine-2,5-diyl group, 1,3-dioxane-2,5-diyl group, tetrahydropyran-2,5-diyl group, 1,3-dithian-2,5-diyl group, or tetrahydrothiopyran-2,5-diyl group, or 1,4-phenylene group in which one or more hydrogen atoms on the six-membered ring may be replaced by a halogen atom; X 1 , X 2 , and X 3 independently represent -(CH 2 ) 4 -, -(CH 2 ) 3 O-, -O(CH 2 ) 3 -, or single bond; Y 1 represents hydrogen atom or an alkyl group having 1 to 15 carbon atoms; m and n are independently 0 or 1; and any atom which constitutes this compound may be replaced by its isotope.

73. 发明公开

EP0926120A4 FLUORINATED ALKYL ETHER COMPOUNDS, LIQUID-CRYSTAL COMPOSITIONS, AND LIQUID-CRYSTAL DISPLAY DEVICES 失效
标题翻译： FLUORIERTE ALKYLETHER，FLÜSSIGKRISTALLINEZUSAMMENSETZUNGEN，SOWIEFLÜSSIGKRISTALLINESICHTANZEIGEN
公开(公告)号：EP0926120A4
公开(公告)日：1999-10-13
申请号：EP97924341
申请日：1997-06-06
申请人： CHISSO CORP
发明人： KONDO TOMOYUKI , MATSUI SHUICHI , MIYAZAWA KAZUTOSHI , TAKEUCHI HIROYUKI , TAKESHITA FUSAYUKI , NAKAGAWA ETSUO
IPC分类号： G02F1/13 , C07C43/192 , C07C43/225 , C07C255/46 , C07C255/50 , C07C323/10 , C07D239/26 , C07D319/06 , C09K19/04 , C09K19/12 , C09K19/14 , C09K19/20 , C09K19/30 , C09K19/34 , C09K19/42 , C09K19/46
CPC分类号： C09K19/3001 , C07C43/225 , C07C2601/14 , C07C2601/16 , C09K19/04 , C09K19/14 , C09K19/3028 , C09K19/42 , C09K19/46 , Y10T428/10
摘要： Liquid-crystal compounds which are excellent in compatibility with other liquid-crystal materials particularly even at low temperatures, have a high voltage retention and a low threshold voltage, are lowered in the temperature dependence of these characteristic values, have a high DELTA n value, and exhibit liquid-crystal properties over a wide temperature range, the compounds being represented by the general formula: Ra-A1-Z1-A2-Z2-(-A3-Z3-)m-A0-Rf (wherein m is 0 or 1; A0, A1, A2 and A3 are each a six-membered ring, with A0 being 1,4-phenylene which may be substituted with one to three fluorine and/or chlorine atoms and A1, A2 and A3 being selected each independently from among trans-1,4-cyclohexane, optionally halogenated 1,4-phenylene, cyclohexene-1,4-diyl and 1,3-dioxane-2,5-diyl; Z1, Z2 and Z3 are each independently a bridge between rings and selected from among -(CH2)2-, -(CH2)4-, -CH2O- and -OCH2- which may be halogenated, and single bond (-); Rf is -OCF2CF2H or -OCF2CFHCF3; and Ra is a C1-C20 linear or branched monovalent organic group); liquid-crystal compositions comprising at least one of the compounds; and liquid-crystal display devices made by using the compositions.
摘要翻译：特别是即使在低温下也与其他液晶材料具有优异的相容性的液晶化合物具有高电压保持率和低阈值电压，这些特性值的温度依赖性降低，具有高Δn值，并且在宽的温度范围内表现出液晶性能，所述化合物由通式：Ra-A1-Z1-A2-Z2-（ - A3-Z3-）m-A0-Rf表示（其中m为0或1 ; A 0，A 1，A 2和A 3各自是六元环，A 0是可以被1-3个氟和/或氯原子取代的1,4-亚苯基，并且A 1，A 2和A 3各自独立地选自反式-1,4-环己烷，任选卤化的1,4-亚苯基，环己烯-1,4-二基和1,3-二氧杂环己烷-2,5-二基; Z 1，Z 2和Z 3各自独立地为环之间的桥并且选自（ - ）; - （CH 2）2 - ， - （CH 2）4 - ， - CH 2 O-和-OCH 2 - 可以被卤化，R f为-OCF 2 CF 2 H或-OCF 2 CFHCF 3; - d Ra是C 1 -C 20直链或支链一价有机基团）; 包含至少一种所述化合物的液晶组合物; 以及使用该组合物制成的液晶显示装置。

74. 发明公开

EP0916639A4 LIQUID CRYSTAL COMPOUNDS, LIQUID CRYSTAL COMPOSITIONS CONTAINING THE COMPOUNDS, AND LIQUID CRYSTAL DISPLAY DEVICES MADE BY USING THE COMPOSITIONS 失效
标题翻译：的液晶化合物，液晶中含筹备工作和这些连接制成的液晶显示器
公开(公告)号：EP0916639A4
公开(公告)日：1999-07-07
申请号：EP97908523
申请日：1997-03-27
申请人： CHISSO CORP
发明人： ANDO TSUGUMICHI , MATSUI SHUICHI , MIYAZAWA KAZUTOSHI , TAKEUCHI HIROYUKI , KOIZUMI YASUYUKI , SEKIGUCHI YASUKO , NAKAGAWA ETSUO , TAKESHITA FUSAYUKI
IPC分类号： G02F1/139 , C07C43/192 , C07C43/225 , C07C67/08 , C07C69/753 , C07C69/76 , C07C69/773 , C07D239/26 , C07D319/06 , C09K19/04 , C09K19/12 , C09K19/14 , C09K19/16 , C09K19/18 , C09K19/20 , C09K19/30 , C09K19/34 , C09K19/42 , C09K19/44 , C09K19/46 , C09K19/54 , G02F1/13 , C07C69/75 , C07C69/757
CPC分类号： C07D239/26 , C07C43/192 , C07C43/225 , C07C69/753 , C07C69/76 , C07D319/06 , C09K19/04 , C09K19/0403 , C09K19/3001 , C09K19/3066 , C09K19/3068 , C09K19/42 , C09K19/44 , C09K19/46 , C09K2019/0407 , C09K2019/0448 , C09K2019/0451 , C09K2019/3027 , Y10T428/10
摘要： Liquid crystal compounds which are lowly viscous and highly dielectrically anisotropic have high specific resistance and high voltage retention, and are stable even when exposed to heat and ultraviolet rays; liquid crystal compositions containing the compounds; and liquid crystal display devices made by using the compositions. The above liquid crystal compounds are represented by general formula (1) wherein R?1 and Y1¿ are each C¿1?-C20 alkyl; X?1, X2 and X3¿ are each independently a single bond, 1,2-ethylene, vinylene, -COO-, -CF¿2?O- or -OCF2-; A?1, A2, A3 and A4¿ are each independently trans-1,4-cyclohexylene or optionally fluorinated or chlorinated 1,4-phénylene, at least one of A?2, A3 and A4¿ being 2,3-difluoro-1,4-phenylene; and m and n are each 0 or 1, with the proviso that the elements constituting the compounds may be each replaced by isotopes thereof.

75. 发明公开

EP0926120A1 FLUORINATED ALKYL ETHER COMPOUNDS, LIQUID-CRYSTAL COMPOSITIONS, AND LIQUID-CRYSTAL DISPLAY DEVICES 失效
标题翻译： FLUORIERTE ALKYLETHER，FLÜSSIGKRISTALLINEZUSAMMENSETZUNGEN，SOWIEFLÜSSIGKRISTALLINESICHTANZEIGEN
公开(公告)号：EP0926120A1
公开(公告)日：1999-06-30
申请号：EP97924341.7
申请日：1997-06-06
申请人： CHISSO CORPORATION
发明人： KONDO, Tomoyuki , MATSUI, Shuichi , MIYAZAWA, Kazutoshi , TAKEUCHI, Hiroyuki , TAKESHITA, Fusayuki , NAKAGAWA, Etsuo
IPC分类号： C07C43/225 , C07D319/06 , C09K19/12 , C09K19/14 , C09K19/30 , C09K19/34 , C09K19/42 , G02F1/13
CPC分类号： C09K19/3001 , C07C43/225 , C07C2601/14 , C07C2601/16 , C09K19/04 , C09K19/14 , C09K19/3028 , C09K19/42 , C09K19/46 , Y10T428/10
摘要： Liquid-crystal compounds which are excellent in compatibility with other liquid-crystal materials particularly even at low temperatures, have a high voltage retention and a low threshold voltage, are lowered in the temperature dependence of these characteristic values, have a high Δn value, and exhibit liquid-crystal properties over a wide temperature range, the compounds being represented by the general formula: R a -A 1 -Z 1 -A 2 -Z 2 -(-A 3 -Z 3 -) m -A 0 -Rf (wherein m is 0 or 1; A 0 , A 1 , A 2 and A 3 are each a six-membered ring, with A 0 being 1,4-phenylene which may be substituted with one to three fluorine and/or chlorine atoms and A 1 , A 2 and A 3 being selected each independently from among trans-1,4-cyclohexane, optionally halogenated 1,4-phenylene, cyclohexene-1,4-diyl and 1,3-dioxane-2,5-diyl; Z 1 , Z 2 and Z 3 are each independently a bridge between rings and selected from among -(CH 2 ) 2 -, -(CH 2 ) 4 -, -CH 2 O-and -OCH 2 - which may be halogenated, and single bond (-); Rf is -OCF 2 CF 2 H or -OCF 2 CFHCF 3 ; and Ra is a C 1 -C 20 linear or branched monovalent organic group); liquid-crystal compositions comprising at least one of the compounds; and liquid-crystal display devices made by using the compositions.
摘要翻译：与其他液晶材料的相容性优异，特别是即使在低温下也具有高电压保持和低阈值电压的液晶化合物在这些特性值的温度依赖性方面降低，具有高DELTA n值，并且在宽的温度范围内具有液晶性能，该化合物由通式表示：Ra-A1-Z1-A2-Z2 - （ - A3-Z3-）m-A0-Rf（其中m为0或1 A 0，A 1，A 2和A 3分别为六元环，A 0为可被1〜3个氟原子和/或氯原子取代的1,4-亚苯基，A1，A2和A3各自独立地选自反式-1,4-环己烷，任选卤代的1,4-亚苯基，环己烯-1,4-二基和1,3-二恶烷-2,5-二基; Z 1，Z 2和Z 3各自独立地为环之间的桥，可以被卤化的 - （CH 2）2 - ， - （CH 2）4 - ， - CH 2 O-和-OCH 2 - ，和单键（ - ）; R f是-OCF 2 CF 2 H或-OCF 2 CFHCF 3; Ra为C1-C20直链或支链一价有机基团）; 包含至少一种化合物的液晶组合物; 以及使用该组合物制成的液晶显示装置。

76. 发明公开

EP0785179A4 CHLOROBENZENE DERIVATIVE AND LIQUID-CRYSTAL COMPOSITION CONTAINING THE SAME 失效
标题翻译：氯苯衍生物以及含有FLÜSSIGKRISTALCONNECTIONS
公开(公告)号：EP0785179A4
公开(公告)日：1998-02-25
申请号：EP95932213
申请日：1995-09-22
申请人： CHISSO CORP
发明人： MATSUI SHUICHI , KONDO TOMOYUKI , MIYAZAWA KAZUTOSHI , GOTO YASUYUKI , NAKAGAWA ETSUO , SAWADA SHINICHI
IPC分类号： C07C17/12 , C07C17/26 , C07C17/354 , C07C25/18 , C07C45/29 , C07C45/59 , C07C45/62 , C07C45/68 , C09K19/14 , C09K19/30 , C09K19/42 , G02F1/13
CPC分类号： C07C17/12 , C07C17/263 , C07C17/2632 , C07C17/2635 , C07C17/354 , C07C25/18 , C07C45/29 , C07C45/59 , C07C45/62 , C07C45/68 , C09K19/3001 , C09K19/3003 , C09K19/3028 , C07C25/24 , C07C47/546 , C07C49/657 , C07C49/683
摘要： A tetracyclic chlorobenzene derivative represented by general formula (I) and being suitable for use in active-matrix display elements and a liquid-crystal composition containing the same (wherein each of rings A, B and C independently represents trans-1,4-cyclohexylene, etc.; each of Z1, Z2 and Z3 represents -CH2CH2- or a covalent bond provided that at least one thereof is -CH2CH2-; each of L1 and L2 represents H, etc.; and R represents C1-C10 alkyl, etc.; provided that the ring A is 1,4-phenylene when Z1 and Z3 are covalent bonds and Z2 is -CH2CH2- and is trans-1,4-cyclohexylene when Z1 and Z2 are covalent bonds and Z3 is -CH2CH2- and that the rings B and C cannot be 1,4-phenylene). This compound has large values of refractive index and permittivity anisotropies, exhibits a liquid-crystal phase in a wide temperature range, is excellent in low-temperature compatibility with known liquid-crystal compounds and provides a liquid-crystal composition suitable of, especially, TFT drive.

77. 发明授权

EP0385692B1 Optcally active compounds 失效
标题翻译：有效的化合物
公开(公告)号：EP0385692B1
公开(公告)日：1993-10-06
申请号：EP90302013.9
申请日：1990-02-26
申请人： SANYO CHEMICAL INDUSTRIES LTD.
发明人： Satoh, Masahiro , Watanabe, Tetsuya , Yoshio, Kunkiyo , Kishiki, Hiroshi
IPC分类号： C09K19/32 , C09K19/12 , C09K19/34 , C09K19/14 , C09K19/18 , C07C69/76 , C07C43/174 , C07C43/225 , C07C43/176 , C07C255/33 , C07D213/64
CPC分类号： C09K19/588 , C07C43/174 , C07C43/176 , C07C43/225 , C07C255/33 , C07C255/37 , C07C255/38 , C07D239/34 , C09K19/126 , C09K19/18 , C09K19/322 , C09K19/3441 , C09K19/586

78. 发明授权

EP0357702B1 FLUORINATED OLIGOPHENYL DERIVATIVES 失效
标题翻译：氟化二乙烯衍生物
公开(公告)号：EP0357702B1
公开(公告)日：1992-08-12
申请号：EP89901464.1
申请日：1989-01-09
申请人： MERCK PATENT GmbH
发明人： COATES, David , SAGE, Ian, Charles , GREENFIELD, Simon
IPC分类号： C09K19/20 , C09K19/14
CPC分类号： C09K19/20 , C09K19/14 , C09K19/2007
摘要： The invention relates to chiral tilted smectic liquid crystal media comprising at least two liquid crystalline compounds, wherein at least one compound is of formula (I), wherein R1, R2, L1, L2, L3, L4, L5, L6 and n have the meanings indicated in Patent Claim 1 and to ferroelectric display devices which contain such media.

79. 发明授权

EP0325796B1 A liquid crystal compound and a mixture containing the same 有权
标题翻译：液晶化合物和含有它的混合物
公开(公告)号：EP0325796B1
公开(公告)日：1992-03-11
申请号：EP88121786.3
申请日：1988-12-28
申请人： Chisso Corporation
发明人： Kitano, Kisei , Ushioda, Makoto , Uchida, Manabu , Suzuki, Toshiharu
IPC分类号： C09K19/30 , C09K19/12 , C09K19/14 , C09K19/20 , C07C22/04 , C07C43/192 , C07C43/176 , C07C25/24 , C07C43/225
CPC分类号： C07C22/08 , C07C43/176 , C07C43/192 , C07C43/225 , C07C2601/14 , C09K19/12 , C09K19/14 , C09K19/3001

80. 发明公开

EP0385692A3 Optcally active compounds 失效
标题翻译：有效的化合物
公开(公告)号：EP0385692A3
公开(公告)日：1991-10-30
申请号：EP90302013.9
申请日：1990-02-26
申请人： SANYO CHEMICAL INDUSTRIES LTD.
发明人： Satoh, Masahiro , Watanabe, Tetsuya , Yoshio, Kunkiyo , Kishiki, Hiroshi
IPC分类号： C09K19/32 , C09K19/12 , C09K19/34 , C09K19/14 , C09K19/18 , C07C69/76 , C07C43/174 , C07C43/225 , C07C43/176 , C07C255/33 , C07D213/64
CPC分类号： C09K19/588 , C07C43/174 , C07C43/176 , C07C43/225 , C07C255/33 , C07C255/37 , C07C255/38 , C07D239/34 , C09K19/126 , C09K19/18 , C09K19/322 , C09K19/3441 , C09K19/586
摘要： Optically active compounds represented by the following formula (1), (2) or (3) are disclosed.
wherein R and R are C 1 - 20 alkyl groups; X and Y 1 are -, O, S, or divalent groups such as COO, OOC and OCOO; m is 0 or 1; n is 0 to 5; A 2 is a cyclic group, such as p,p'-biphenylene, 2,6-naphthylene, 2,5-pyrimidinylene-1,4-phenylene, A 1 -Y 2 -pyridylene or A 4 -Y 2 -A 5 ; Y 2 is CH 2 CH 2 or C-C triple bond; A3 is 2,6-naphthylene, A 1 -Y 2 -pyridylene or A 6 -CH 2 CH 2 -A 7 ; A 1 , A4, As, A 6 and A 7 are cyclic groups, such as 1,4-phenylene and/or 4,4 -biphenylene.

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